• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.77-77
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• 2016

Thin films synthesized by plasma processes have been widely applied in a variety of industrial sectors. The structure control of thin film is one of prime factor in most of these applications. It is well known that the structure of this film is closely associated with plasma parameters and species of plasma which are electrons, ions, radical and neutrals in plasma processes. However the precise control of structure by plasma process is still limited due to inherent complexity, reproducibility and control problems in practical implementation of plasma processing. Therefore the study on the fundamental physical properties that govern the plasmas becomes more crucial for molecular scale control of film structure and corresponding properties for new generation nano scale film materials development and application. The thin films are formed through nucleation and growth stages during thin film depostion. Such stages involve adsorption, surface diffusion, chemical binding and other atomic processes at surfaces. This requires identification, determination and quantification of the surface activity of the species in the plasma. Specifically, the ions and neutrals have kinetic energies ranging from ~ thermal up to tens of eV, which are generated by electron impact of the polyatomic precursor, gas phase reaction, and interactions with the substrate and reactor walls. The present work highlights these aspects for the controlled and low-temperature plasma enhanced chemical vapour disposition (PECVD) of Si-based films like crystalline Si (c-Si), Si-quantum dot, and sputtered crystalline C by the design and control of radicals, plasmas and the deposition energy. Additionally, there is growing demand on the low-temperature deposition process with low hydrogen content by PECVD. The deposition temperature can be reduced significantly by utilizing alternative plasma concepts to lower the reaction activation energy. Evolution in this area continues and has recently produced solutions by increasing the plasma excitation frequency from radio frequency to ultra high frequency (UHF) and in the range of microwave. In this sense, the necessity of dedicated experimental studies, diagnostics and computer modelling of process plasmas to quantify the effect of the unique chemistry and structure of the growing film by radical and plasma control is realized. Different low-temperature PECVD processes using RF, UHF, and RF/UHF hybrid plasmas along with magnetron sputtering plasmas are investigated using numerous diagnostics and film analysis tools. The broad outlook of this work also outlines some of the 'Grand Scientific Challenges' to which significant contributions from plasma nanoscience-related research can be foreseen.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.3
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• pp.321-330
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• 2011

We experimentally investigated the effect of applied DC electric fields on the flame spread over polyethylene-coated electrical wire. The flame-spread rates over electrical wire with negative and positive DC electric fields from 0 to ${\pm}7$ kV were measured and analyzed. We compared the results for DC electric fields with previous results for AC electric fields. We explored whether or not various flame shapes could be obtained with DC electric fields and the main reason for the flame-spread acceleration, particularly at the end of the electrical wire, for AC electric fields. We found that DC electric fields do not significantly affect the flame-spread rates. However, the flame shape is mildly altered by the ionic wind effect even for DC electric fields. The flame-spread rate is relevant to the flame shape and the slanted direction in spite of the mild impact. A possible explanation for the flame spread is given by a thermal-balance mechanism and fuel-vapor jet.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.40 no.4
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• pp.423-428
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• 2016

The last stage blades of a low pressure (LP) turbine get frequently fractured because of stress corrosion cracking. This is because they operate in a severe corrosive environment that is caused by the impurities dissolved in condensed steam and high stress due to high speed rotation. To improve the reliability of the blades under severe conditions, 12% Cr martensitic stainless steel, having excellent corrosion resistance and higher strength, is widely used as the blade material. This paper shows the result of root cause analysis on a blade which got fractured suddenly during normal operation. Testing of mechanical properties and microstructure examination were performed on the fractured blade and on a blade in sound condition. The results of testing of mechanical properties of the fractured blade showed that the hardness were higher but impact energy were lower, and were not meeting the criteria as per the material certificate specification. This result showed that the fractured blade became embrittled. The branch-type crack was found to have propagated through the grain boundary and components of chloride and sulfur were detected on the fractured surface. Based on these results, the root cause of fracture was confirmed to be stress corrosion cracking.

