• Title/Summary/Keyword: thermal degradation temperature

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Study on the Microstructural Degradation of the Boiler Tubes for Coal-Fired Power Plants

  • Yoo, Keun-Bong;He, Yinsheng;Lee, Han-Sang;Bae, Si-Yeon;Kim, Doo-Soo
    • KEPCO Journal on Electric Power and Energy
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    • v.4 no.1
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    • pp.25-31
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    • 2018
  • A boiler system transforms water to pressured supercritical steam which drives the running of the turbine to rotate in the generator to produce electricity in power plants. Materials for building the tube system face challenges from high temperature creep damage, thermal fatigue/expansion, fireside and steam corrosion, etc. A database on the creep resistance strength and steam oxidation of the materials is important to the long-term reliable operation of the boiler system. Generally, the ferritic steels, i.e., grade 1, grade 2, grade 9, and X20, are extensively used as the superheater (SH) and reheater (RH) in supercritical (SC) and ultra supercritcal (USC) power plants. Currently, advanced austenitic steel, such as TP347H (FG), Super304H and HR3C, are beginning to replace the traditional ferritic steels as they allow an increase in steam temperature to meet the demands for increased plant efficiency. The purpose of this paper is to provide the state-of-the-art knowledge on boiler tube materials, including the strengthening, metallurgy, property/microstructural degradation, oxidation, and oxidation property improvement and then describe the modern microstructural characterization methods to assess and control the properties of these alloys. The paper covers the limited experience and experiment results with the alloys and presents important information on microstructural strengthening, degradation, and oxidation mechanisms.

Study on the Degradaion Behavior of Acrylonitrile Rubber(NBR) O-ring by Intermittent CSR and Time-Temperature Superposition Principle (간헐 압축응력완화 시험법과 시간-온도 중첩 이론을 이용한 NBR 오링의 노화 거동 분석 연구)

  • Lee, Jin Hyok;Bae, Jong Woo;Choi, Myung Chan;Yun, Yu Mi;Kim, Wonho;Park, Sung Han;Jo, Nam-Ju
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.46-51
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    • 2019
  • Intermittent CSR testing was used to investigate the degradation of a NBR O-ring, and also the prediction of its life-time. An intermittent CSR jig was designed taking into consideration the O-ring's environment under use. Degradation of O-rings by thermal aging was observed between $40^{\circ}C$ and $120^{\circ}C$. O-rings showed non-linear degradation behavior under $80^{\circ}C$. At 20% of failure condition, predicted life-times were 32.5 years by Arrhenius plot and 22.6 years by WLF plot.

A Comparative Study on the Characteristics of Accelerated aging at Low and High Temperatures of the Fluorocarbon Rubber Composites (불소 고무복합체의 저온과 고온촉진노화 특성에 대한 비교 연구)

  • Park, JeongBae;Lee, BeomCheol;Jeong, YoonSeok;Park, SungHan
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.915-922
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    • 2017
  • The study on the thermal and oil resistance rubber composite, 2016. [6] predicted the lifetime of Fluorocarbon Rubber by accelerating aging at high temperature ($150^{\circ}C$, $175^{\circ}C$, $200^{\circ}C$). general rubber products are likely to exhibit different properties depending on the degradation factors such as temperature, humidity, ozone, light, emulsion, mechanical and electrical stress. To solve these problems, We compared the rate of change about tensile strength, elongation rate, volume change rate, weight change rate, thickness change rate, thermal conductivity in low temperature promoting aging on the basis of predictive lifetime of high temperature promoting aging. As a result of the review, the required life expectancy was satisfied, but there was a slight difference in the rate of change between the high-temperature promoted aging life result and the low temperature promoted aging life result. The cause was a reduction in "tensile strength / elongation" and an increase in "volume / weight / thickness" caused by the main chain decomposition of fluorine rubber due to aging at high temperature promoting aging. However, the low temperature promoting aging was caused by the curing reaction of fluorine rubber at $80^{\circ}C$. The tensile strength / elongation and volume / weight / thickness changes were small.

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Improving the effectiveness of a photovoltaic system by cooling on the surface of photovoltaic cells (태양광발전 시스템 효율향상을 위한 셀 표면 냉각에 관한 연구)

  • Jin, Joo-Seok;Yu, Sang-Phil;Kim, Yi-Hyun;Jeong, Seong-Dae;Seo, Yong-Seog;Jeong, Nam-Jo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.183-186
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    • 2009
  • The crystalline silicon solar cell was one of the first to be developed and it is still the most widely used type. The photovoltaic cells will exhibit long-term degradation if the temperature exceed a certain limit. The purpose of this study is to investigate the possible of improving the performance of a photovoltaic cooling system. According to the results of the experiment, the thermal degradation of 44.63degrees was observed by cooling on the surface of photovoltaic cells. It is a decrease of 22.215percent of generating power. It is shown that photovoltaic cooling system is effected on improving the effectiveness of a photovoltaic out of power.

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A Study on the Electrical and Mechanical Properties of a Epoxy Powder for Compact Bus Duct (콤팩트 부스덕트용 에폭시분체도료의 전기적.기계적 특성연구)

  • Kim, Sang-Hyun;Choi, Jin-Wook;Kim, Dong-Wook;Kim, Hyun-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.3
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    • pp.210-217
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    • 2009
  • Insulated methods of compact bus duct has been applied a way of coating Epoxy powder. The problem which is caused by degradation during operation is very important in severe environment. Therefore, this study compared and verified many kind of properties ; electrical breakdown by thermal and water aging, v-t characteristic, arc discharge, mechanical properties, bending test and cross cut. Sample D was stable before the $T_g$ to be about $7{\sim}10 %$ decrease in the breakdown test according to temperature change. In case of V-t and arc discharge, it had been kept up suitable characteristic. Also, in case of electrical and mechanical characteristic, both sample D and A have excellent capacity.

