• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.12
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• pp.23-32
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• 2020

This study investigated the thermal degradation and fading behavior of PTT dyed with vat dye and its dyeing ability. The PTT sample was dyed with vat dye using an acid treatment and pad-steam method to improve the dyeing performance. This method made dye particle nanosize and allowed it to penetrate the polymer material easily. The sample dyed using the pad-steam method showed level dyeing and enhanced dyeing affinity, compared to the batch-dyeing method. The degradation behavior of PTT dyed with vat dye after each heat and UV treatment was examined with the change in tensile strength or K/S value on the sample. The tensile strength and K/S values of the sample dyed with vat dye after the heat and UV treatment decreased with increasing temperature and exposure time. Although they showed high degradation under severe conditions, its rate constant was improved compared to the samples dyed with disperse dye. Consequently, acid treatment and the pad-steam method resulted in the introduction of vat dye on PTT. In addition, the PTT dyed with vat dye showed enhanced thermal and UV resistance because of their high molecular weight and chemical structure for stable adsorption behavior.

• Structural Engineering and Mechanics
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• v.32 no.3
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• pp.429-445
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• 2009

Thermal stability of quasi-isotropic composite and polymeric structures is considered one of the most important criteria in predicting life span of building structures. The outdoor applications of these structures have raised some legitimate concerns about their durability including moisture resistance and thermal stability. Exposure of such quasi-isotropic composite/polymeric structures to various and severe climatic conditions such as heat flux and frigid climate would change the material behavior and thermal viability and may lead to the degradation of material properties and building durability. This paper presents an analytical model for the generalized problem. This model accommodates the non-linearity and the non-homogeneity of the internal heat generated within the structure and the changes, modification to the material constants, and the structural size. The paper also investigates the effect of the incorporation of the temperature and/or material constant sensitive internal heat generation with four encountered climatic conditions on thermal stability of infinite cylindrical quasi-isotropic composite/polymeric structures. This can eventually result in the failure of such structures. Detailed critical analyses for four case studies which consider the population of the internal heat generation, cylindrical size, material constants, and four different climatic conditions are carried out. For each case of the proposed boundary conditions, the critical thermal stability parameter is determined. The results of this paper indicate that the thermal stability parameter is critically dependent on the cylinder size, material constants/selection, the convective heat transfer coefficient, subjected heat flux and other constants accrued from the structure environment.

• Polymer(Korea)
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• v.37 no.6
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• pp.722-729
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• 2013

In order to enhance the thermal conductivity of poly(dimethyl siloxane) (PDMS), boron nitride (BN) and carbon nanotubes (CNTs) were incorporated as the thermally conductive fillers. The amount of BN was increased from 0 to 100 phr (parts per hundred rubber) and the amount of CNTs was increased from 0 to 4 phr at a fixed amount of the boron nitride (100 phr). The thermal conductivity of the composites increased with an increasing concentration of BN, but the incorporation of CNTs had only a slight effect on the enhancement of thermal conductivity. Unexpectedly, the thermal degradation of the composites was accelerated by the addition of CNTs in 100 phr BN filled PDMS. Activation energy for thermal decomposition of the composites was calculated using the Horowitz-Metzger method. The curing behavior, electrical resistivity, and mechanical properties of PDMS filled with BN and CNTs were investigated.

• Smart Structures and Systems
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• v.16 no.5
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• pp.835-851
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• 2015

This paper presents theoretical and experimental evaluation of the structural health monitoring (SHM) capability of piezoelectric wafer active sensors (PWAS) at elevated temperatures. This is important because the technologies for structural sensing and monitoring need to account for the thermal effect and compensate for it. Permanently installed PWAS transducers have been One of the extensively employed sensor technologies for in-situ continuous SHM. In this paper, the electro-mechanical impedance spectroscopy (EMIS) method has been utilized as a dynamic descriptor of PWAS behavior and as a high frequency standing wave local modal technique. Another SHM technology utilizes PWAS as far-field transient transducers to excite and detect guided waves propagating through the structure. This paper first presents how the EMIS method is used to qualify and quantify circular PWAS resonators in an increasing temperature environment up to 230 deg C. The piezoelectric material degradation with temperature was investigated and trends of variation with temperature were deduced from experimental measurements. These effects were introduced in a wave propagation simulation software called Wave Form Revealer (WFR). The thermal effects on the substrate material were also considered. Thus, the changes in the propagating guided wave signal at various temperatures could be simulated. The paper ends with summary and conclusions followed by suggestions for further work.

