• 한국조명전기설비학회지:조명전기설비
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• 제11권1호
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• pp.99-105
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• 1997

본 논문에서는 주상변압기 절연유의 가속열화반응을 수행하였다. 유중가스를 air bubbling 법으로 추출하여 가스크로마토크라프로 성분을 분석하였으며 가스농도는 각 가스의 추출율을 감안하여 보정하였다. 절연재료의 열화는 열분해반응과산화반응에의하여 진행되었으며 두 종류의 반응은 모두 0차반응의 특성을 보였고 탄화수소류, CO+{{{{ { CO}_{2 } }}}} 및 수소가스의 생성속도식을 얻었다. 유중가스 분석과 UV-Visible 분광광도법에 의하여 변압기내의 철심과 동코일이 열화과정에서 촉매역활을 함을 확인하였다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.1597-1602
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• 2003

Numerical analysis is carried out to assess the temperature distribution on the mixing tee line of Residual Heat Removal System (RHRS). In RHRS, hot and cold fluids of main and bypass piping are mixed and unmixed by the flow rate or piping layout. Thermal stratification phenomenon is a cause of major degradation on RHRS piping. According to the analysis for each operation modes, maximum temperature difference between top and bottom of piping were evaluated about 60K when the flow rate of main and bypass lines is same. Temperature difference will be decreased at the elbow on RHRS piping if the length of vertical piping is increased.

• 전기학회논문지
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• 제59권10호
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• pp.1832-1838
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• 2010

Aging of transformer insulating material in natural ester insulating oil is compared to that in conventional transformer oil. Aging of insulating paper and insulating oil have been studied by performing accelerated thermal aging test. Sealed aging test vessels containing cooper, laminated core, Kraft paper and insulating oil(natural oil or mineral oil) were aged at $140^{\circ}C$ for 500, 1000, 1500 and 2000 hours. Insulating oils after aging are investigated with total acid number, breakdown voltage and viscosity. Also, degradation of insulating paper after aging is determined using breakdown voltage and mechanical strength. Accelerated aging studies demonstrate a slower aging rate for natural ester insulating oil compared to the rate for conventional mineral oil.

• 전기화학회지
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• 제23권3호
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• pp.57-65
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• 2020

리튬이온전지의 열적 열화 메커니즘을 이해하는 것은 전지의 안전성을 향상시키기 위한 필수적인 과정이다. 본 논문에서는 대표적인 양극물질의 하나인 리튬코발트산화물(LiCoO₂, LCO)이 고온에서 작동할 때 형성되는 표면 필름에 의한 전기화학적 성능 열화를 조사하였다. 먼저 25℃와 60℃ 각각의 온도에서 사이클 테스트를 진행한 결과, 60℃에서 25℃에 비해 저하된 사이클 수명을 보였다. 이후 처음 5사이클을 25℃, 60℃에서 구동시킨 LCO 양극을 각각 25-LCO, 60-LCO라 명명하였으며, 이후 임피던스 및 출력 특성 분석은 25℃에서 진행하였다. 이때 두 샘플 모두 저속에서의 초기 용량은 비슷함에도 불구하고 60-LCO가 25-LCO에 비해 높은 임피던스와 낮은 출력 특성을 보였다. X-선 광전자분광 (XPS)분석 결과 60-LCO 샘플에서 cathode-electrolyte interphase의 성분 중 하나인 절연성의 수산화 리튬 (LiOH) 성분이 다량 검출되었으며, 이는 고온에서 과도한 표면 필름 형성이 양극의 표면 저항 증가 및 속도/수명 특성 저하를 가져왔음을 보여준다.

• Fibers and Polymers
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• 제5권4호
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• pp.289-296
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• 2004

The kinetic parameters, including the activation energy E, the reaction order n, and the pre-exponential factor Z, of the degradation of the copolymers based on the poly(L-lactide) (PLLA) or poly(p-dioxanone-co-L-lactide) (PDO/PLLA) and diol-terminated poly(ethylene glycol) (PEG) segments have been evaluated by the single heating methods of Friedman and Freeman-Carroll. The experimental results showed that copolymers exhibited two degradation steps under nitrogen that can be ascribed to PLLA or PDO/PLLA and PEG segments, respectively. However, copolymers exhibited almost single degradation step in air. Although the values of initial decomposition temperature were scattered, copolymers showed the lower maximum weight loss rate and degradation-activation energy in air than in nitrogen whereas the higher value of temperature at the maximum rate of weight loss was observed in air.

