• Journal of the Korean Geotechnical Society
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• v.26 no.5
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• pp.27-36
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• 2010

Thermal conductivities using the thermal probe method were determined for frost susceptible soil with three types of discarded tire powder under the condition of a temperature variation from $-20^{\circ}C{\sim}+10^{\circ}C$. Also, the amount of unfrozen water contents was measured by the pulsed NMR method. The variation of unfrozen water content in the experimental condition could be expressed as a function of temperature given by an exponential equation. A new model for calculating the thermal conductivity of frozen soil was proposed. It is extended from the two element method and subdivided into three constituent elements.

• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2299-2302
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• 2007

A series of quaternary ammonium-based ionic liquids (ILs) containing an alkyl carbonate group on the cation was first prepared and their physical and electrochemical properties including density, viscosity, thermal stability, electrochemical stability, and ionic conductivity were reported. These ILs exhibited wide electrochemical windows of at least 5.0 V and relatively high conductivities. In contrast to dialkyl-substituted ionic liquids, the ILs with an alkyl carbonate group on the cation showed much smaller drop in conductivities when mixed with a lithium salt, due to the interaction of lithium ions with carbonate groups. Upon interaction with a Li salt, the carbonyl stretching frequency of the carbonate group shifted to a lower frequency whereas the peak associated with C-O single bond moved to a higher frequency.

• Journal of the Korean Solar Energy Society
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• v.32 no.5
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• pp.68-74
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• 2012

Investigation of the effective soil thermal conductivity($k$) is the first step in designing the ground loop heat exchanger(borehole) of a geothermal heat pump system. Another important factor is the borehole thermal resistance($R_b$). Thermal response tests offer a good method to determine the ground thermal properties for the total heat transport in the ground. The first step is measured for initial soil temperature. This is done by supplying a only pump power into a borehole heat exchanger. They need to supply into water unload heat power more than 30 minutes. In this study, the initial soil temperature was found to analysis $14.1{\sim}16.0^{\circ}C$,the ratio was 68.7% represented. In this case of $k$, was 2.1~3.0 $W/m{\cdot}k$, $R_b$ was 0.11~0.20 $m{\cdot}K/W$. In this work, it is also shown that the distribution of a soil thermal conductivity and borehole thermal resistance were on the influence of initial soil temperature. And soil thermal conductivity was related with factors of equation by linear least square method, borehole thermal resistance was on the influence of composite factors.

• Journal of the Korean Solar Energy Society
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• v.31 no.4
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• pp.80-86
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• 2011

Investigation of the effective soil thermal conductivity(k) is the first step in designing the ground loop heat exchanger(borehole) of a geothermal heat pump system. Another important factor is the borehole thermal resistance($R_b$). Thermal response tests offer a good method to determine the ground thermal properties for the total heat transport in the ground. This is done by supplying a constant heat power into a borehole heat exchanger. There are two methods to supply a constant heat power. One is to employ the electricity provided by Korea Electric Power Corporation(KEPCO). The other is to use electricity generated by a generator. In this study, the power supply regulation was found to reduce when the electricity generated by the generator was used. This is because the generator evaluated with the power supply characteristically reduces the power supply regulation between an overload and a complex using. But it sometimes occurs a power supply regulation in In-situ thermal response test. In this case getting of k,$R_b$ requires delay times and restored normal state. However, the effect of the delay times and restored normal state on the soil thermal conductivity and borehole thermal resistance is very small. Therefore it is possible to use a generally accepted delay times and restored normal state in the analysis. In this work, it is also shown that an acceptable range of ${\Delta}k$, ${\Delta}R_b$ for normal state and regulation state might be approximately 0.01-0.16W/m k, and -0.004-0.007m K/W, respectively. Thus, restored normal state of power supply regulation is valuable to recommend.

• Advances in materials Research
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• v.1 no.4
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• pp.299-310
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• 2012

This article describes the synthesis of a novel N-substituted pyrrole monomer containing an azobenzene group. The 2-[N-ethyl-N-[4-[(4-nitrophenyl) azo]-phenyl] amino] ethyl-3-chloropropionate (RedII) compound was synthesized via reaction of 4-nitro-4'-[N-ethyl-N-(2-hydroxyethyl)-amino] azobenzene (RedI) and 3-chloropropionic acid. RedII was reacted with the potassium salt of pyrrole then 2-[N-ethyl-N-[4-[(nitro phenyl) azo] phenyl] amino] ethyl-N-pyrrolyl propionate (Py-RedII) was prepared. Chemical polymerization of Py-RedII and copolymerization of Py-RedII with pyrrole carried out using $FeCl_3$. Poly (2-[N-ethyl-N-[4-[(nitro phenyl) azo] phenyl] amino] ethyl-N-pyrrolyl propionate) (PPy-RedII) was characterized by UV, IR, $^1HNMR$, $^{13}CNMR$ spectroscopies. Electropolymerization of Py-RedII and electroco-polymerization of Py-RedII and pyrrole were studied using conventional three electrodes system, Ag/AgCl reference electrode, platinum counter electrode and GC disk working electrode. Scanning electron microscopy (SEM), thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC) were used for thermal and rheological studies. The TGA curve of PPy-RedII demonstrated a high thermal stability up to 200°C and its DSC thermogram showed two endothermic peaks at 88 and $122^{\circ}C$. The glass transition temperature of the polymer was found to be above the room temperature. Electrical conductivities of PPy-RedII and it's copolymer with pyrrole (PPy-RedII-co-Py) were studied by the four-probe method and produced conductivities of $7.5{\times}10^{-4}$ and $6.5{\times}10^{-3}Scm^{-1}$, respectively.

