• Title/Summary/Keyword: thermal maturity

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Thermal Stress Analysis of the Heat Generation for Mass Concrete Considering Creep Effect (크리이프를 고려한 매스콘크리트의 수화열에 대한 온도응력 해석)

  • Kim, Jin Keun;Lee, Jong Dae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.4
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    • pp.771-781
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    • 1994
  • The heat generation of cement causes the internal temperature rise and volume change at early age, particulary in massive concrete structures. As the results of the temperature rise and restraint conditions, the thermal stress may induce cracks in concrete. Therefore, the prediction of the thermal stress is very important in the design and construction in order to control the cracks developed in mass concrete. In case of young concrete, creep effect by the temperature load is larger than that of old concrete. Thus, the effect of creep must be considered for checking the cracks, serviceability, durability and leakage. This paper is concentrated on the development of a finite element program which is capable of simulating the temperature history and the thermal stress considering creep and the modified elastic modulus due to inner temperature change and maturity. The analytical results in the inner parts highest important to control cracks are in good agreement with experimental data. Therefore this study may provide available method to control the cracks.

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Simulation of the Hydrogen Conversion Rate Prediction for a Solar Chemical Reactor (태양열 화학반응기의 수소전환효율 예측 시뮬레이션)

  • Ko, Jo-Han;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
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    • 2008.11a
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    • pp.294-299
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    • 2008
  • Steam reforming of methane is the most wide spread method for hydrogen production. It has heed studied more than 60 years. methane reforming has advantages in technological maturity and economical production cost. Using a high-temperature solar thermal energy is an advanced technology in Steam reforming process. The synthesis gas, the product of the reforming process, can be applied directly for a combined cycle or separated for a hydrogen. In this paper, hydrogen conversion rate of a solar chemical reactor is calculated using commercial CFD program. 2 models are considered. Model-1 is original model which is designed from the former researches. And model-2 is ring-disk set of baffle is inserted to enhance the performance. The solar chemical reactor has 3 inlet nozzle at the bottom of the side wall near quartz glass and an exit is located at the top. Methane and steam is premixed with 50:50 mole fraction and goes into the inside. Passing through the porous media, the reactants are conversed into hydrogen and carbon monoxide.

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Themal Stress Analysis of the Heat of Hydration Considering Pipe-Cooling (파이프 쿨링을 고려한 수화열 해석기법에 관한연구)

  • 긴진근;김국한;최계식;양주경;최고일
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.04a
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    • pp.274-279
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    • 1995
  • The heat of hyderation of cement causes the internal temperature rise and volume change at early age, paticular in massive concrete structures. As the results of the temperature rise and extenal restraint conditions, the themal stress may induce cracks in concrete. Therefore various techenuques of the themal stress control of the mass concrete has been widely used. One of these techniques is pipe-cooling which is considered in this study. The objective of this paper is to develop finite element program which is capable of simulating the temperature history and the thermal stress considering pipe-cooling, creep and the modified elastic modulus dud to maturity effect.

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An experimental study on the mechanical properties of early age concrete (초기재령 콘크리트의 역학적 특성에 관한 실험적 연구)

  • Lee, Kwang-Gyo;Yang, Eun-Ik;Yi, Seong-Tae;Kim, Myung-You;Park, Jin-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.668-671
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    • 2004
  • Recently, the concern for mechanical properties at early age concrete are increasing because of the importance of the thermal stress and the determination of removal time of form work and prestressing work. In this study, an estimation for the development of compressive strength and elastic modulus with age in concretes isothermally cured $(10^{\circ}C,\;20^{\circ}C)$ and having W/C ratio of 30, 40, and $50\%$ were investigated. According to experiment results, the development of compressive strength and elastic modulus shows higher values at early ages as the W/C ratio decreases and curing temperature increases. When the maturity concept, for estimation of the strength, is adopted, a modification for W/C ratio is required at early ages.

