• Title/Summary/Keyword: thermal ignition theory

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A Study on Spontaneous Ignition of Hydroxy Propyl Methyl Cellulose (Hydroxy Propyl Methyl Cellulose의 자연발화에 관한 연구)

  • 최재욱;목연수;하동명
    • Fire Science and Engineering
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    • v.15 no.4
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    • pp.34-40
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    • 2001
  • The spontaneous ignition of hydroxypropyl methyl cellulose(HPMC) was investigated at constant ambient temperature in the oven and minimum ignition temperature of dust clouds with Godbret-Creenwald Furnace respectively, In the experiments of the vessel filled with sample. the larger the vessel was the lower the spontaneous ignition temperature and ambient temperature was calculated from the Frank-Kamenetskii thermal ignition theory. The minimum ignition temperature for the dust cloud state was found under 21% oxygen concentration. At the experiment with the change of oxygen concentration, HPMC was not ignite at 10% $O_2$and so the limiting oxygen concentration was obtained at 10%.

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Relationship Between the Minimum Ignition Energy(MIE) and the Temperature (최소발화에너지와 온도의 관계)

  • 하동명
    • Fire Science and Engineering
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    • v.11 no.2
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    • pp.3-10
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    • 1997
  • Attempts are being made to investigate temperatures dependence of minimum ignition energy (MIE) based on concept of quantity of heat and thermal ignition theory. Regression equations for predicting MIE by means of temperature variations on the basis of statistical and mathematical methods are proposed. This study is undertaken to learn what proposed method is satisfactory hydrocarbons(propane and pentane). The proposed method has been tested and compared sucessfully with previously reported data in various journal.

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A Study on Pressure Dependence of Minimum Ignition Energy (최소발화에너지의 압력의존성에 관한 연구)

  • Ha Dong-Myeong;Lee Su-Kyung
    • Journal of the Korean Institute of Gas
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    • v.1 no.1
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    • pp.7-13
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    • 1997
  • To investigate the pressure dependence of minimum ignition energy(MIE), thermal ignition theory, concept of heat transfer, ideal gas law, and kinetic theory are discussed. Correlation equations for the MIE and pressure were obtained through a regression analysis of reported data. In the proposed methodology the predicted MIE with pressure variations agree with reported data within a few average absolute deviations(A.A.D.). Therefore the proposed methodology has provided to be the general method for predicting the MIE of hydrocarbons.

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A Study on Spontaneous Ignition of Painting Waste (도장 폐기물의 자연발화에 관한 연구)

  • 최재욱;목연수;옥곤;사공성호
    • Journal of the Korean Society of Safety
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    • v.14 no.2
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    • pp.90-96
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    • 1999
  • The characteristics of spontaneous ignition of painting waste was investigated at constant ambient temperature in oven. As the results of experiments, the spontaneous ignition temperature decreased as the sample vessel became large, and the spontaneous ignition temperature of the sample in small, intermediate and large vessels was $165.5^{\circ}C$, $144.5^{\circ}C$ and $134.5^{\circ}C$ respectively. The apparent activation energy calculated by the Frank-Kamentskii's thermal ignition theory was 34.73 kcal/mol.

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A Study on Char Oxidation Kinetics by Direct Measurement of Coal Ignition Temperature (석탄점화온도의 직접적인 측정에 의한 촤산화 반응율 도출에 대한 연구)

  • Kwon, Jong-Seo;Kim, Ryang-Gyoon;Song, Ju-Hun;Chang, Young-June;Jeon, Chung-Hwan
    • Journal of Energy Engineering
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    • v.20 no.4
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    • pp.346-352
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    • 2011
  • The experiment was designed to study the char oxidation kinetics of pulverized coals commonly utilized in Korean power plants. The kinetics has been estimated using the Semenov's thermal spontaneous ignition theory adapted to coal char particle ignition temperature. The ignition temperature of coal char particle is obtained by a direct measurement of the particle temperature with photo detector as well as by means of a solid thermocouple which is used as both a heating and a measuring element. The ignition temperatures for subbituminous coal, Wira, and bituminous coal, Yakutugol, have been measured for 4 sizes in the range of 0.52-1.09 mm. The ignition temperature of the particle increases with the increasing diameter. The results were used to calculate the activation energy and the pre-exponential factor. As a result, the kinetic parameters are in an agreement with ones reported from other investigations.

