• Title/Summary/Keyword: thermal processes

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Improvement on Coupling Technique Between COMSOL and PHREEQC for the Reactive Transport Simulation

  • Dong Hyuk Lee;Hong Jang;Hyun Ho Cho;Jeonghwan Hwang;Jung-Woo Kim
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.1
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    • pp.175-182
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    • 2023
  • APro, a modularized process-based total system performance assessment framework, was developed at the Korea Atomic Energy Research Institute (KAERI) to simulate radionuclide transport considering coupled thermal-hydraulic-mechanical-chemical processes occurring in a geological disposal system. For reactive transport simulation considering geochemical reactions, COMSOL and PHREEQC are coupled with MATLAB in APro using an operator splitting scheme. Conventionally, coupling is performed within a MATLAB interface so that COMSOL stops the calculation to deliver the solution to PHREEQC and restarts to continue the simulation after receiving the solution from PHREEQC at every time step. This is inefficient when the solution is frequently interchanged because restarting the simulation in COMSOL requires an unnecessary setup process. To overcome this issue, a coupling scheme that calls PHREEQC inside COMSOL was developed. In this technique, PHREEQC is called through the "MATLAB function" feature, and PHREEQC results are updated using the COMSOL "Pointwise Constraint" feature. For the one-dimensional advection-reaction-dispersion problem, the proposed coupling technique was verified by comparison with the conventional coupling technique, and it improved the computation time for all test cases. Specifically, the more frequent the link between COMSOL and PHREEQC, the more pronounced was the performance improvement using the proposed technique.

Laser-Induced Recrystallization of Perovskite Materials for High-Performance Flexible Light-Emitting Diode (고성능 유연 발광 다이오드 소자 구현을 위한 레이저 기반 페로브스카이트 소재의 재결정화)

  • Jae Chan Heo;Ji Eun Kim;Dong Gyu Lee;Yun Sik Hwang;Yu Mi Woo;Han Eol Lee;Jung Hwan Park
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.3
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    • pp.286-291
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    • 2023
  • Perovskite materials are promising candidates for next-generation optoelectronic devices owing to their outstanding external quantum efficiency, high color purity, and ability to tune the light emission wavelength. However, conventional thermal annealing processes caused the degradation of perovskite, resulting in poor optoelectronic properties and a short lifetime. Herein, we propose a laser-induced recrystallization of perovskite thin film to enhance its light-emitting properties. Laser-induced recrystallization process was performed using rapid and instantaneous laser heating, which successfully induced grain growth of the perovskite material. The laser processing conditions were thoroughly optimized based on theoretical calculations and various material analyses such as x-ray diffraction, scanning electron microscope, and photoluminescence spectroscopy.

Research on Solar System Small Bodies using the Korean Small Telescopes Network

  • Ishiguro, Masateru
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.60.4-60.4
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    • 2019
  • Small bodies in the solar system are pristine leftovers of planetesimals since the formation epoch (~4.6 Gyr ago). After the formation, icy planetesimals have been preserved in the distant cold place beyond 30 au (i.e., Trans-Neptunian region) until recently without any catastrophic processes but have just been injected into inner region (<~5 au from the Sun) to be observed as comets. On the contrary, asteroids are rocky primitive objects (although some of them contains icy volatiles) distributing in the mainbelt between Mars and Jupiter orbits. Because of frequent encounters in the mainbelt, asteroids have experienced a number of repeated impacts until the present day. Namely, it is important to investigate thermal alternation process of cometary volatiles and refractories in the solar radiation field, whereas collisional and subsequence phenomena of asteroidal bodies. Although recent spacecraft observations revealed the physical natures on the surfaces of comets and asteroids, their interiors still remain largely unexplored. It is likely that a sudden brightening of a comet is associated with rapid sublimation of internal CO and CO2 or phase transition of amorphous H2O. An episodic dust ejection from an asteroid is causally related to an impact among asteroids, sudden sublimation of remaining subsurficial volatiles, etc. Because these transient phenomena provide rare opportunities to investigate their interiors, immediate observations using any optical instruments are particular important. In my presentation, I will review some examples of such transient phenomena in the solar system and propose possible collaborative research using the Korean Small Telescope Network.