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Life cycle analysis on correlation relationship between GHG emission and cost of electricity generation system for energy resources (전과정을 고려한 에너지 자원별 전력생산의 온실가스 배출량과 비용의 상관관계 분석)

  • Kim, Heetae;Ahn, Tae Kyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.136.2-136.2
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    • 2011
  • In this work, we analyzed correlations between life-cycle greenhouse gas (GHG) emissions and life-cycle cost of energy resources. Energy resources studied in this paper include coal, natural gas, nuclear power, hydropower, geothermal energy, wind power, solar thermal energy, and solar photovoltaic energy, and all of them are used to generate electricity. We calculated the mean values, ranges of maximum minus minimum values, and ranges of 90% confidence interval of life-cycle GHG emissions and life-cycle cost of each energy resource. Based on the values, we plotted them in two dimensional graphs to analyze a relationship and characteristics between GHG emissions and cost. Besides, to analyze the technical maturity, the GHG emissions and the range of minimum and maximum values were compared to each other. For the electric generation, energy resources are largely inverse proportional to the GHG emission and the corresponding cost.

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Stratigraphy and Petroleum Geochemical Characteristics of Jiaolai Basin in Shandong Province of China (중국 교래분지의 층서와 석유지화학적 특성)

  • Cheong, Tae-Jin;Oh, Jae-Ho;Lee, Young-Joo;Kim, Ji-Hoon
    • The Korean Journal of Petroleum Geology
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    • v.12 no.1
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    • pp.1-8
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    • 2006
  • Jiaolai Basin is the Cretaceous continental sedimentary basin developed in Shandong Province of China. It is interpreted as a pull-apart basin which is filled with fluvio-lacustrine sediments and volcanic rocks. The sedimentary strata are divided into three formations: Laiyang Formation, Qingshan Formation and Wangshi Formation in ascending order. Laiyang Formation of the early Cretaceous consists of conglomerate, sandstone and shale, which are grey, black or red in color, respectively. Qingshan Formation of early Cretaceous includes various kinds of volcanic rocks. Late Cretaceous Wangshi Formation consists of red conglomerate, sandstone and shale. Various types of oil shows are observed on many outcrops in the basin such as asphalt filing fissures, oil smelling, rocks wetted with oil. However, commercial oil discovery was not made. Laiyang Formation is the richest in terms of organic matter contents. Some grey or black shales of Laiyang Formation contain more than 1% of organic matter. Kerogens of some layers mainly consist of amorphous organic matter or pollen. Thermal maturity of the organic matter reached main oil generation zone and hydrocarbon genetic potential is fairly good. According to such geochemical data, some layers of Laiyang Formation can act as hydrocarbon source rocks.

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Thermal Maturation and Diagenesis of the Gyeongsang Supergroup, Euiseong Area, SE Korea (의성지역 경상누층군의 열적진화와 속성작용)

  • Son Byeong-Kook;Cheong Tae-Jin;Oh lae-Ho;Kwak Young-Hoon
    • The Korean Journal of Petroleum Geology
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    • v.2 no.2 s.3
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    • pp.83-90
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    • 1994
  • Thermal maturation and diagenesis of the Gyeongsang Supergroup in the Euiseong area are studied by means of organic geochemical techniques and illite crystallinity. Black mudrocks of the Singdong Group contain organic matter of $0.5{\~}2{\%}$ derived from higher plants, being compared to type Ⅲ. Thermal maturity of organic matter reached dry gas generation phase. Tmax by Rock Eval pyrolysis varies between $578^{\circ}C$ and $593^{\circ}C$ regardless of stratigraphic position and localities, and vitrinite reflectance is about 2.9 and $3{\~}4{\%}Ro$ in the Jinju and the Nagdong Formations, respectively. Vitrinite reflectance measurements indicate that the maturation is mainly due to burial and partly to be affected by post-depositional intrusions. Illite crystallinity values from the Nagdong, Hasandong, Jiniu Formations and part of the Iljig Formation are plotted around the boundary between diagenesis and anchizone, indicating dry gas generation stage. However, the values are not dependent on stratigraphic position. The values from the Iljig, Hupyeongdong, Geomgog, and Sagog Formations fall into the range of anchizone, probably resulted from the post-depositional intrusions which occur locally. Both organic geochemical and illite crystallinity data indicate thermal maturation stage of dry gas generation. Diagenesis of the Gyeongsang strata is mostly controlled by burial, and partly affected by post-depositional intrusions. Paleotemperature of the Sindong Group is estimated at around $200^{\circ}C$ on the basis of illite crystallinity.