• Food Science of Animal Resources
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• v.33 no.5
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• pp.664-671
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• 2013

The objective of this study was to investigate the effect of high pressure treatment and type of binding agents on the quality characteristics of restructured pork. For binding agents, 2% (w/w) isolated soy protein (SP), 0.5% (w/w) wheat flour (WF) and 0.5% (w/w) ${\kappa}$-carrageenan (KC) were incorporated into meat batter with or without 0.5% (w/w) glucono-${\delta}$-lactone (GdL). The restructured pork was pressurized at varying pressure levels (0.1-450 MPa) for 3 min under ambient temperature and thermal treated at $75^{\circ}C$ for 30 min. As quality parameters of restructured pork, pH, water binding properties, instrumental color and texture profile analysis were determined and compared with control (C, no binder). For type of binders, SP exhibited the best water binding properties, however, the impact on textural properties were lesser than KC and WF. The addition of GdL decreased the pH of restructured pork down to 0.4 unit, while high pressure processing prevented the moisture loss caused from pH decrease by GdL. In particular, meat restructuring efficiency of SP as a binder improved under the presence of GdL. Therefore, the present study demonstrated the potential advantages of low amount of GdL (0.5%, w/w) combined with protein based binder (SP) and high pressure processing in restructuring meat particles.

• Environmental and Resource Economics Review
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• v.16 no.1
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• pp.27-63
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• 2007

Using the CGE model, this paper investigates economic impacts of a shortage in crude oil resulting from voluntary export restraints, OPEC's agreement of a cut in oil production, and/or a storing on speculation. Unlike most previous studies considering oil price as the unpredictable variable, this study constructs the model to determine the oil price endogenously under the condition of an insufficient supply of crude oil. According to IEA's extraordinary steps for a shortage of crude oil, we investigate an economic impact of 7~12% shortage below the level of business as usual. The results show that oil price soars by 17.3~33.5%, the rate of economic growth falls by 0.52~0.96%p, and the consumer price index(CPI) rises by 0.8~1.51%p. These results imply that increasing in 1%p of oil price results in decreasing in 0.03%p of economic growth and increasing in 0.045%p of consumer price index. The production of electricity declines because of the increase in production cost. A shortage of crude oil has an effect on sources of electricity. Most reduction in electricity generation occurs from the reduction in the thermal power generation which is highly dependent on crude oil. The shortage of crude oil causes demand for petroleum to significantly decline but demand for coal and heat to increase because of the substitution effect with petroleum. Demand for gas rise in the first year but falls from the second year.

• Polymer(Korea)
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• v.36 no.3
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• pp.251-261
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• 2012

The nanocomposites containing graphene oxide flakes were prepared in order to improve the mechanical properties of artificial marbles based on poly(methyl methacrylate)(PMMA) matrix. Graphene oxide flakes were prepared from graphite by oxidation with Hummers method followed by exfoliation with thermal treatment. Surface of graphene oxide flakes were modified with oxyfluorination in various oxygene:fluorine compositions to improve the interfacial compatibility. The nanocomposites containing graphenes modified with oxyfluorination in the oxygen content of 50% and higher showed the significant increase in flexural strength, flexural modulus, Rockwell hardness, Barcol hardness, and Izod impact strength. The morphology of fractured surface showed the improved interfacial adhesion between PMMA matrix and the graphenes which were properly treated with oxyfluorination. The mechanical properties of nanocomposite were deteriorated by increasing the content of graphene above 0.07 phr due to the nonuniform dispersion of graphenes.

• Journal of Korean Ophthalmic Optics Society
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• v.20 no.1
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• pp.1-7
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• 2015

Purpose: For optimizing properties of final glasses frame, the aim of this study is to examine the correlation of processing conditions and properties of cellulose acetate (CA) sheets through the investigation of properties of CA sheets prepared under processing steps. Methods: The properties of CA sheets were investigated in terms of different glasses frame processing conditions, bending process, barrel process, and ultrasonic cleaning process. CA sheets prepared through the sequential processing were examined by various analysis: gloss, mechanical properties, thermal properties. Results: After barrel process, hardness and tensile strength of CA sheet were increased. However, bending strength and impact strength were decreased. It is suggested the CA sheet had became rather stiff state (brittle). Also, in degradation temperature region of plasticizer, about 3% of reduction in plasticizer weight was confirmed upon TGA analysis. Conclusions: Glasses frame process, especially in the barrel process have a profound influence on the properties of CA sheet owing to reduction of total amount of plasticizer.