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Effects of Thermal Dispersion Damage on the Pyrolysis and Reactor Relarionship Using Comutational Fluids Dynamics (전산유체역학을 활용한 폐플라스틱열분해 반응기의 기체분산판에 대한 유동해석)

  • Jongil, Han;SungSoo, Park;InJea, Kim;Kwangho, Na
    • New & Renewable Energy
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    • v.19 no.4
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    • pp.53-60
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    • 2023
  • The Computational Fluid Dynamics (CFD) model is a method of studying the flow phenomenon of fluid using a computer and finding partial differential equations that dominate processes such as heat dispersion through numerical analysis. Through CFD, a lot of information about flow disorders such as speed, pressure, density, and concentration can be obtained, and it is used in various fields from energy and aircraft design to weather prediction and environmental modeling. The simulation used for fluid analysis in this study utilized Gexcon's (FLACS) CODE, such as Norway, through overseas journals, for the accuracy of the analysis results through many experiments. It was analyzed that a technology for treating two or more catalysts with physical properties under low-temperature atmospheric pressure conditions could not be found in the prior art. Therefore, it would be desirable to establish a continuous plan by reinforcing data that can prove the effectiveness of producing efficient synthetic oil (renewable oil) through the application that pyrolysis under low-temperature and atmospheric pressure conditions.

Combined Non-Thermal Microbial Inactivation Techniques to Enhance the Effectiveness of Starter Cultures for Kimchi Fermentation

  • Su-Ji Kim;Sanghyun Ha;Yun-Mi Dang;Ji Yoon Chang;So Yeong Mun;Ji-Hyoung Ha
    • Journal of Microbiology and Biotechnology
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    • v.34 no.3
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    • pp.622-633
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    • 2024
  • For quality standardization, the application of functional lactic acid bacteria (LAB) as starter cultures for food fermentation is a well-known method in the fermented food industry. This study assessed the effect of adding a non-thermally microbial inactivated starter culture to kimchi, a traditional Korean food, in standardizing its quality. In this study, pretreatment based on sterilization processes, namely, slightly acidic electrolyzed water (SAEW) disinfection and ultraviolet C light-emitting diode (UVC-LED) of raw and subsidiary kimchi materials were used to reduce the initial microorganisms in them, thereby increasing the efficiency and value of the kimchi LAB starter during fermentation. Pretreatment sterilization effectively suppressed microorganisms that threatened the sanitary value and quality of kimchi. In addition, pretreatment based on sterilization effectively reduced the number of initial microbial colonies in kimchi, creating an environment in which kimchi LAB starters could settle or dominate, compared to non-sterilized kimchi. These differences in the initial microbial composition following the sterilization process and the addition of kimchi LAB starters led to differences in the metabolites that positively affect the taste and flavor of kimchi. The combined processing technology used in our study, that is, pre-sterilization and LAB addition, may be a powerful approach for kimchi quality standardization.

Optimum Design of Junctionless MOSFET Based on Silicon Nanowire Structure and Analysis on Basic RF Characteristics (실리콘 나노 와이어 기반의 무접합 MOSFET의 최적 설계 및 기본적인 고주파 특성 분석)

