• Title/Summary/Keyword: thermal oil system

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Thermochemical Sulfate Reduction Simulation Experiments on the Formation and Distribution of Organic Sulfur Compounds in the Tuha Crude Oil

  • Yue, Changtao;Li, Shuyuan;Song, He
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.2057-2064
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    • 2014
  • Thermochemical sulfate reduction (TSR) was conducted in autoclave on the system of crude oil and $MgSO_4$ at different temperatures. Gas chromatography pulsed flame photometric detector (GC-PFPD) was used to detected the composition of organic sulfur compounds in oil phase products. The results of the analysis indicate that with increased temperature, the contents of organic sulfur compounds with high molecular weight and thermal stability, such as benzothiophenes and dibenzothiophenes, gradually became dominated. In order to gain greater insight into the formation and distribution of organic sulphur compounds from TSR, positive ion electrospray Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) was used in detecting the detailed elemental composition and distribution of them. The mass spectra showed that the mass range of sulfur compounds was 200-550 Da. Four sulfur class species, $S_1$, $N_1S_1$, $O_1S_1$ and $O_2S_1$, were assigned in the positive-ion spectrum. Among the identified sulfur compounds, the $S_1$ class species was dominant. The most abundant $S_1$ class species increase associated with the DBE value and carbon number increasing which also indicates the evolution of organic sulfur compounds in TSR is from the labile series to the stable one. In pure blank pyrolysis experiments with crude oil cracking without TSR, different composition and distribution of organic sulfur compounds in oil phase products were seen from mass spectra in order to evaluate their pyrolysis behaviors without $MgSO_4$. FT-IR and XRD were used in analyzing the products of solid phases. Two distinct crystallographic phases MgO and $MgSO_4$ are found to coexist in the products which demonstrated the transformation of inorganic sulfur compounds into organosulfur compounds exist in TSR.

A Design of Fire Detection System based on Infrared Thermal Imaging & CCD Camera (적외선 열영상 및 CCD 카메라 기반 화재감지 시스템 설계)

  • Kim, Tae Wan;Choi, Chang Yong;Lee, Dong Myung
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2013.05a
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    • pp.597-598
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    • 2013
  • A lot of fire and crime accidents are caused to a significant national loss. For example, the network and power facilities in national industry facilities, the fire risk region in large scale factories such as nuclear and thermal power plants, large-sized buildings, cultural properties, metal and steel mills, chemical plants, oil refineries. The development of a fire detection system that can detects the temperature and movement of objects as high-level quality is essential to prevent these incidents and accidents fundamentally. In this paper, the fire detection system based on infrared thermal imaging & CCD camera id designed to solve these problems.

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Heat Pump System Using Heated Effluent of Thermal Power Generation Plant as a Heat Source (해수를 이용한 화력발전소 폐열회수 히트펌프 시스템)

  • Ryou, Y.S.;Kang, Y.K.;Kim, Y.H.;Jang, J.K.;Kim, J.G.;Lee, H.M.;Kang, G.C.;Nah, K.D.;Huh, T.H.
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.190-190
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    • 2011
  • In South Korea the gross generation and heated effluent of power generation plant was 259 TWh and 4.73 billion tons in 2008. And then the waste heat from power generation was 388 TWh. It shows that the efficiency of thermal power generation plant is about 40%. Therefore to reduce $CO_2$ emission from thermal power generation plant, the energy of this heated effluent must be reused to heat buildings or farm facilities. In South Korea horticultural facilities of about 25% are heated in winter season. Total area of greenhouses which are heated is about 13,000 ha. Total heat amount needed to warm greenhouse of 13,000 ha in winter season is only 3.4% of total waste heat from power generation plant. In this study a heat pump system was designed to reuse the waste heat from power generation. Especially new heat exchanger was developed to recover the thermal energy from waste water and this model considered anti-corrosion against sea water and low cost for economic feasibility. This heat recovery system was installed in mango growing greenhouse around thermal power generation plant in Seogwipo-city, Jeju Special Self-Governing Province. The result of preliminary test shows that the heating cost of about 90% is saved as compared to boiler using tax free light oil as a fuel.

