• 제목/요약/키워드: thermal degradation temperature

검색결과 576건 처리시간 0.023초

열 열화에 의한 폴리에틸렌 테레프탈레이트 필름의 전기 특성에 관한 연구 (A Study on Electricity Properties of Polyethylene Terephthalate Film due to Thermally Degradation)

  • 이성일
    • 한국전기전자재료학회논문지
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    • 제30권11호
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    • pp.693-698
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    • 2017
  • In this study, the thermal degradation properties of polyethylene terephthalate film has been examined by the capacitance, Tan ${\delta}$, thermography, FTIR, and SEM results at temperatures of $90{\sim}170^{\circ}C$ and frequencies of 0.3~3,000 kHz. It was found that the capacitance decreased with increasing thermal imaging temperature, probably caused by weakening of chemical bond with increasing temperature. Tan ${\delta}$ decreased upon increasing temperature from $90^{\circ}C$ to $170^{\circ}C$, probably due to the molecular motion of COOH radical or OH radical. The FT-IR measurement reveals that no structural change of the material occurs upon thermal radiation. The SEM measurement shows that the material is stabilized by thermal decomposition with increasing temperature; however, excessive thermal degradation obstructs the stabilization of the material.

가속 열열화 시험에 의한 고정자 형권 코일의 절연특성에 관한 연구 (A Study on the Insulation Properties for Stator Form-wound Winding by Thermal Degradation Test)

  • 채승훈;김상걸;오현석;신철기;왕종배;김기준;이준웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.115-118
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    • 2000
  • In case of developing new motor, many examinations was tested to decide a motor efficiency and reliability. To give reliability judgment, traction motor winding insulation was tested by electrical method after appling electrical, heat, mechanical, environmental stress. In this study, stator form-wound winding of traction motor in urban transit E.M.U was tested by accelerative thermal degradation test. Stator form-wound winding was tested on the accelerative degradation composed of heat, vibration, moisture, overvoltage and researched insulation resistance, dielectric loss, partial discharge for insulation degradation properties, evaluated withstand voltage. Degradation temperature was $230[^\circ{C}]$, $250[^\circ{C}]$, $270[^\circ{C}]$, for stator form-wound winding respectively. On the test results of accelerative thermal degradation, insulation properties were relied all temperature until 10 times and expected life was evaluated by the rule of reducing $10[^\circ{C}]$ life into halves. Expected life was 31.8 years. It is guaranteed insulation reliability because of exceeding 25 years life times as considering.

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열열화된 PVC 케이블의 부분방전 진단 (Partial Discharge Diagnosis of Thermal Degradated PVC Cable)

  • 송기태;이성일
    • 한국전기전자재료학회논문지
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    • 제24권3호
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    • pp.208-214
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    • 2011
  • In this thesis, the partial discharge according to applied voltage and variations of cross-sectional area and length of the conductor related to general condition for using cable was measured in order to study degradation diagnosis for 2-Core cable of the PVC insulator used in industrial fields for other safety installations. Also the thermal degradation conditions under various installation circumstances of cables were studied by assuming degradation conditions with each different degradation rate (50%, 67%, 100%) such as variation in degradated temperature, thermal exposure time, normal state, partially degradated state and overall degradated state for thermal degradation diagnosis. The quantity of electric discharge (V-Q) according to applied voltage was measured for measurement of inception voltage and extinction voltage. The quantity of electric discharge and the number of electric discharge (Q-N) were measured with applied voltage kept constantly. In addition, pictures were taken using SEM (scanning electron microscope) to compare the surface of external insulator to degradated state of internal insulator according to thermal degradation temperature and also compare the surface of external insulator to degradated surface state of internal insulator according exposure time of cables to thermal stress.

