• Title/Summary/Keyword: thermal co-evaporation

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Fabrication of Flexible CIGS thin film solar cells using Polyimide substrate (Polyimide 기판을 이용한 Flexible CIGS 박막 태양전지 제조)

  • Jung, Seung-Chul;Ahn, Se-Jin;Yun, Jae-Ho;Gwak, Ji-Hye;Kim, Do-Jin;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.153-155
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    • 2009
  • In this study, we fabricated the $Cu(In,Ga)Se_2$ (CIGS) thin-film solar cells by using a polyimide substrate. The CIGS thin-film was deposited on Mo coated polyimide substrate by a 3-stage co-evaporation technique. Because the polyimide shows thermal transformation at about $400^{\circ}C$, the substrate temperature of co-evaporation process was set to below $400^{\circ}C$. Corresponding solar cell showed a conversion efficiency of 7.08 % with $V_{OC}$ of 0.58 V, $J_{SC}$ of 24.99 $mA/cm^2$ and FF of 0.49.

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Characteristics Of TiO$_2$ Optical Thin Films With Ag Content by RF Magnetron Co-sputtering Method (RF magnetron co-sputtering으로 제작한 TiO$_2$ 광학 박막의 Ag 함량에 따른 특성)

  • 김상철;김의정;한성홍
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.07a
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    • pp.282-283
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    • 2003
  • TiO$_2$ 박막은 높은 굴절률과 유전 상수를 가지며, 가시광선과 근적외선 영역에서 우수한 투과성을 나타낸다. 따라서, 전기적, 광학적 특성이 우수한 광학코팅에 응용되고 있다. 또한 화학적으로 안정하고 비교적 큰 에너지 밴드 갭을 지닌 반도체 물질로서 유전체 다층 박막을 제작하는데 있어서 중요한 물질로 사용되고 있다. TiO$_2$ 박막을 제작하기 위한 물리적인 방법으로는 sputtering, anodic 또는 thermal, e-beam evaporation 등이 이용되고 있으며, sol-gel법, CVD 등과 같은 화학적인 방법도 이용되고 있다. (중략)

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Experimental Validation on Performance of Waste-heat-recovery Boiler with Water Injection (물분사 폐열회수 보일러의 효용성에 대한 실험적 검증)

  • Jaehun Shin;Taejoon Park;Hyunseok Cho;Junsang Yoo;Seoksu Moon;Changeon Lee
    • Journal of ILASS-Korea
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    • v.28 no.1
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    • pp.43-48
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    • 2023
  • The waste-heat-recovery boiler with water spray (HR-B/WS) applies the heat exchange between the inlet air and exhaust gas with the water spray into the inlet air. The evaporation of water in the inlet air promotes heat recovery from the exhaust gas so that thermal efficiency can be improved by the enhanced condensing effect. The NOx emission can also be reduced by lowering the flame temperature due to the dilution effect of the water. In this study, the validity of this concept is examined by the practical boiler test performed with a 24 kW condensing boiler under the full load condition according to the water injection amount. The theoretical amount of water injection is calculated under the assumption of full evaporation of the sprayed water, which is calculated as 50 g/min. Since the injected water cannot evaporate fully in the actual system, the maximum water spray amount is set as 100 g/min. The results showed that the water injection can increase the thermal efficiency up to 95.59% and reduce NOx and CO emissions simultaneously to 8.9 ppm and 35 ppm at 0% of O2. Although the heat energy loss increased due to the unevaporated water, the increase in water injection amount caused higher thermal efficiency due to the increased amount of the evaporated water.

Thermal Analysis on the LNG Storage Tank of LNG Bunkering System Applied with Double Shield Insulation Method (LNG 벙커링용 이중 단열적용 LNG 저장탱크 열해석)

  • Jung, Il-Young;Kim, Nam-Guk;Yun, Sang-Kook
    • Journal of the Korean Institute of Gas
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    • v.22 no.4
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    • pp.1-6
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    • 2018
  • An LNG bunkering system stores LNG in a horizontal IMO's C-Type tank insulated with perlite powder, and $10^{-2}$ Torr vacuum in the annular space between the double walls. Current storage tanks have high heat leakage, evaporating over 2.0% daily. A more efficiently insulated storage tank reducing the evaporation rate is required to develope. This research carried out thermal analysis on a new effective insulation method, i.e. double shield insulation system, that separates high super vacuum in the annular space between two tanks with a perlite vacuum in the back side of outer tank. This highly efficient insulation system obtained an evaporation rate of 0.16% per day under a $10^{-4}$ Torr vacuum. Even if the space loses its vacuum, the new insulation system showed a lower evaporation rate of 5.23% than the present perlite system of 4.9%.