• Korean Chemical Engineering Research
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• 제61권4호
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• pp.591-597
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• 2023

Pakistan depends heavily on imports for its fuel requirements. In this experiment, catalytic pyrolysis of a blend of feedstock's consisting of date seed, wheat straw, and corn cob was conducted in a fixed bed reactor to produce oil that can be used as an alternative fuel. The main focus was to emphasize the outcome of important variables on the produced oil. The effects of operating conditions on the yield of bio-oil were studied by changing temperature (350-500 ℃), heating rate (10, 15, 20 ℃/min), and particle size (1, 2, 3 mm). Moreover, ZnO was used as a catalyst in the process. First, the thermal degradation of the feedstock was investigated by TGA and DTG analysis at 10 ℃/min of different particle sizes of 1, 2, and 3mm from a temperature range of 0 to 1000 ℃. The optimum temperature was found to be 450 ℃ for maximum degradation, and the oil yield was indicated to be around 37%. It was deduced from the experiment that the maximum production of bio-oil was 32.21% at a temperature of 450 ℃, a particle size of 1mm, and a heating rate of 15 ℃/min. When using the catalyst under the same operating conditions, the bio-oil production increased to 41.05%. The heating value of the produced oil was 22 MJ/kg compared to low-quality biodiesel oil, which could be used as a fuel.

• 한국유체기계학회 논문집
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• 제6권3호
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• pp.36-43
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• 2003

Operating performance of industrial gas turbines in combined cycle power plants depends upon atmospheric conditions. Compressor fouling caused by airborne particles in the atmosphere and their adhesions on compressor blades is one of critical phenomena related to the performance degradation of industrial gas turbines. Compressor fouling provokes increase of pressure loss in inlet duct, decrease of mass flow rate of intake air and decrease of compressor stage efficiency. In this study, impacts of compressor fouling on the performance of an industrial gas turbine operating at design point condition are investigated analytically. As results, it is found that the reduction of produced power with decreased mass flow rate of intake air caused by narrowed flow area by the adhesion of airborne particles on compressor blades is the most dominant impact on the gas turbine performance by the compressor fouling phenomena.

• Elastomers and Composites
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• 제56권3호
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• pp.124-135
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• 2021

Evaluating service lives of rubber materials at certain temperatures requires a destructive method (typically using elongation at break). In this study, a non-destructive method based on hardness change rate was proposed for evaluating the service life of chloroprene rubber (CR). Compared to the destructive method, this non-destructive method ensures homogeneity of CR specimens and requires a small number of samples. Thermal accelerated degradation test was conducted on the CR specimens at 55, 70, 85, 100, and 125℃, and the tensile strength, elongation at break, and hardness were measured. The results of the experiment were compared to those of the accelerated life evaluation method proposed in this study. Comparing the analyzed lives in the high temperature region (70, 85, 100, and 125℃), the difference between the service lives for the destructive method (using the elongation at break) and non-destructive method (using the hardness) was approximately 0.1 year. Therefore, it was confirmed that the proposed non-destructive evaluation method based on hardness changes can evaluate the actual life of CR under thermally accelerated degradation conditions.

• 한국산학기술학회논문지
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• 제8권5호
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• pp.1042-1046
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• 2007

본 연구에서는 제 3의 화학 원소 첨가에 의한 코발트 실리사이드와 니켈 실리사이드의 열적 안정성 향상 메카니즘을 조사하였다. 즉, Co-Si 시스템에 텅스텐을 첨가하는 경우 CoSi의 heat of formation이 증가하는 것으로 관찰되었다. 이러한 증가는 시스템 에너지 감속 속도의 최대화로 대변되는 실리사이드 형성 kinetics가 선호하는 glass의 형성을 억제하는 것으로 밝혀졌다. 이 경우 CoSi와 실리콘 기판 사이의 계면에 형성되는 다결정 구조는 glass의 self-diffusion보다 확산계수가 훨씬 작아 상 변이를 위해서는 보다 높은 열에너지를 요구하게 되어 궁극적으로 CoSi의 열적 안정성이 향상되는 것을 알 수 있었다.

• Composites Research
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• 제30권1호
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• pp.7-14
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• 2017

In this paper, the inter-lamina shear strength (ILSS) of multi-wall carbon nanotube (MWNT) reinforced carbon fiber reinforced plastics (CFRP) and thin-ply composites were verified under low earth orbit (LEO) space environment. CFRP, MWNT reinforced CFRP, thin-ply CFRP and MWNT reinforced thin-ply CFRP were tested after aging by using accelerated ground simulation equipment. The used ground simulation equipment can simulate high vacuum ($2.5{\times}10^{-6}torr$), atomic oxygen (AO, $9.15{\times}10^{14}atoms/cm^2{\cdot}s$), ultraviolet light (UV, 200 nm wave length) and thermal cycling ($-70{\sim}100^{\circ}C$) simultaneously. The duration of aging experiment was twenty hours, which is an equivalent duration to that of STS-4 space shuttle condition. After the aging experiment, ILSS were measured at room temperature ($27^{\circ}C$), high temperature ($100^{\circ}C$) and low temperature ($-100^{\circ}C$) to verify the effect of operation temperature. The MWNT and thin-ply shows good improvement of ILSS at ground condition especially with the thin-ply. And after LEO exposure large degradation of ILSS was observed at MWNT added composite due to the thermal cycle. And the degradation rate was much higher under the high temperature condition. But, at the low temperature condition, the ILSS was largely recovered due to the matrix toughening effect.