• 한국구조물진단유지관리공학회 논문집
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• 제17권4호
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• pp.91-100
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• 2013

이 연구에서는 기존아파트 외벽체의 단열 성능저하 및 보수보강에 필요한 기초 자료를 만들기 위해서 아파트의 구조체 단열성능 측정분석과 함께 단열하자에 대한 기준수립 및 평가를 하고자 한다. 또한 아파트 건축물 구조체의 열교 및 결로발생 부분을 예측하고자 하였다. 한편 시공연도별 분석에 의하여 단열기준 및 시간 경과에 따른 단열성능 정도를 분석하기 위함이다.

• 한국식품과학회지
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• 제34권2호
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• pp.238-243
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• 2002

자색고구마 anthocyanin 색소 용액은 가열에 의해 1차 반응속도식에 따라 색소 함량이 감소하였으며, 이 반응은 색소용액의 농도와 가열온도에 영향을 받았다. 이 반응의 활성화 에너지 값은 색소 용액의 농도에 따라 51.29-73.02 kJ/mol이었으며, 농축하지 않은 색소 추출액을 제외하면 활성화 에너지는 색소의 농도가 증가함에 따라 직선적으로 감소하였다. 자색고구마색소를 첨가한 매실음료의 anthocyanin 색소 역시 저장 중 1차 반응에 따라 색소가 감소하였는데, 저장온도가 낮아질수록 반응속도가 낮아져 저장기간이 증가하여, $5^{\circ}C$에서 저장한 경우는 저장 8개월까지 80%이상의 색소 잔존률을 나타냈다. 매실음료에 함유된 자색고구마 anthocyanin색소 변화에 대한 활성화 에너지는 75.80 kJ/mol이었다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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• pp.24-24
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• 2003

Research activity in the III-V nitrides materials system has increased markedly in the past several years ever since high-brightness blue light-emitting diodes (LEDs) became commercially available. Despite of excellent optical properties of the GaN, however, inherently poor thermal property of the sapphire used as a substrate material n these devices may lead to thermal degradation of devices, especially during their high power operation. Therefore, dependable thermal analysis and packaging schemes of GaN-based LEDs are necessary for solid lighting applications under high power operation. In this paper, emphasis will be placed upon thermal design of GaN-based LEDs. Thermal measurements of LEDs on chip and packaging scale were performed using the liquid crystal thermographic technology and micro thermocouples for different bias conditions. By a series of optical arrangement, hot spots with specific transition temperatures were obtained with increasing input power. Thermal design of LEDS was made using the finite element method and analytical unit temperature profile approach with optimal boundary conditions. The experimental results were compared to the simulated data and the results agree well enough for the establishment of dependable prediction of thermal behavior in these devices. The paper will present a more detailed understanding of the thermal analysis of the GaN-based blue and white LEDs for high power applications.

• Structural Engineering and Mechanics
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• 제50권6호
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• pp.755-772
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• 2014

A simplistic approach towards evaluation of complete load deflection response of Reinforced Concrete (RC) flexural members under post fire (residual) scenario is presented in this paper. The cross-section of the RC flexural member is divided into a number of sectors. Thermal analysis is performed to determine the temperature distribution across the section, for given fire duration. Temperature-dependent stress-strain curves for concrete and steel are then utilized to perform a moment-curvature analysis. The moment-curvature relationships are obtained for beams exposed to different fire durations. These are then utilized to obtain the load-deflection plots following pushover analysis. Moreover one of the important issues of modeling the initial stiffness giving due consideration to stiffness degradation due to material degradation and thermal cracking has also been addressed in a rational manner. The approach is straightforward and can be easily programmed in spreadsheets. The presented approach has been validated against the experiments, available in literature, on RC beam subjected to different fire durations viz. 1hr, 1.5hrs and 2hrs. Complete load-deflection curves have been obtained and compared with experimentally reported counterparts. The results also show a good match with the results obtained using more complicated approaches such as those involving Finite element (FE) modeling and conducting a transient thermal stress analysis. Further evaluation of the beams during fire (at elevated temperatures) was performed and a comparison of the mechanical behavior of RC beams under post fire and during fire scenarios is made. Detailed formulations, assumptions and step by step approach are reported in the paper. Due to the simplicity and ease of implementation, this approach can be used for evaluation of global performance of fire affected structures.

• Composites Research
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• 제22권5호
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• pp.37-42
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• 2009

온도, 수분 및 자외선과 같은 자연환경을 모사할 수 있는 가속노화시험장치를 적용하여 복합적인 환경인자에 노출된 탄소섬유/에폭시 복합재의 열분석 특성과 화학구조분석을 수행하였다. 복합적인 환경인자의 최대 노출시간은 3000시간으로 노출시간에 따른 복합재의 열분석 특성과 화학구조는 Modulated DSE와 FTIR을 통해 조사하였다. Modulated DSC 시험을 통한 연우-결과에 따르면 노출시간이 증가할수록 복합재 내에 치밀한 망사 구조가 형성되어 유리전이온도는 증가함을 알 수 있었다. 또한 노출시간이 증가할수록 복합재의 특성에 영향을 미치는 물리시효가 발생하여 엔탈피 완화현상을 나타내는 흡열 피크가 관찰되었다. 아울러 FTIR 시험을 통해 관찰된 피크의 위치는 노출시간에 큰 영향을 받지 않지만 피크의 세기는 노출시간이 증가할수록 에폭시기에 발생되는 경화 반응으로 인해 점차 감소함을 알 수 있었다.