• Elastomers and Composites
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• v.48 no.2
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• pp.161-166
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• 2013

Thermal degradation behavior of chlorine cure-site ACM and carboxylic cure-site ACM rubbers was studied by non-isothermal TGA thermal analysis. Carboxylic cure-site ACM rubber exhibited comparatively more thermally stable than chlorine cure-site ACM, showing higher peak temperature, at which maximum reaction rate occurred. Activation energies from Kissinger method were calculated as 118.6 kJ/mol for the chlorine cure-site ACM and 105.5 kJ/mol for the carboxylic cure-site ACM, showing similar values from Flynn-Wall-Ozawa analysis over the conversion range of 0.1~0.2. From the analysis of the reaction order change, both samples seemed thermally decomposed through the multiple reaction mechanism as is the common rubber materials.

• Composites Research
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• v.36 no.4
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• pp.264-269
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• 2023

Spent coffee grounds (SCG) are a ubiquitous byproduct of coffee consumption, representing a significant waste management challenge, as well as an untapped resource for economic development and sustainability. Improper disposal of SCG can result in environmental problems such as methane emissions and leachate production. This study aims to investigate the physicochemical properties of SCG and their potential as a reinforcement material in polypropylene (PP) to fabricate an eco-friendly composite via extrusion and injection molding, with SCG filler ratios ranging from 5-20%. To evaluate the effect of SCG on the morphological and mechanical properties of the bio- composite, thermogravimetric analysis, SEM, tensile, flexural, and impact tests were conducted. The results demonstrated that the addition of SCG lead to a slight increase in brittleness of the composite but did not significantly affect its mechanical properties. Impressively, the presence of a significant organic component in SCG contributed to the enhanced thermal performance of PP/SCG composites. This improvement was evident in terms of increased thermal stability, delayed onset of degradation, and higher maximum degradation temperature as compared to pure PP. These findings suggest that SCG has potential as a filler material for PP composites, with the ability to enhance the material's properties without compromising overall performance.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.257-258
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• 2006

The $I_c$ degradation behaviors of externally-reinforced Bi-2223 superconducting tapes under pressurized liquid nitrogen were investigated. Tapes with different thickness of reinforcement layers were compared and the results showed that when the bending strain was calculated at the outer surface, the tape with the thicker reinforcement showed a better bending strain tolerance of $I_c$, but when the bending strain was calculated at the outermost filament, the $I_c$ degradation behavior became identical for all tapes. $I_{c0}$ decreased with the increase of applied pressure. After depressurization to atmospheric pressure from 1 MPa, the $I_c$ was completely recovered to its initial values. Ballooning occurred after a thermal cycle.

• 한국정보디스플레이학회:학술대회논문집
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• 2008.10a
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• pp.1026-1029
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• 2008

Temperature increase during OLED operation can significantly degrade the device lifetime. By using top-emission OLEDs fabricated on glass and silicon substrates that have different thermal conductivities, we found that efficient heat dissipation and corresponding lifetime improvement can be obtained by making a direct contact between the OLED anode and the high thermally-conductive silicon substrate. We describe substrate-dependent OLED heat dissipation behavior and OLED lifetime improvement by using infrared camera images and constant current stress test methods.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.11
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• pp.527-536
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• 2019

This study examines the degradation of PTT BCF and fading behavior of disperse dye by heat treatment and UV irradiation. The behavior in strength degradation of PTT BCF after treat treatment was examined by measuring the tensile strength of samples. The strength retention of PTT BCF rapidly decreased with increasing exposure time at 150℃. The K/S value decreased with increasing temperature and its trend accelerated with increasing exposure time on heat. The behavior on strength degradation of PTT BCF and the fading of disperse dye on it were studied under UV irradiation at various temperatures. The tensile strength of PTT BCF and the K/S value of the sample dyed with disperse dye after UV irradiation decreased with increasing temperature and exposure time. PTT BCF exposed under UV irradiation exhibited lower strength and K/S value compared with the sample after heat treatment. Additional study on the effects of additives used to improve the resistance to fading of disperse dye and degradation of PTT BCF revealed that antioxidant and UV absorbent in PTT BCF showed a small improvement in the strength degradation of PTT BCF and the fading of dye.

• Tunnel and Underground Space
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• v.22 no.3
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• pp.188-195
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• 2012

Using a computational fluid dynamics (CFD) code, FLUENT, the present study investigated the thermal stratification behavior of Lyckebo storage in Sweden, which is the very first large-scale rock cavern for underground thermal energy storage. Heat transfer analysis was carried out for numerical cases with different temperatures of the surrounding rock mass in order to examine the effect of rock mass heating due to periodic storage and production of thermal energy on thermal stratification and heat loss. The change of thermal stratification with respect to time was quantitatively examined based on an index of the degree of stratification. The results of numerical simulation showed that in the early operational stage where the surrounding rock mass was less heated, the stratification of stored thermal energy was rapidly degraded over time, but the degradation and heat loss tended to reduce as the surrounding rock mass was heated during a long period of operation.