• 한국재료학회지
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• 제9권1호
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• pp.35-41
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• 1999

In this study we investigated the effects of process variables on the bond strength, and its dependency upon the interfacial chemistry when the joined $ZrO_2$ toughened $Na\beta$"-alumina to $\alpha$-alumina using B$_2$$O_3$-$SiO_2$-Al$_2$$O_3$-CaO glass sealant. We observed that bond strength is mainly determined by the strength of the glass, which, in turn, depends on the glass composition established after joining reaction. Joining at $950^{\circ}C$ for 15min yielded the highest average bond strength of 66MPa. Different types of interfacial reaction seem to occur at each interface. After joining at $950^{\circ}C$ for 15min we found that Ca and Si diffuse much deeper(~15$\mu\textrm{m}$) into the $\beta$"-alumina composite than into the $\alpha$-alumina(<1$\mu\textrm{m}$) as a result of ion exchange reaction and more effective grain boundary diffusion. Thermal expansion coefficient of the glass was found to have changed more closely to those of the $\beta$"-alumina composite and $\alpha$-alumina, which put the glass under a slight compressive stress.ressive stress.

• 한국환경과학회지
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• 제26권4호
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• pp.467-481
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• 2017

This study sought to determine the changes in weather conditions in urban streets, along with conditions of traffic and roads in urban areas. The variations in weather conditions depending on traffic differed according to distance. First, the temperature difference measured by traffic results is as follows: T1 point $1.03^{\circ}C$, T2 point $1.04^{\circ}C$, T3 point $0.9^{\circ}C$, T4 point $1.01^{\circ}C$, and T5 point $0.31^{\circ}C$. The average difference between the measured temperatures by the point of measurement was $0.86^{\circ}C$. The changes in wind velocity according to traffic volume results of the measurements is T1 point 1.32 m/s, T2 point 0.80 m/s, T3 point 0.29 m/s, T4 point 0.04 m/s, and T5 point 0.09 m/s. The difference between the average wind speeds was 0.51 m/s and traffic jams caused substantial differences in distance. The relative humidity tended to be inversely proportional to temperature. The measurements results ares T1 point 2.29%, T2 point 2.67%, T3 point 2.47%, T4 point 2.16%, and T5 point 0.91% The difference between the average relative humidity was 7.3%. In case of independent sampling T test according to traffic volume, changes in wind velocity and temperature were directly proportional to the level of statistical significance(p<0.01). On the other hand, relative humidity tended to be inversely proportional; however, there was no statistical significance.

• 한국항공우주학회지
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• 제41권8호
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• pp.597-604
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• 2013

본 논문에서는 열분해 및 삭마 환경의 복합재 구조물에 대한 열기계적 연계 해석을 수행하였다. 열분해 과정의 재료 밀도 감소, 기공 가스 확산, 흡열 반응 에너지와 삭마 과정에서의 표면 침식 효과 등을 고려하였다. 상용 유한요소 코드에 교차 연계 알고리듬을 적용하여 완전 연계된 열 해석 및 구조 해석 인터페이스를 구성하였다. 수치 실험을 통해서 탄소/페놀릭 복합재료의 기본적인 열분해 및 삭마 특성을 분석하였다. 특히, 화학적 및 기계적 삭마에 영향을 미치는 주요 인자에 따른 표면 침식량 등을 비교하였다. 또한, 열분해 과정의 수축 또는 팽창 변형도가 재료의 열기계적 거동에 미치는 영향도 검토하였다.

• Journal of Advanced Marine Engineering and Technology
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• 제35권5호
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• pp.616-624
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• 2011

본 연구에서는 사각채널내에 주유속 방향에 가로지르게 배치된 반원 리브의 난류 유동에 대한 유동 특성과 열전달 증대에 관해 수치해석적으로 살펴보았다. 사각채널의 종횡비는 5이고, 수력직경 대비 리브 높이비는 0.07, 사각채널 높이 대비 리브 높이비는 0.117로서 리브 높이 대비 리브 피치비가 8~14인 리브를 주기적으로 배열하여 연구를 수행하였다. 난류 모델의 선정은 실제 현상과 근접한 벽 근처 유동 특성과 열전달을 위해 SST k-${\omega}$ 난류 모델과 v2-f 난류 모델을 이용하였다. 수치해석의 결과는 실험에 의 해 관찰된 난류 유동 특성, 열전달 및 마찰계수의 결과를 잘 예측함을 보여준다. 본 결과에서 난류 운동 에너지가 재순환류 영역의 확산과 밀접한 관련이 있음을 알 수 있고 v2-f 난류 모델이 SST k-${\omega}$ 난류 모델에 비해 실험결과를 더 잘 예측하였다.