CO Sensing Characteristics of $Pt-SnO_{2-x}$ Thin Film Devices Fabricated by Thermal Oxidation (열산화법으로 형성한 $Pt-SnO_{2-x}$ 박막소자의 CO 가스 감지특성)

  • Shim, Chang-Hyun;Park, Hyo-Derk;Lee, Jae-Hyun;Lee, Duk-Dong
    • Journal of Sensor Science and Technology
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    • v.1 no.2
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    • pp.117-123
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    • 1992
  • $Pt-SnO_{2-x}$ thin film sensing devices has been fabricated by thermal oxidation of stacked Pt-Sn thin film on the heater. The thickness of Sn thin film deposited by thermal evaporation was $4000{\AA}$ and the thickness of Pt deposited by D. C. sputtering on Sn thin film was $14{\sim}71{\AA}$ range. The XRD analysis show that the $Pt-SnO_{2-x}$ thin films are formed by grains with a diameter of about $200{\AA}$ randomly connected and the crystalline phase of the thin films are preferentally oriented in the (110) direction. $Pt-SnO_{2-x}$ thin film device (Pt thickness : $43{\AA}$) to 6000 ppm CO shows the sensitivity of 80% and high selectivity to CO. And the operating temperature and the thermal oxidation temperature of $Pt-SnO_{2-x}$ thin film device with high sensitivity to CO were $200^{\circ}C$ and $500^{\circ}C$, respectively.

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Numerical Study on the Evaporation Flow Phenomena of Natural Refrigerant CO2 through Small Diameter Tubes (천연냉매인 이산화탄소의 세관 유동시 발생하는 증발 유동 현상에 대한 수치해석 연구)

  • Choi, In-Su;Park, Byung-Duck
    • Journal of the Korean Society of Industry Convergence
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    • v.10 no.2
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    • pp.89-96
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    • 2007
  • For the environment protection, carbon dioxide as a natural refrigerant has been studied to use in an automotive air conditioning system. Hence, a numerical model has been developed to describe the evaporation phenomena of carbon dioxide flowing through very small diameter tubes. The two dimensional low-Reynolds $k-{\varepsilon}$ model was used to predict the flow phenomena of carbon dioxide in the two phase during its evaporation. Furthermore, the results obtained from the model were compared with the experiments for the validation. The heat transfer coefficient is lower, as the tube inner diameter becomes smaller. However, the amount of heat absorbed by a unit mass of carbon dioxide is greater due to more surface area. Therefore, the small diameter tube has advantage in terms of compact design of evaporator. When the inlet condition of pressure and temperature is low, the heat transfer coefficient is slightly high at the same size of tube because of the thermal properties of carbon dioxide.

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Thermogravimetric and Fourier Transform Infrared Analysis of Switchgrass Pyrolysis (스위치그라스 열분해에 대한 TGA-FTIR 분석)

  • Lee, Seong-Beom;Fasina, Oladiran O.
    • Journal of Biosystems Engineering
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    • v.34 no.1
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    • pp.44-49
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    • 2009
  • This study was conducted to investigate the pyrolysis characteristics of switchgrass using TGA-FTIR instrument. Switchgrass is a high yielding perennial grass that has been designated as a potential energy crop, because of its high energy value. Ground switchgrass were pyrolysed at different heating rates of 10, 20, 30, and $40^{\circ}C/min$ in a TGA-FTIR instrument. The thermal decomposition characteristics of switchgrass were analyzed, and the gases volatilized during the experiment were identified. The thermal decomposition of switchgrass started at approximately $220^{\circ}C$, followed by a major loss of weight, where the main volatilization occurred, and the thermal decomposition was essentially completed by $430^{\circ}C$. The pyrolysis process was found to compose of four stages; moisture evaporation, hemicellulose decomposition, cellulose decomposition, and lignin degradation. The peak temperatures for hemicellulose decomposition ($306^{\circ}C$ to $327^{\circ}C$) and cellulose decomposition ($351^{\circ}C$ to $369^{\circ}C$) were increased with greater heating rates. FTIR analysis showed that the following gases were released during the pyrolysis of switchgrass; $CO_2$, CO, $CH_4$, $NH_3$, COS, $C_{2}H_{4}$, and some acetic acid. The most gas species were released at low temperature from 310 to $380^{\circ}C$, which was corresponding well with the observation of thermal decomposition.