  • Cha, Seong-Jae;Kim, Kyung-Rok;Park, Byung-Gook;Rang, In-Man
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.10
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    • pp.14-22
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    • 2010
  • The source/channel/drain regions are formed by ion implantation with different dopant types of $n^+/p^{(+)}/n^+$ in the fabrication of the conventional n-type metal-oxide-semiconductor field effect transistor(NMOSFET). In implementing the ultra-small devices with channel length of sub-30 nm, in order to achieve the designed effective channel length accurately, low thermal budget should be considered in the fabrication processes for minimizing the lateral diffusion of dopants although the implanted ions should be activated as completely as possible for higher on-current level. Junctionless (JL) MOSFETs fully capable of the the conventional NMOSFET operations without p-type channel for enlarging the process margin are under researches. In this paper, the optimum design of the JL MOSFET based on silicon nanowire (SNW) structure is carried out by 3-D device simulation and the basic radio frequency (RF) characteristics such as conductance, maximum oscillation frequency($f_{max}$), current gain cut-off frequency($f_T$) for the optimized device. The channel length was 30 run and the design variables were the channel doping concentration and SNW radius. For the optimally designed JL SNW NMOSFET, $f_T$ and $f_{max}$ high as 367.5 GHz and 602.5 GHz could be obtained, respectively, at the operating bias condition $V_{GS}$ = $V_{DS}$ = 1.0 V).

Effects of stabilizing temperature gradients on thermal convection in rectangular enclosures during phsysical vapor trnasport (승화법에 의한 단결정성장공정에서 이중온도구배가 대류현상에 미치는 영향)

  • 김극태;최장우;이민옥;권무현;권순길
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.94-100
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    • 1999
  • Mercurous chloride($Hg_2Cl_2$) crystals hold promise for many acousto-optic and opto-electronic applications, which are prepared in closed ampoules by the physical vapor transport(PVT) growth methods. The thermal boundary conditions established by imposing different temperature on sidewalls of the enclosure cause simultaneous horizontal and vertical convectie flow in the PVT processes of$Hg_2Cl_2$ . It is found that for the ratios of horizontal to vertical thermal Rayleigh numbers$Ra_H/Ra{\ge}1.5$, the convective flow structure changes from multicellular to unicellular for the base parametric state of Ra=($2.79{\times}10^4$) , Pr=0.91, Le=1.01, Pe=4.60, Ar=0.2 and$C_V =1.01$. For the $\Delta T^{*}_H$ greater than 0.3, the $$\mid$U$\mid$_{max}$is increased with increasing $\Delta$ T^{*}_H$ and decreasing the aspect ratio. For the aspect ratios ranging from 0.1 to 1.0, there is a direct and linear relationship between $$\mid$U$\mid$_{max}$ and $\sqrt{{\Delta}T^_H\;^{\ast}}$.A decrease in the aspect ratio destabilizes the convective flow and results in an increase of the magnitude of convection in the crystal growth reactor. The vertical gradient tends to destabilize the convective flow which leads to oscillations, whereas the horizontal gradient stabilizes the convection.

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Measurements of Inner Defects of the Plate using Dual-beam Shearography (Dual-Beam Shearography를 이용한 물체의 내부결함 측정)

  • Ham, Hyo-Shick;Choi, Sung-Eul
    • Korean Journal of Optics and Photonics
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    • v.16 no.3
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    • pp.239-247
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    • 2005
  • In this study, we have used newly developed dual-beam shearography which is based on laser speckle that includes various information about an object. Among the several shearing techniques, we used Michelson shearing interference technique which is the most powerful. Acrylate plate was used as a sample, which has inner defects and low thermal conductivity. Michelson shearing interferometer was used for obtaining speckle fringes. We also used phase shifting technique to get a phase map. Using single beam illumination, we could obtain mixture of deformation components of both in-plane and out-of-plane. In order to separate the two components, we have used dual-beam shearography technique. We have obtained a speckle pattern of both before and after deformation. Through LS filtering and unwrapping processes, we could find a position and a shape of the inner defects easily. Deformation of the acrylate plate due to thermal heating has occurred mainly in z-direction(out-of-plane) because it has low thermal conductivity. The acrylate plate was deformed only at the restricted area where the electrical heat applied.