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Ru and $RuO_2$ Thin Films Grown by Atomic Layer Deposition

  • Shin, Woong-Chul;Choi, Kyu-Jeong;Jung, Hyun-June;Yoon, Soon-Gil;Kim, Soo-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.149-149
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    • 2008
  • Metal-Insulator-Metal(MIM) capacitors have been studied extensively for next generation of high-density dynamic random access memory (DRAM) devices. Of several candidates for metal electrodes, Ru or its conducting oxide $RuO_2$ is the most promising material due to process maturity, feasibility, and reliability. ALD can be used to form the Ru and RuO2 electrode because of its inherent ability to achieve high level of conformality and step coverage. Moreover, it enables precise control of film thickness at atomic dimensions as a result of self-limited surface reactions. Recently, ALD processes for Ru and $RuO_2$, including plasma-enhanced ALD, have been studied for various semiconductor applications, such as gate metal electrodes, Cu interconnections, and capacitor electrodes. We investigated Ru/$RuO_2$ thin films by thermal ALD with various deposition parameters such as deposition temperature, oxygen flow rate, and source pulse time. Ru and $RuO_2$ thin films were grown by ALD(Lucida D150, NCD Co.) using RuDi as precursor and O2 gas as a reactant at $200\sim350^{\circ}C$.

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Geochemistry of Shallow gases taken from the core sediments in the southeastern Ulleung Basin (울릉분지 남동부 시추 퇴적물 내에 함유되어 있는 천부가스의 특성)

  • Lee Young joo;Huh Shik;Kwak Young hoon;Kim Hag ju;Chun Jong Hwa;Jun Sang Joon;Yoo Hai Soo
    • The Korean Journal of Petroleum Geology
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    • v.7 no.1_2 s.8
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    • pp.35-40
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    • 1999
  • Chemical and isotopic compositions of hydrocarbon gases were analyBed to characterize the properties of the shallow gases distributed in the southeastern part of the Ulleung Basin, offshore Korea. Sediments from the core were also analyzed to determine the characteristics and relationship to shallow gases. Hydrocarbon gases in the sediments consisted of methane (697.9-6054.4 ppm), ethane, propane, butane and hexane. The total carbon content of the sediments ranges from 1.84fe to $5.11{\%}$ and the total organic carbon content ranges from $0.29{\%} \;to\; 2.65{\%}$. High C/N ratio (>10) indicates that input of terrestrial organic matter was prevalent at the time of deposition. The methane content and stable isotopic data indicate that hydrocarbon gases from the sediments are identified to be thermogenic gas and mixture of both biogenic and thermal gases. Based on the Rock-Eval and carbon isotopic data, the level of thermal maturity of organic matter in the sediments $(Tmax<425^{\circ}C)$ is lower than that of gas. It suggests that thermal gases in the sediments migrated from the deeper sediments than the penetrated depth.

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Comparison of the Chicken Large Intestine to the Large Intestine of Pigs and the Rumen of Cows (닭의 대장을 돼지의 대장이나 소의 제 1위 (Rumen)와 비교 연구)

  • Nahm K.H.
    • Korean Journal of Poultry Science
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    • v.33 no.1
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    • pp.81-95
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    • 2006
  • The large intestine of the chicken differs both anatomically and physiologically from the pig's large intestine and the men of the cow. The chicken's large intestine is less developed than the pig's large intestine or the cow's lumen. This paper summaries these differences. The chicken's large intestine contains a microbiological population similar to that found in the rumen. The chicken's caeca especially contains a large number of microorganisms, but this population varies according to age, fred, maturity, antibiotic use and etc.. Protein is an essential nutrient for the formation of intestinal microvilli. A study showed that the length of the small intestine was 63 % of the total gastrointestinal tract (GIT) length, while caecum was 8.1 %, and the colon and rectum were 4.6 %. The establishment of the microbial population of the small intestine occurs earlier than that of the caeca, but the identity of approximately 90 % of microbial population of the chicken GIT is hon. Recent studies have shown that energy, volatile fatty acid (VFA) and electrolytes that are found in the large intestine may be absorbed to a certain degree. The chicken small intestine is the primary location for digestion with a variety of enzymes being secreted here. Much research is being conducted into the digestion of sucrose thermal oligosaccharide caramel (STOP), fructooligosaccharides (FOS), mannanoligosaccharide (MOS), galactooligosaccharides (GOS) and isomalto-oligosaccharides (IMO) in the chicken caeca and large intestine. Excessive fibre content in the feed has detrimental effects, but proper fibre supplementation to chicken diets can improve the length and capacity of the small intestine.