A Study on the Life Assessment for Turbine Rotor by the In-field Electrochemical Method (터빈 수명평가를 위한 전기화학법의 현장적용에 관한 연구)

  • Chang, S.H.;Kim, J.H.;Song, G.W.;Yu, H.S.
    • Proceedings of the KSME Conference
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    • 2000.04a
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    • pp.13-18
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    • 2000
  • Nowadays, 60 percent of thermal power plants already have been operated over their own design life. These operations of old power plant over their design life have caused a fracture accident of degradation a loss of economic and human. Therefore, the new life assessment and prediction technology is necessary to improve the safety and reliability of high pressure and high temperature power plant facilities. In this paper, innovative electrochemical test method have been used and results have been compared to the conventional test. Finally, the electrochemical test is applied to the in-field HP turbine and a database is currently in progress for the development of the life assessment standard and procedure.

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Nondestructive Evaluation for Thermally Degraded Co-base Superalloy by Scanning Acoustic Microscope (초음파현미경을 이용한 Co 기 초내열 합금 열화재의 비파괴평가)

  • Kim, Chung-Seok;Song, Jin-Hun;Kwon, Sook-In;Lim, Jea-Seang;Park, Ik-Keun
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.336-341
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    • 2004
  • This research investigates the feasibility of ultrasonic microscope for nondestructive assessment of thermal degradation in artificially aged commercial Co-base superalloy, FSX414. This alloy has been used for high temperature structure applications such as stationary gas turbine blade and nozzle chamber in fossil plant. Microstructural change was found that the fine carbides became coarser and spheroidized in matrix as aging time increased. The leaky surface acoustic wave velocity gradually decreases by a maximum of 4.7% with increasing aging time up to 4,000hours. However, the longitudinal wave velocity has a little change. Also, it has a good correlation between leaky surface acoustic wave velocity and Vickers hardness. Consequently, LSAW can be used to examine the degree of degradation in thermally aged Co-base superalloy.

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The Improvements for Fire Retardancy and Radiation Resistance of Chloroprene Rubber (클로로프렌 고무의 난연성 및 내방사선 특성 향상)

  • Kim, Ki-Yup;Lee, Chung;Ryu, Boo-Hyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.11
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    • pp.1205-1211
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    • 2004
  • This study has investigated radiation degradation of chloroprene rubber in the presence of some fire retardant. Ammonium polyphosphate, aluminium trihydroxide, magnesium hydroxide, calcium carbonate and antimony trioxide were selected as flame retardant. Samples were irradiated using a Co$^{60}$ ${\gamma}$ -ray and ray up to 2000 kGy at a dose rate of 5 kGy/hr in the presence of air atmosphere at room temperature. After irradiation, samples were assessed fire retardancy with electrical properties and mechanical properties. Some considerations concerning the effects of the fire retardants added to chloroprene rubber on the radiation and thermal stability of chloroprene rubber are presented. From fire retardancy with electrical and mechanical property measurements, it was found that addition of magnesium hydroxide resulted in maximum fire retardant effect.

AC loss comparison of Bi-2223 and coated conductor HTS tapes under bending

  • Kim, Hae-Joon;Cho, Jeon-Wook;Sim, Ki-Deok;Kim, Jae-Ho;Kim, Seok-Ho;Jang, Hyun-Man;Lee, Soo-Gil
    • Progress in Superconductivity and Cryogenics
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    • v.9 no.4
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    • pp.41-45
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    • 2007
  • Superconductor is developed for applications in high-power devices such as power-transmission cables, transformers, motor and generators. In such applications, HTS tapes are subjected to various kinds of stress or strain. AC loss is also important consideration for many large-scale superconducting devices. In the fabrication of the devices, the critical current $(I_c)$ of the high temperature superconductor degrades due to many reasons including the tension applied by bending and thermal contraction. These bending or tension reduces the $I_c$ of superconducting wire and the $I_c$ degradation affects the AC loss of the wire. The $I_c$ degradation and AC loss (self field loss) of Bi-2223 HTS and Coated conductor were measured under tension and bending conditions at 77K and self-field.

Thermal Properties of Corn-Starch Filled Biodegradable Polymer Bio-Composites (옥수수 전분을 충전제로 첨가한 생분해성 고분자 복합재료의 열적성질)

  • Kim, Hee-Soo;Yang, Han-Seung;Kim, Hyun-Joong;Lee, Young-Kyu;Park, Hee-Jun
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.5
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    • pp.29-38
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    • 2004
  • In this study, we investigated the thermal properties of corn-starch filled polybutylene succinate-adipate (PBS-AD) bio-composites. Thermal analysis (TA) is used to describe the analytical method for measuring the chemical property and weight loss of composite materials as a function of temperature. The thermal stability of corn-starch was lower than that of pure PBS-AD. As corn-starch loading increased, the thermal stability and degradation temperature of the bio-composites decreased and the ash content increased. It can be seen that the degree of compatibility and interfacial adhesion of the bio-composites decreased because of the increasing mixing ratio of the corn-starch. As the content of corn-starch increased, there was no significant change in the glass transition temperature (Tg) and the melting temperature (Tm) for the bio-composites. The storage modulus (E') and loss modulus (E") of the corn-starch flour filled PBS-AD bio-composites were higher than those of PBS-AD, because of the incorporation of corn-starch increased the stiffness of the bio-composites. At higher temperatures, the decreased storage modulus (E') of bio-composites was due to the increased polymer chain mobility of the matrix polymer. From these results, we can expect that corn-starch has potential as a reinforcing filler for bio-composites. Furthermore, we recommend using a coupling agent to improve the interfacial adhesion between corn-starch and biodegradable polymer.