One-Pot Synthesis, Crystal Structures and Thermal Properties of Two Three-Dimensional Cobalt(II) Complexes

  • Tao, Bo;Lei, Wen;Cheng, Feiran;Xia, Hua
    • Bulletin of the Korean Chemical Society
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    • v.33 no.6
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    • pp.1929-1933
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    • 2012
  • Two cobalt(II) compounds $[Co(2,2{^\prime}-bipy)(H_2O)_2(SO_4)]_n$ (1) and $[Co_2(2,2^{\prime}-bipy)_2(btec)(H_2O)_6]{\cdot}2H_2O$ (2) (2,2'-bipy = 2,2'-bipyridine, $H_4btec$ = 1,2,4,5-benzenetetracarboxylic acid), have been simultaneously synthesized by a one-pot slow solvent evaporation reaction. Their structures were determined by single-crystal X-ray diffraction and further characterized by X-ray powder diffraction (XRPD), IR, elemental and thermogravimetric analysis (TGA). The structural analysis reveals that compound 1 exhibits an infinite 1D chain structure with the octahedral Co(II) centers bridging by the tetrahedral ${\mu}_2-SO{_4}^{2-}$ ligands, while compound 2 possesses a dinuclear $Co_2(2,2^{\prime}-bipy)_2(btec)(H_2O)_6$ unit and the two adjacent octahedral Co(II) ions are linked by the bismonodentately coordinated btec ligand. Additionally, compound 2 exhibits blue fluorescent emission in the solid state at room temperature.

Fabrication of Flexible CIGS thin film solar cells using STS430 substrate (STS430 기판을 이용한 Flexible CIGS 박막 태양전지 제조)

  • Jung, Seung-Chul;Ahn, Se-Jin;Yun, Jae-Ho;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.436-437
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    • 2008
  • Flexible CIGS thin film solar cell was fabricated using STS430 plate as a flexible substrate in this work. A diffusion barrier layer of $SiO_2$ thin film was deposited on STS430 substrate by PECVD followed by deposition of double layered Mo back contact. After depositing CIGS absorber layer by co-evaporation, CdS buffer layer by chemical bath deposition, ZnO window layer by RF sputtering and Al electrode by thermal evaporation, the solar cell fabrication processes were completed and its performance was evaluated. Corresponding solar cell showed an conversion efficiency of 8.35 % with $V_{OC}$ of 0.52 V, $J_{SC}$ of 26.06 mA/$cm^2$ and FF of 0.61.

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Thermal Stability and the Effect of Substrate Temperature on the Structural and Magnetic Properties of Pd/Co Multilayer Films (Pd/Co 다층박막의 구조 및 자기적 특성에 미치는 기판온도 및 열적안정성에 관한 연구)

  • 허용철;김상록;이성래;김창수
    • Journal of the Korean Magnetics Society
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    • v.3 no.4
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    • pp.298-304
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    • 1993
  • The effects of the substrate temperature and the Pd underlayer on the structure and the magnetic properties of Pd/Co multilayer films prepared by the thermal evaporation were studied. As the substrate temperature increases up to $150^{\circ}C$, the crystallinity of sublayers, (111) texture and the interface sharpness of Pd/Co multilayers were improved due to the enhanced mobility of adatoms. As results of that, the perpendicular and surface anisotropy energies were increased but the coercivity was decreased because the pinning sites of domain wall decreased due to the grain growth. The grain size of the multilayers increased with Pd underlyer thickness. Thermal degradation was enhanced at above $200^{\circ}C$ due to interdiffusion at the Pd/Co interface. The intensity of the main diffraction peak rapidly decayed in the initial stage of aging and then decreased slowly. The rapid change of the intensity in the initial stage was speculated to be due to the structural relaxation phenomena and the later stage change was due to the interdiffusion. The activation energy for the interdiffusion in Pd4/Co1 multilayers was 14.9 KCal/mole.K.

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