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Importance Of Tribology in Positive-Displacement Type of Fluid Machinery and Heat Engine

  • Nakahara, Tsunamitsu
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.10a
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    • pp.3-8
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    • 1998
  • The industrial revolution in England was based on the manufacturing systems by the power of water mill and rapidly progressed by the innovation of steam engine. It is no exaggeration to say that today's civilization is realized by the development of various types of power machinery, namely fluid machinery and heat engine. The electric energy is converted mainly from thermal energy (mainly steam) of mineral oil, coal and nuclear fuel through generator connected with steam turbine which is a kind of power machinery. There are various types of power machinery as shown in Tables 1a and 1b. They are classified into two types by use. One is absorption type of fluid and/or thermal energy, for examples, windmill and heat engine. The other is provision type of the energies for examples, pump, compressor and propulsion. By flow type, they are also classified by two types, turbo type and positive-displacement type. The turbo type began from water mill and windmill and evolve to steam turbine and finally to gas turbine. The positive-displacement type started from reciprocating water pump and developed into steam engine and changed to reciprocating combustion engine. The pumps and motors used in oil hydraulic system for power control are also positive-displacement type.

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n Analysis of Elastohydrodynamic lubrication in Line Contacts-the effect of temperature variation (유체 온도 변화를 고려한 선 접촉면사이의 탄성유체윤활 해석)

  • 서민호;임윤철
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.11a
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    • pp.364-373
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    • 2001
  • This paper describes the variation of lubricant's temperature effects on elastohydrodynamic lubrication. The Newton-Raphson technique was used to solve the simultaneous system of Reynolds and elasticity equations. To show effects of lubricant's temperature, average temperature across the oil film was calculated using the energy equation. Pressure distribution, film shape, and temperature distribution were obtained for fully flooded conjunctions, and various dimensionless speed parameters while load and material parameters were held constant. Minimum film thickness were obtained for various material properties while load and velocity were held constant. It is drawn that the thermal effects have a strong influence on a minimum film thickness under high rolling velocity and slip ratio.

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The Development of the Simplified Simulation Technique for the Best Generation Mix (최적전원차성을 위한 절감 시뮬레이션 방법의 개발)

  • 송길영;최재석
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.37 no.6
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    • pp.339-349
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    • 1988
  • The simplified simulation technique for the best generation mix is developed and the studied results are described. The best generation mix over study time from the economic point of view can be easily constructed by this technique. Generator maintenance, the operation of pumpgenerator and LNG thermal generator with limited energy are simulated variously, so a role of each generator is also easily evaluated. Through parametric analysis, useful planning guide points are obtained for the best generation mix transition, nuclear power plant construction cost, ruanium cost , oil cost, coal cost and midnight factor in the study case corresponding to real power system size model.

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A Study on Actual Condition Analysis of Solar Thermal System Demonstrative Enterprise in the J City (J시 태양열 시범사업의 실태조사.분석에 관한 연구)

  • Yoo, Dong-Chul;Lee, Doo-Ho;Lee, Eung-Jik
    • 한국태양에너지학회:학술대회논문집
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    • 2011.04a
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    • pp.80-85
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    • 2011
  • As the instability of oil prices rose because of the situation in Libya, oil prices worldwide recorded the highest level due to the interference in supply. And so, in the 21st century, increasing efforts are being made to use clean new renewable energy centered on solar energy in accommodation of the cycle of nature instead of being reliant on the oil exporting nations. In order to reduce city energy internationally, the implementation of a low carbon city under the combined cooperation of industrial. construction, new renewable energy and transportation sectors with continuous development centered on low carbon green urban planning is now becoming established as the paradigm of the times. Recently, the government has begun carrying out the One Million Green Home Project, which is a project where the government with the goal of providing one million renewable energy homes by 2020 gives renewable energy subsidization for a partial amount of the standard unit price of installation when solar ray, solar heat, geothermal heat, small wind power or fuel cell energy is used. Thus, through this thesis which studies the state of and surveys the green village at Shingok-ri Songhak-myun Jaecheon-shi, it is the desire that the One Million Green Homes Project will be more efficiently developed and plans for improvement formed so that a high level of satisfaction in the product will be provided.