• Korean Chemical Engineering Research
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• 제47권2호
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• pp.169-173
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• 2009

Dynamic DSC와 TGA를 이용하여 NR/CR 고무복합체의 가황시스템에 따른 가교화반응과 열화반응특성을 연구하였다. 주어진 샘플에 대하여 승온속도를 각각 달리하여 DSC 곡선을 얻었고, 가황반응이 끝난 같은 샘플을 이용하여 TGA에서도 같은 승온 속도의 실험으로 열분해 곡선을 얻은 다음, Kissinger의 해석 방법에 따라 가교 및 열화 반응의 활성화에너지를 구하고 서로 비교하였다. 실험에 사용된 NR/CR 고무복합재료는 대개 $120{\sim}180^{\circ}C$와 $350{\sim}450^{\circ}C$ 사이의 온도영역에서 각각 가교 반응과 열분해반응이 일어나는 것으로 관찰되었으며 Kissinger의 해석방법이 잘 적용될 수 있는 것으로 나타났다. 또한 DSC에 의한 생성 활성화에너지는 $83.0{\pm}5.0kJ/mol$로서 TGA에 의한 분해 활성화에너지인 $147.0{\pm}2.0kJ/mol$보다 매우 낮은 값을 나타내었다. 이러한 사실로부터 가황제/가황촉진제의 조성비 변화는 반응기구의 변화에는 크게 영향을 미치지 않지만 생성반응 시에는 샘플내의 저분자 화합물들과 함께 촉매역할을 하여 활성화에너지를 낮추는 역할을 하게 되는 반면, 반응이 끝난 후에는 더 이상 촉매로서 작용하지 못하게 되며 이에 따라 열분해활성화에너지는 주쇄의 분해반응에 의해 상대적으로 더 높게 나타내게 되는 것으로 생각할 수 있었다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.303-306
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• 2009

High temperature solid oxide fuel cells (SOFCs) offer a clean, pollution-free technology to electrochemically generate electricity at high efficiencies. Solid oxide fuel cells in several different designs have been investigated; these include planar and tubular geometries. The tubular type cell is widely researched due to it have advantages about thermal expansion and sealing issues. Unfortunately, lab scale tubular cell for testing has thermal expansion and sealing problems. The previous Jig for lab scale tubular cell testing has many sealing problems. When we feed fuel gas to jig inlet, ceramic glue sealant has amount of gas expansion pressure, because temperature of feeding gas changes ambient temperature to high temperature ($700{\sim}900^{\circ}C$). Furthermore, when we carry out long time test, something like degradation test, crack of ceramic glue sealant due to weakness of mechanical properties can make stop working the test. Additionally, we reduce setting process for assembling, because micanite is not required drying or debinding process.

• 대한기계학회논문집A
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• 제20권2호
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• pp.520-528
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• 1996

Four point bending tests of the brazed joint composed of sintered silicon nitride and 0.2% carbon steel with Cusil ABA filler which were fabricated at 86$0^{\circ}C$ were performed at temperatures, 25, 100, 200, 300, 400, 50$0^{\circ}C$ From the experiments, the maximum bending strength was measured at 30$0^{\circ}C$ From the 3D FE analysis of the residual stress of the brazed joint, it was revealed that the thermally induced residual stresses were minimized when the environmental temperature was 35$0^{\circ}C$ Considering the degradation of the filler material at high temperatures, it was calculated that the maximum bending strength of the brazed joint occured just below the temperature of the minimum thermal residual stress and the thermal residual stress was the dominative parameter of the brazed joint.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집A
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• pp.370-376
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• 2001

When an adhesive joint is exposed to high environmental temperature, the tensile load capability of the adhesive joint decreases because the elastic modulus and failure strength of structural adhesive decrease. The thermo-mechanical properties of structural adhesive can be improved by addition of fillers to the adhesive. In this paper, the elastic modulus and failure strength of adhesives as well as the tensile load capability of tubular single lap adhesive joints were experimentally and theoretically investigated with respect to the volume fraction of filler (alumina) and the environmental temperature. Also the tensile modulus of the fille containing epoxy adhesive was predicted using a new equation which considers filler shape, filler content and environmental temperature. The tensile load capability of the adhesive joint was predicted by using the effective strain obtained from the finite element analysis and a new failure model, from which the relation between the bonding length and the crack length was developed with respect to the volume fraction of filler.

• 한국수소및신에너지학회논문집
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• 제29권5호
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• pp.442-449
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• 2018

Research on High temperature polymer electrolyte fuel cell (HT-PEMFC) has actively been conducted all over the world. Since the HT-PEMFC can be operated at a high temperature of $120-180^{\circ}C$ using phosphoric acid-doped polybenzimidazole (PBI) electrolyte membrane, it has considerable advantages over conventional PEMFC in terms of operating conditions and system efficiency. However, If the thermal distribution is not uniform in the stack unit, degradation due to local reaction and deterioration of lifetime are difficult to prevent. The thin plate separator reduces the volume of the fuel cell stack and improves heat transfer, consequently, enhancing the cooling effect. In this paper, a large area flow field of thin plate separator for HT-PEMFC is designed and sub-stack is fabricated. We have studied stack performance evaluation under various operating conditions and it has been verified that the proposed design can achieve acceptable stack performance at a wide operating range.