• Journal of Radiation Protection and Research
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• v.43 no.3
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• pp.120-123
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• 2018

Background: Analysis of enrichment of $UO_2$ is important to verify the information declared by the license-holders. The redundancy methods are required to guarantee the analysis result. Korea Institute of Nuclear Nonproliferation and Control (KINAC) used to analyze it with alpha spectrometry and consign to Korea Basic Science Institute (KBSI) Thermal Ionization Mass Spectrometry (TIMS). This article evaluated the similarity of the results with two methods and derive correlation equation. It could be compared to the results measured by TIMS running by KBSI. Materials and Methods: There are not many certified materials for the uranium enrichment value. Therefore, 34 uranium pellets, which have the wide range of uranium enrichment from 0.21 to 4.69 wt%, were used for the experiments by the alpha spectrometry and the TIMS. Results and Discussion: The study shows there are the tendency of analyzed enrichment by each equipment. It shows uranium enrichment with alpha spectrometry evaluated 17% higher than that with TIMS on average. The regression equations were also derived in case the similarity between the two results with two methods is lower than predicted. Two experiments were designed to compare the effect of number of samples. The $R^2$ was 0.9977 with 34 pellets. It shows the equation is appropriate to predict the enrichment values by TIMS with that of alpha spectrometry. The $R^2$ was 0.9858 with four pellets for ten times. The $R^2$ decreased while the number of samples increased. The discrepancy between the lowest and highest enrichment seems to be one of the reason for it. Conclusion: KINAC expects the first equation with 34 samples is useful to predict the result with TIMS, the redundancy method, based on the alpha spectrometry. The extra samples are necessary to collect if the enrichment value analyzed by TIMS is lower than the value predicted with the equation. Further study would be followed related to the impact of the peak counts for each uranium isotopes, sample amount and number of experiments when TIMS established in KINAC by the end of 2018.

• Applied Chemistry for Engineering
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• v.23 no.4
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• pp.372-376
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• 2012

Carbon nanotubes (CNT) are considered as one of ideal nano-fillers in the field of composites with their excellent electrical, mechanical, and thermal properties. Therefore CNT composites are increasingly used in fabricating conductive materials, structural materials with high strength and low weight, and multifunctional materials. The main problem of the CNT composites is difficulty in the dispersion of CNT in the polymer matrix. In this study multi-walled carbon nanotubes (MWNT) were pretreated by the physical process utilizing a wrapping method. After the pretreatment polymer/MWNT nanocomposites were prepared by melt processing. The effect of functionalization MWNT by wrapping with styrene acrylonitrile (SAN) on the mechanical and electrical properties of acrylonitrile butadiene styrene resin (ABS)/MWNT composites was studied by comparing the properties of ABS mixed with the neat MWNT. Electrical and mechanical properties of ABS/MWNT nanocomposites were studied as a function of the functionalization and content of MWNT. The tensile strength of the ABS/MWNT nanocomposites increased, but the impact strength decreased. The polymer wrapping in ABS system has little effect on the improvement of electrical properties.

• Journal of Bio-Environment Control
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• v.29 no.3
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• pp.285-292
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• 2020

Because the inner environment of greenhouse has a direct impact on crop production, many studies have been performed to develop technologies for controlling the environment in the greenhouse. However, it is difficult to apply the technology developed to all greenhouses because those studies were conducted through empirical experiments in specific greenhouses. It takes a lot of time and cost to develop the models that can be applicable to all greenhouse in real situation. Therefore studies are underway to solve this problem using computer-based simulation techniques. In this study, a model was developed to predict the inner environment of glass greenhouse using CFD simulation method. The developed model was validated using primary and secondary heating experiment and daytime greenhouse inner temperature data. As a result of comparing the measured and predicted value, the mean temperature and uniformity were 2.62℃ and 2.92%p higher in the predicted value, respectively. R² was 0.9628, confirming that the measured and the predicted values showed similar tendency. In the future, the model needs to improve by applying the shape of the greenhouse and the position of the inner heat exchanger for efficient thermal energy management of the greenhouse.