Prediction of Development Process of the Spherical Flame Kernel (구형 화염핵 발달과정의 예측)

  • 한성빈;이성열
    • Transactions of the Korean Society of Automotive Engineers
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    • v.1 no.1
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    • pp.59-65
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    • 1993
  • In a spark ignition engine, in order to make research on flame propagation, attentive concentration should be paid on initial combustion stage about the formation and development of flame. In addition, the initial stage of combustion governs overall combustion period in a spark ignition engine. With the increase of the size of flame kernel, it could reach initial flame stage easily, and the mixture could proceed to the combustion of stabilized state. Therefore, we must study the theoretical calculation of minimum flame kernel radius which effects on the formation and development of kernel. To calculate the minimum flame kernel radius, we must know the thermal conductivity, flame temperature, laminar burning velocity and etc. The thermal conductivity is derived from the molecular kinetic theory, the flame temperature from the chemical reaction equations and the laminar burning velocity from the D.K.Kuehl's formula. In order to estimate the correctness of the theoretically calculated minimum flame kernel radius, the researcheres compared it with the RMaly's experimental values.

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A Study on Autoignition of Granulated Activated Carbon with Change of Ambient Temperature (주위온도 변화에 따른 입상활성탄의 자연발화에 관한 연구)

  • 목연수;최재욱
    • Journal of the Korean Society of Safety
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    • v.7 no.4
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    • pp.45-53
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    • 1992
  • Sponataneous ignition characteristics for granulated activated carbon were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 5$^{\circ}C$, 1$0^{\circ}C$ and 15$^{\circ}C$ respectively, and the period in each amplitude was varied at an interval of 30minutes from zero to 3hours. As the results of experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample decreased as the sample vessel size increased. Apparent activation energy of the sample calculated from the Frank-Kamenetskii's thermal Ignition theory was 38.82[kca1/mo1] In case of varying the ambient temperature sinusoidally, the critical spontaneous ignition tempera-ture was lower than that at the constant ambient temperature, and the minimum critical spontaneous ignition temperature decreased with the amplitude of heating sinusoidal curve. At the same amplitude, the critical spontaneous ignition temperature decreased until it reached the minimum point and then in-creased as the period increased.

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A Study on Spontaneous Ignition of Granulated Activated Carbon (입상활성탄의 자연발화에 관한 연구(I))

  • 목연수;최재욱;김상렬;최광재
    • Journal of the Korean Society of Safety
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    • v.6 no.4
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    • pp.66-72
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    • 1991
  • Spontaneous ignition characteristics were observed by performing experiments for granulated activated carbon at constant ambient temperature in an oven. As the results of the experiments, the critical spontaneous ignition temperature of sample for large, intermediate and small vessels was 158.5$^{\circ}C$ , 165.5$^{\circ}C$ and 174.5$^{\circ}C$, respectively. It was found that the critical spontaneous ignition temperature decreased and the ignition induction time increased as the sample vessel size increased. Apparent activation energy of the sample calculated from the Frank= kamenetskii's thermal ignition theory was 17.81*10$^3$J/mol.

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A Study on Autoignition of Fish Meal with Change of Ambient Temperature (주위온도 변화에 따른 어분의 자연발화에 관한연구)

  • 목연수;최재욱
    • Journal of the Korean Society of Safety
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    • v.7 no.1
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    • pp.47-56
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    • 1992
  • Spontaneous ignition charactenstics for fish meal were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. As the results of the experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample for large, intermediate and small vessels was 170.5$^{\circ}C$, 177.5$^{\circ}C$ and 188.5$^{\circ}C$, respectively. The critical spontaneous ignition temperature decreased as the sample vessel size increased. Apparent activation energy of used fish meal calculated from the Frank-Kamenetskii's thermal ignition theory was 37.60Kcal/mol. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 1$0^{\circ}C$, 2$0^{\circ}C$ and 3$0^{\circ}C$ respectively with the period in each amplitude 1hr, 2hrs and 3hrs. The results showed that the critical spontaneous ignition temperatures at the varied amplitudes of temperature were lower than that at the constant anbient temperature and increased as the amplitude increased. At the same amplitude, the critical spontaneous ignition temperature increased with the period.

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Research about Thermoacoustic Resonance Ignition (열음향 공진 점화에 대한 연구)

  • Seo, Seonghyeon;Kang, Sang Hun;Bae, Jong Yeol;Lee, Jin Young
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.1
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    • pp.82-89
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    • 2016
  • The unique phenomenon that jet flow kinetic energy is converted to thermal energy through thermoacoustic resonance can be applied for the multiple ignition of liquid rocket engines. The present article includes the basic principle and theory behind the phenomenon as well as major outstanding, previous research works. The thermoacoustic phenomenon is affected by underexpanded jet flow characteristics from a nozzle, geometries of a nozzle and a resonance tube, and chemical composition of jet flow. The paper concludes with discussion what should be considered as crucial issues for the future research on the development of a multiple ignition system of liquid rocket engines.