• Journal of Powder Materials
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• v.30 no.6
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• pp.463-469
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• 2023

Aluminum alloys, known for their high strength-to-weight ratios and impressive electrical and thermal conductivities, are extensively used in numerous engineering sectors, such as aerospace, automotive, and construction. Recently, significant efforts have been made to develop novel aluminum alloys specifically tailored for additive manufacturing. These new alloys aim to provide an optimal balance between mechanical properties and thermal/electrical conductivities. In this study, nine combinatorial samples with various alloy compositions were fabricated using direct energy deposition (DED) additive manufacturing by adjusting the feeding speeds of Al6061 alloy and Al-12Si alloy powders. The effects of the alloying elements on the microstructure, electrical conductivity, and hardness were investigated. Generally, as the Si and Cu contents decreased, electrical conductivity increased and hardness decreased, exhibiting trade-off characteristics. However, electrical conductivity and hardness showed an optimal combination when the Si content was adjusted to below 4.5 wt%, which can sufficiently suppress the grain boundary segregation of the α-Si precipitates, and the Cu content was controlled to induce the formation of Al₂Cu precipitates.

• Journal of the Korean Ceramic Society
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• v.34 no.9
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• pp.969-978
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• 1997

The properties of microstructure, hydrophobicity/hydrophilicity, mechanical strength, and thermal conduction of pure/opacified silica aerogels synthesized by the sol-gel supercritical drying technique were investigated. The hydrophobic surface of opacified silica aerogels doped with carbon (0.13 g/cm3 density, 94% porosity, 580 m2/g specific surface area) transformed to hydrophilic surface after heat-treated above 30$0^{\circ}C$. The values of compressive modulus (1.85 MPa) and strength (0.5 MPa) of opacfied silica aerogels were about 20 times higher than those of pure silica aerogels. The mechanical properties of pure silica aerogels heat-treated at $700^{\circ}C$ were also considerably improved without changing their porosity and density. Particularly, compressive modulus and compressive strength of pure silica aerogels GPSed under 100$0^{\circ}C$ and 80 bar were improved 140 and 37 times, respectively. Thermal conductivities of pure/opacified silica aerogels measured at room temperature and 227$^{\circ}C$ were about 0.013 and 0.019 W/m.K, respectively, and were to be found very low value of 0.004 W/m.K below 10 torr pressure at room temperature.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.33 no.2
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• pp.153-161
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• 2009

Three-dimensional finite-element methods(FEM) have been used to analyze the thermal stress of an exhaust gas recirculation(EGR) cooler due to thermal and pressure load. Since efficiency and capability of the heat exchanger are mainly dependent on net heat transferring area of the EGR cooler system, the tube inside the system has a numerous dimples on the surface. Thus for finite element analysis, firstly the dimple-typed tube is modeled as a plain element without the dimple, and then the equivalent thermal conductivities and elastic modulus are calculated. This work describes the numerical homogenization procedure of the dimple-typed tube and verifies the equivalent material properties by comparison of a single unit and the actual full model. Finally, the homogenization scheme presented in this study can be efficiently applied to finite element analyses for the thermal stress and deformation behavior of the EGR cooler system with the dimple-typed tube.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.456-459
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• 2007

Thermal conductivities (TC) of 57 Jurassic muscovitic granite samples (KIGAM) and 149 porphyritic granite samples (Yeonki: BE-2, BE-3) were measured with LFA-447. Ranges of TC values are $2.429{\sim}3.878$ W/mK (KIGAM), $2.220{\sim}3.767$ W/mK (Yeonki, BE-2) and $2.019{\sim}3.990$ W/mK (Yeonki, BE-3); arithmetic means are 2.924 W/mK (KIGAM), 2.907 W/mK (Yeonki, BE-2), and 2.881 W/mK (Yeonki, BE-3), respectively. In this study, harmonic mean values were calculated to estimate the average value of TC. Harmonic mean values are 2.883 W/mK (KIGAM), 2.886 W/mK (Yeonki, BE-2), and 2.866 W/mK (Yeonki, BE-3), respectively. Heat extraction rates of a borehole heat exchanger strongly depend on TC values. Heat-extraction rates from re values are expected to be a little lower than 84 W/m in all sites. However, considering ground water flow, it is expected that actual heat extraction rate would be higher than the expected value.

• Korean Journal of Materials Research
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• v.5 no.2
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• pp.215-222
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• 1995

Anisotropic pitch-based C-type and hollow carbon fibers can obtain wider shear stresses during the spinning and induce higher molecular orientation than that of round along the fiber axis. These fibers reinforced unidirectional epoxy composites were prepared by hot-press moulding method and perpendicular and parallel thermal conductivities of the composites were measured by a steady-state meth od. In the case of round carbon fibers reinforced epoxy composites(H-CF/EP), thermal anisotropic factor showed nearly 50, while those of H-CF/EP and C-CF/EP showed about 130 and 118, respectively. As a result, both H-CF/EP and C-CF/EP had an excellent directional thermal conductivity to distribute heat, above 200 %.