• 한국의류학회지
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• 제41권1호
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• pp.131-140
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• 2017

Uniform nanofibers of polyurethane with different content of Juniperus Chinensis extracts (JCE) were successfully prepared by the electrospinning method. We investigated physiochemical properties of prepared compound nanoweb according to various concentrations of Juniperus Chinensis extracts using a Fourier transform infrared (FT-IR) spectrometer, X-ray diffractometer (XRD), thermogravimeter (TGA), and differential scanning calorimeter (DSC). The antibacterial activity of the JCE loaded PU nanofiber was conducted using the disk diffusion test against Gram-positive and Gram-negative bacteria. JCE was induced in the infrared spectra in the absorption band of PU/JCE nanowebs at $3,300cm^{-1}$, $2,960cm^{-1}$, $1,400-1,600cm^{-1}$, and $1,050cm^{-1}$. Thermal stability decreased with increasing JCE content in the PU/JCE nanowebs. The DSC curve of the PU nanoweb shows an endotherm peak at $420^{\circ}C$; in addition, the peak also became smaller and broader with increasing JCE content. The diffraction intensities of PU observed at 2 theta of $20^{\circ}$ decreased with the increasing amount of JCE in the compound nanoweb. In addition, the crystal intensities of the compound nanowebs also decreased along with the JCE content. Structural analysis indicates that JCE and PU are miscible. Juniperus Chinensis incorporated PU nanofibers demonstrated excellent antibacterial properties against both Gram-positive and Gram-negative bacteria.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 1997년도 추계학술강연 및 발표대회 강연 및 발표논문 초록집
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• pp.7-7
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• 1997

During sintering of very porous green bodies, as obtained by compaction of hard powders - such as tungsten carbide or ceramics - or by injection moulding, important shrinkage occurs. Due to heterogeneous green density field, gravity effects, friction on the support, thermal gradients, etc., this shrinkage is often non-uniform, which' may induce significant shape changes. As the ratio of compact dimension to powder size is very high, the mechanics of continuum is relevant to model such phenomena. Thus numerical techniques, such as the finite element method can be used to simulate the sintering process and predict the final shape of the sintered part. Such type of simulation has much been developed in the last decade firstly for hot isostatic pressing and next for die compaction. Finite element modelling has been recently applied to free sintering. The simulation of sintering should be based on constitutive equations describing the thermo-mechanical behaviour of the material under any state of stress and any temperature which may arise within the sintering body. These equations can be drawn either from experimental data or from micromechanical models. The experiments usually consist in free sintering and sinter-forging tests. Indeed applying more complex loading conditions at high temperature under controlled atmosphere is delicate. Micromechanical models describe the constitutive behaviour of aggregates of spheres from the deformation of two-sphere contact either by viscous flow or grain boundary diffusion. Such models are not able to describe complex microstructure and mechanisms as observed in real materials but they can give some basic information on the formulation of constitutive equations. Practically both experimental and theoretical approaches can be coupled to identify the constitutive equations. Such procedure has been performed for modelling the sintering of compacts obtained by die pressing of a mixture of tungsten carbide and cobalt powders. The constitutive behaviour of this material during sintering has been described by a linear viscous constitutive model, whose functions have been fitted from results of free sintering and sinter-forging experiments. This model has next been introduced in ABAQUS finite element code to simulate the sintering of heterogeneous green compacts of various geometries at constant temperature. Examples of simulations are shown and compared with experiments.