배전용 ZnO 피뢰기 소자의 열적/전기적 파라미터 분석에 관한 연구 (A study on analysis of thermal and electrical parameters of the ZnO arrester block)

  • 이복희;이수봉;이승주;전병욱;김동성
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2007년도 춘계학술대회 논문집
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    • pp.353-356
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    • 2007
  • This paper presents the thermal and electrical characteristics of ZnO arrester blocks under the AC voltages. The leakage currents of ZnO arrester blocks were measured as a function of time. The temperature distributions of ZnO arrester blocks were observed by the forward looking infrared camera The degradation and thermal runaway of ZnO arrester blocks were closely related with the temperature limit of ZnO arrester blocks which decided heat generation and dissipation As a result, the degradation and thermal runaway of ZnO arrester blocks depend on the temperature and leakage current of ZnO arrester blocks.

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Effect of thermal conductivity degradation on the behavior of high burnup $UO_2$ fuel

  • Lee, Byung-Ho;Koo, Yang-Hyun;Sohn, Dong-Seong
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 춘계학술발표회논문집(3)
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    • pp.265-270
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    • 1996
  • The temperature distribution in the pellet was obtained from beginning the general heat conduction equation. The thermal conductivity of pellet used the SIMFUEL data that made clear the effect of burnup on the thermal conductivity degradation. Since the pellet rim acts as the thermal barrier to heat flow. the pellet was subdivided into several rings in which the outer ring was adjusted to play almost the same role as the rim. The local burup in each ring except the outer ring was calculated from the power depression factor based on FASER results. whereas the rim burnup at the outer ring was achieved by the pellet averaged burnup based on the empirical relation. The rim changed to the equivalent Xe film so the predicted temperature shooed the thermal jump across the rim. The observed temperature profiles depended on linear heat generation rate. fuel burnup. and power depression factor. The thermal conductivity degradation modelling can be applied to the fuel performance code to high burnup fuel,

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폴리인산염 첨가에 의한 폴리프로필렌 기반의 Wood Plastic Composites 열안정성 (Thermal Stability of Polypropylene-Based Wood Plastic Composites by The Addition of Ammonium Polyphosphate)

  • 전상진;이선영
    • Journal of the Korean Wood Science and Technology
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    • 제42권6호
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    • pp.682-690
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    • 2014
  • 본 연구에서는 WPC의 열안정성을 향상시키기 위해 폴리프로펠렌 매트릭스에 목분과 폴리인산염(ammonium polyphosphate, APP)의 삼종혼합 후, 목분과 난연제 첨가에 따른 목재플라스틱 복합재(wood plastic composites, WPC)의 열분해 거동이 조사되었다. 모든 배합비의 WPC 열분해 거동은 질소의 환경에서 분당 $10^{\circ}C$ 상승속도로 제어하여 열중량분석기(Thermogravimetric analyzer)를 통해 분석하였다. 목분의 열분해온도가 PP의 열분해온도 보다 낮기 때문에 목분에 의해 생성된 char막은 PP로의 열전달 속도를 낮추며, 2차 열분해온도 증가 및 열분해속도를 늦춘다. APP를 첨가한 WPC의 경우 1차 열분해온도 감소 및 2차 열분해온도의 증가를 보여준다. 목분의 함량이 높은 WPC의 경우, APP 첨가 시 1차 열분해온도 감소 및 2차 열분해속도가 증가하였고, 고온에서 잔여물의 양은 APP 함량이 증가할수록 크게 증가하였다. APP가 첨가된 WPC 경우, 목분의 함량이 10 wt%에서 50 wt%로 증가 시 고온에서 잔여물 양이 증가하였는데, 이는 APP 및 목질섬유의 char화가 동시에 발생되기 때문으로 보이며 결과적으로 목분 함량이 증가할수록 APP의 효과가 높게 나타나 열안정 효과를 관찰할 수 있었다.

ZnO 피뢰기 소자의 열적.전기적 특성 분석 (Analysis of Thermal and Electrical Characteristics of ZnO Arrester Blocks)

  • 이수봉;이복희
    • 조명전기설비학회논문지
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    • 제21권10호
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    • pp.82-88
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    • 2007
  • 이 논문에는 교류전압에서 ZnO 피뢰기 소자의 열적 전기적 특성을 기술하였다. ZnO 피뢰기 소자의 누설전류는 시간의 변화에 따라 측정하였다. ZnO 피뢰기 소자의 온도분포를 열화상카메라에 의해 관측하였다. ZnO 피뢰기 소자의 열화 및 열폭주 현상은 열발생과 열방산을 결정짓는 ZnO 피뢰기 소자의 온도한계와 밀접한 관계가 있다. ZnO 피뢰기 소자의 저항은 ZnO 피뢰기 소자의 온도와 누설전류에 의해 민감하게 변화한다. 결론적으로 ZnO 피뢰기 소자의 열화 및 열폭주 현상은 ZnO 피뢰기 소자의 온도와 소자를 통해 흐르는 누설전류에 상당히 의존적인 것으로 나타났다.