Establishment of Thermal Infrared Observation System on Ieodo Ocean Research Station for Time-series Sea Surface Temperature Extraction (시계열 해수면온도 산출을 위한 이어도 종합해양과학기지 열적외선 관측 시스템 구축)

  • KANG, KI-MOOK;KIM, DUK-JIN;HWANG, JI-HWAN;CHOI, CHANGHYUN;NAM, SUNGHYUN;KIM, SEONGJUNG;CHO, YANG-KI;BYUN, DO-SEONG;LEE, JOOYOUNG
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.22 no.3
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    • pp.57-68
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    • 2017
  • Continuous monitoring of spatial and temporal changes in key marine environmental parameters such as SST (sea surface temperature) near IORS (Ieodo Ocean Research Station) is demanded to investigate the ocean ecosystem, climate change, and sea-air interaction processes. In this study, we aimed to develop the system for continuously measuring SST using a TIR (thermal infrared) sensor mounted at the IORS. New SST algorithm is developed to provide SST of better quality that includes automatic atmospheric correction and emissivity calculation for different oceanic conditions. Then, the TIR-based SST products were validated against in-situ water temperature measurements during May 17-26, 2015 and July 15-18, 2015 at the IORS, yielding the accuracy of 0.72-0.85 R-square, and $0.37-0.90^{\circ}C$ RMSE. This TIR-based SST observing system can be installed easily at similar Ocean Research Stations such as Sinan Gageocho and Ongjin Socheongcho, which provide a vision to be utilized as calibration site for SST remotely sensed from satellites to be launched in future.

Impact of Expanded Small Alkyl-Binding Pocket by Triple Point Mutations on Substrate Specificity of Thermoanaerobacter ethanolicus Secondary Alcohol Dehydrogenase

  • Dwamena, Amos K.;Phillips, Robert S.;Kim, Chang Sup
    • Journal of Microbiology and Biotechnology
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    • v.29 no.3
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    • pp.373-381
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    • 2019
  • Site-directed mutagenesis was employed to generate five different triple point mutations in the double mutant (C295A/I86A) of Thermoanaerobacter ethanolicus alcohol dehydrogenase (TeSADH) by computer-aided modeling with the aim of widening the small alkyl-binding pocket. TeSADH engineering enables the enzyme to accept sterically hindered substrates that could not be accepted by the wild-type enzyme. The underline in the mutations highlights the additional point mutation on the double mutant TeSADH introduced in this work. The catalytic efficiency ($k_{cat}/K_M$) of the ${\underline{M151A}}$/C295A/I86A triple TeSADH mutant for acetophenone increased about 4.8-fold higher than that of the double mutant. A 2.4-fold increase in conversion of 3'-methylacetophenone to (R)-1-(3-methylphenyl)-ethanol with a yield of 87% was obtained by using ${\underline{V115A}}$/C295A/I86A mutant in asymmetric reduction. The ${\underline{A85G}}$/C295A/I86A mutant also produced (R)-1-(3-methylphenyl)-ethanol (1.7-fold) from 3'-methylacetophenone and (R)-1-(3-methoxyphenyl)-ethanol (1.2-fold) from 3'-methoxyacetophenone, with improved yield. In terms of thermal stability, the ${\underline{M151A}}$/C295A/I86A and ${\underline{V115A}}$/C295A/I86A mutants significantly increased ${\Delta}T_{1/2}$ by $+6.8^{\circ}C$ and $+2.4^{\circ}C$, respectively, with thermal deactivation constant ($k_d$) close to the wild-type enzyme. The ${\underline{M151A}}$/C295A/I86A mutant reacts optimally at $70^{\circ}C$ with almost 4 times more residual activity than the wild type. Considering broad substrate tolerance and thermal stability together, it would be promising to produce (R)-1-(3-methylphenyl)-ethanol from 3'-methylacetophenone by ${\underline{V115A}}$/C295A/I86A, and (R)-1-phenylethanol from acetophenone by ${\underline{M151A}}$/C295A/I86A mutant, in large-scale bioreduction processes.