• Journal of Pharmaceutical Investigation
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• 제28권3호
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• pp.177-183
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• 1998

Low toxicity, reverse thermal gelation and high drug loading capabilities suggest that poloxamer 407 gels have great potential as a topical drug delivery system. Kojic acid (KA) is an antimelanogenic agent which has been widely used in cosmetics to whiten the skin color. However, it has the drawbacks of skin irritancy due to its acidic pH. Poloxamer gels of different polymer contents were formulated to overcome the problem and compared to the cream type formulations of either w/o/w multiple emulsion cream or o/w type emulsion cream. Using Franz diffusion cells mounted with a synthetic cellulose membrane (MWCO 12,000), drug release characteristics of the formulations were evaluated by the HPLC assay of KA concentration in the receptor compartment of pH 7.4 phosphate buffered saline solutions. Drug release from w/o/w multiple emulsion cream was controlled by oil membrane, showing the apparent zero order release kinetics. The KA release from the poloxamer gels was also controlled by the gel matrix, showing that drug release increased linearly as KA contents increase, but decreased exponentially as the polymer contents increase. In the skin irritancy test, the primary irritancy index(PII) of poloxamer gel base was lower than those of multiple emulsion cream base and o/w cream. Depending on KA contents or polymer contents in the gel. PH values in poloxamer gels were ranged from 1.3 to 2.0, which are interpreted as low or negligible irritation on skin. There was a good correlation between the log value of flux in drug release and PII value in skin irritation. It was possible to conclude that the poloxamer gels containing KA might be a good candidate for an antimelanogenic topical delivery system by virtue of the controlled release of the drug and the reduced skin irritancy.

• Transactions on Electrical and Electronic Materials
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• 제4권3호
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• pp.34-37
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• 2003

[ $HfO_2$ ] and $HfO_xN_y$ films were deposited by plasma-enhanced chemical vapor deposition using $Hf[OC(CH_3)_3]_4$ as the precursor in the absence of $O_2$. The crystallization temperature of the $HfO_xN_y$ films is higher than that of the $HfO_2$ film. Nitrogen incorporation in $HfO_xN_y$ was confirmed by auger electron spectroscopy analysis. After post deposition annealing (PDA) at 800$\Box$, the EOT increased from 1.34 to 1.6 nm in the $HfO_2$ thin films, whereas the increase of EOT was suppressed to less than 0.02 nm in the $HfO_xN_y$. The leakage current density decreased from 0.18 to 0.012 $A/cm^2$ with increasing PDA temperature in the $HfO_2$ films. But the leakage current density of $HfO_xN_y$ does not vary with increasing PDA temperature because an amorphous $HfO_xN_y$ films suppresses the diffusion of oxygen through the gate dielectric.

• 전자공학회논문지A
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• 제31A권10호
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• pp.87-93
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• 1994

Ohmic contacts between Au and p-HgHg_{0.7}Cd_{0.3}Te$ with low specific contact resistance have been obtained. The contact region of the wafer is first pre-heated for 5 seconds in a rapid thermal processing equipment. The temperature reaches a maximum value of about 200$^{\circ}C$ at the end of the 5 seconds. Next, a thin Au film is formed on the contact region by immersing the sample in AuCl$_{3}$ solution. the sample is then post-annealed in the same condition as the pre-heating after Pb/In pad metals are deposited on the electroless Au contacts. The specific contact resistance measured by transmission line model is 5${\times}10^{-3}{\Omega}cm^{2}$ at 80K. RBS and differential Hall measurement data suggest that the above low resistance ohmic contact is ascribed to surface traps and increased gold diffusion rate.

• 한국추진공학회지
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• 제21권5호
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• pp.1-9
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• 2017

초임계 환경에서 와류형 분사기의 극저온 질소 분무 동적 특성 분석을 위하여 3차원 LES 난류 모델을 적용하였다. 초임계 상태에서 질소의 상태량들을 정확하게 예측하기 위해 SRK 실기체 상태방정식을 사용하였고, 점성계수와 열전도도는 Chung의 고압 상태 혼합물에 대한 방정식, 그리고 확산 계수는 Fuller의 이론에 Takahashi의 보정식을 적용하였다. 질소 분무 결과, 분사기 내, 외부에서 유동장과 음향장 사이의 상호작용으로 복잡한 유동구조가 형성된다. 복잡한 유동 현상을 분석하기 위해 FFT, POD 그리고 DMD 기법을 적용하여 해석을 수행하였다. FFT 해석을 수행하여 분사기 내, 외부에서 나타나는 특정 주파수를 파악하였으며, POD와 DMD를 통해 각 주파수가 어떠한 유동 구조를 갖는지에 대한 연구를 수행하였다. 또한, DMD를 통해 각 주파수의 감쇠 계수를 파악하여 이를 실험 결과와 비교하였다.