혼합폐플라스틱 열분해 왁스오일의 고급화 연구 (A Study of Upgrading of Pyrolysis Wax Oil Obtained from Pyrolysis of Mixed Plastic Waste)

  • 이경환;남기윤;송광섭;김극태;최정길
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.321-324
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    • 2009
  • Upgrading of pyrolysis wax oil has been conducted in a continuous fixed bed reactor at $450^{\circ}C$, 1hour, LHSV 3.5/h. The catalytic degradation using HZSM-5 catalyst are compared with the thermal degradation and also was studied with a function of experimental variables. The raw pyrolysis wax oil shows relatively high boiling point distribution ranging from around $300^{\circ}C$ to $550^{\circ}C$, which has considerably higher boiling point distribution than that of commercial diesel. The product characteristic from thermal degradation shows a similar trend with that of raw pyrolysis wax oil. This means the thermal degradation of pyrolysis wax oil at high degradation temperature is not sufficiently occurred. On the other hand, the catalytic degradation using HZSM-5 catalyst relative to the thermal degradation shows the high conversion of pyrolysis wax oil to light hydrocarbons. This liquid product shows high gasoline range fraction as around 90% fraction and considerably high aromatic fraction in liquid product. Also, in the catalytic degradation the experimental variable such as catalyst amount and reaction temperature was studied.

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Condensation Prevention Performance Assessment Taking Into Account Thermal Insulation Performance Degradation Due to Aging for Apartment Housing

  • Choi, Doo-Sung;Lee, Myung-Eun
    • KIEAE Journal
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    • 제15권6호
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    • pp.11-18
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    • 2015
  • Purpose: The current study analyzed trends in thermal insulation performance with aging, and condensation characteristics caused by the former. Method: Thermal insulation and condensation prevention performance of an architecture were assessed using Temperature Difference Ration Inside, or TDRi. Subjects of this quantitative analysis in thermal insulation performance change due to aging included recently constructed apartments and aged apartments older than 40 years. Time series comparison and analysis were conducted to observed changes in the thermal insulation performance and condensation characteristics. Result: Analysis showed that wall insulation performance degraded with aging regardless of fortified insulating material usage or insulating material type, which caused increased danger of condensation. In addition, when fortified insulating material was installed on the connection between the walls, insulation performance degradation was lower compared to cases in which fortified materials were not used. In all cases from 1 to 10, the rate of thermal insulation performance degradation increased after 20 years of aging.

Thermal Degradation and Cyclodepolymerization of Poly(ethylene terephthalate-co-isophthalate)s

  • Yoo, Dong Il;Shin, Younsook;Youk, Ji Ho
    • Fibers and Polymers
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    • 제2권2호
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    • pp.75-80
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    • 2001
  • The thermal degradation of poly(ethylene terephthalate-co-isophthalate)s (PETIs) is investigated by using isothermal thermogravimetric analysis at the temperature range of 280-31$0^{\circ}C$. The degradation rate of PETIs is increased as the mole ratio of ethylene isophthaloyl (EI) units in PETIs increases. The activation energies for the thermal degradation of poly(ethylene terephthalate), PETI(5/5), and poly(ethylene isophthalate) are 33.4, 16.6, and 8.9 kcal/mole, respectively. The degradation rate of PETIs is influenced by their volatile cyclic oligomer components formed during the polymerization and the thermal degradation. It is simulated by the rotational isomeric state model that the content of cyclic dimer in PETIs, which is the most volatile cyclic oligomer component, increases with the EI units in PETIs.

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