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Catalytic Cracking of Pyrolysed Waste Lube-oil Into High Quality Fuel Oils Over Solid Acid Catalysts (고체산 촉매를 이용한 페윤활유 열분해유의 고급연료유화 특성 연구)

  • 박종수;윤왕래;고성혁;김성현
    • Journal of Energy Engineering
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    • v.8 no.2
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    • pp.248-255
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    • 1999
  • Catalytic cracking of pyrolysed waste lubricating oil over solid acid catalysts (HY zeolite, ${\beta}$-zeolite, HZSM-5) has been carried out in a micro-fixed bed system. The feed oil for catalytic activity tests has been prepared by thermal cracking of waste lubricating oil under the reaction conditions of 480$^{\circ}C$, 60 min. Optimum reaction conditions for the maximum light oil yields($\_$21/) were WHSV(weight hourly space velocity)=1 at 375$^{\circ}C$. The amounts of total and strong acid sites appeared to be the largest in ${\beta}$-zeolite as determined by NH$_3$, TPD. It is seen that the catalytic activity order, in terms of the light fuel oil ($\_$21/) production, were HY zeolite)${\beta}$-zeolite>HZSM-5. Also, coke formation followed the same order. The highest activity in HY zeolite may be attributed from the fact that it has supercages facilitating the easy diffusion of larger molecules and also the effectiveness of the acid sites for cracking within the pore. This fact could be confirmed by the coke formation characteristics.

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Prismatic-core advanced high temperature reactor and thermal energy storage coupled system - A preliminary design

  • Alameri, Saeed A.;King, Jeffrey C.;Alkaabi, Ahmed K.;Addad, Yacine
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.248-257
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    • 2020
  • This study presents an initial design for a novel system consisting in a coupled nuclear reactor and a phase change material-based thermal energy storage (TES) component, which acts as a buffer and regulator of heat transfer between the primary and secondary loops. The goal of this concept is to enhance the capacity factor of nuclear power plants (NPPs) in the case of high integration of renewable energy sources into the electric grid. Hence, this system could support in elevating the economics of NPPs in current competitive markets, especially with subsidized solar and wind energy sources, and relatively low oil and gas prices. Furthermore, utilizing a prismatic-core advanced high temperature reactor (PAHTR) cooled by a molten salt with a high melting point, have the potential in increasing the system efficiency due to its high operating temperature, and providing the baseline requirements for coupling other process heat applications. The present research studies the neutronics and thermal hydraulics (TH) of the PAHTR as well as TH calculations for the TES which consists of 300 blocks with a total heat storage capacity of 150 MWd. SERPENT Monte Carlo and MCNP5 codes carried out the neutronics analysis of the PAHTR which is sized to have a 5-year refueling cycle and rated power of 300 MWth. The PAHTR has 10 metric tons of heavy metal with 19.75 wt% enriched UO2 TRISO fuel, a hot clean excess reactivity and shutdown margin of $33.70 and -$115.68; respectively, negative temperature feedback coefficients, and an axial flux peaking factor of 1.68. Star-CCM + code predicted the correct convective heat transfer coefficient variations for both the reactor and the storage. TH analysis results show that the flow in the primary loop (in the reactor and TES) remains in the developing mixed convection regime while it reaches a fully developed flow in the secondary loop.

Effects of Partial Beef Fat Replacement with Gelled Emulsion on Functional and Quality Properties of Model System Meat Emulsions

  • Serdaroglu, Meltem;Nacak, Berker;Karabiyikoglu, Merve;Keser, Gokcen
    • Food Science of Animal Resources
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    • v.36 no.6
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    • pp.744-751
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    • 2016
  • The objective of this study was to investigate the effects of partial beef fat replacement (0, 30, 50, 100%) with gelled emulsion (GE) prepared with olive oil on functional and quality properties of model system meat emulsion (MSME). GE consisted of inulin and gelatin as gelling agent and characteristics of gelled and model system meat emulsions were investigated. GE showed good initial stability against centrifugation forces and thermal stability at different temperatures. GE addition decreased the pH with respect to increase in GE concentration. Addition of GE increased lightness and yellowness but reduced redness compared to control samples. The results of the study showed that partial replacement of beef fat with GE could be used for improving cooking yield without negative effects on water holding capacity and emulsion stability compared to C samples when replacement level is up to 50%. The presence of GE significantly affected textural behaviors of samples (p<0.05). In conclusion, our study showed that GE have promising impacts on developing healthier meat product formulations besides improving technological characteristics.