• 제목/요약/키워드: thermal aging

검색결과 620건 처리시간 0.025초

Vanadia SCR의 열적 열화에 따른 조촉매의 영향 (The Effect of Additive Catalyst according to Thermal Aging of Vanadia SCR)

  • 서충길
    • 동력기계공학회지
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    • 제18권3호
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    • pp.14-19
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    • 2014
  • The purpose of the study is to investigate the effect of additive catalyst according to the thermal aging of vanadia SCR catalysts. At a fresh condition, the $3V_2O_5-5WO_5-92TiO_2$ SCR showed the highest NOx conversion rate of about 30%, the performance of 5 kinds of SCR to which additive catalysts were added was not improved due to the insignificant effect of acid site control. For catalysts aged for 12h at $700^{\circ}C$, the SCR to which 3wt% Zeolite was added decreased in NOx conversion rate by 2.5% on average compared to the fresh SCR, it showed higher thermal durability than other additive catalyst. For 3Zeolite with high performance of NOx conversion rate during thermal aging, the Zeolite with stronger durability at a high temperature than other 5 kinds of SCR catalysts decreased the sintering of catalysts.

시효처리와 thermal cycling이 치관전장용 복합레진의 2축굽힘강도에 미치는 영향 (EFFECTS OF AGING AND THERMAL CYCLING ON THE BIAXIAL FLEXURE STRENGTH OF VENEERING RESIN COMPOSITES FOR CROWN)

  • 정관호;하일수;송광엽
    • 대한치과보철학회지
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    • 제37권5호
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    • pp.597-606
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    • 1999
  • This study was performed to evaluate the effect of aging and thermal cycling on the biaxial flexure strength of low commercially available veneering resin composites for crown(Dentacolor : DC, Artglass : AG, Esternia : ET and Targis : TG). Disc specimens were fabricated in a teflon mold giving 12mm in diameter and 1mm in thickness. All samples were divided into 4 groups. Group 1 was dried in a dessicator at $25^{\circ}C$ for 30 days. Group 2 was immersed in distilled water at $37^{\circ}C$ for 30 days. Group 3 was immersed in distilled water at $65^{\circ}C$ for 30 days. Group 4 was subjected to 10,000 thermal cycles between $5^{\circ}C\;and\;55^{\circ}C$, and the immersion time in each bath was 15 seconds per cycle. Biaxial flexure test was conducted using the ball-on-three-ball method at the cross head speed of 0.5mm/min and fracture surfaces were observed with scanning electoron microscope. The results obtained were summarized as follows; 1. Weibull modulus values, except for the AG group, decreased after thermal cycling treatment. 2. Biaxial flexure strength values of aging group at $37^{\circ}C$ were the lowest in all sample groups. Except for the DC group, strength values were significantly decreased for the drying group. 3. After thermal cycling test, the highest value of biaxial flexure strength of 188.8 MPa was observed in the ET group and the lowest value of 73.2 MPa was observed in the DC group. The strength values showed the significant differences in each group (p<0.05). 4. Observation of surfaces after thermal cycling test revealed the ditching in the part of surrounding large fillers.

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ARC(Heat-Wait-Search method)와 isothermal 조건을 이용한 압축형 복합화약의 열적 특성 및 노화 예측 연구 (Study on the thermal Property and Aging Prediction for Pressable Plastic Bonded Explosives through ARC(Heat-Wait-Search method) & isothermal conditions)

  • 이소정;김진석;김승희;권국태;추초롱;전영진
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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    • pp.172-178
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    • 2017
  • 열적 특성은 에너지 물질 분야에서 중요한 특성 중 하나로, 에너지 물질 분해 시 분해열을 방출하기 때문에 DSC(시차 주사 열량계, Differential Scanning Calorimetry)를 자주 사용하고 있다. 승온속도를 달리한 DSC 측정의 경우, 용융과 같은 열역학적 변화로 인해 물질의 열적 측정에 방해를 준다. 또한 kg 단위로 예측하기 때문에 mg 단위 때와는 다른 공간상의 열 변화의 변수가 생긴다. 이번 연구에서는 이 문제점을 해결하는 방안으로, 등온 조건으로 한 DSC(Differential Scanning Calorimetry) 기초 데이터로 ATKS thermokinetic 프로그램을 이용하여 열적 노화 특성을 예측한다. 그리고 g 단위로 측정하는 ARC(Accelerating Rate Calorimetry)의 데이터를 이용하여 열적 노화 특성을 예측하고 결과를 비교 할 것이다.

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ACCELERATED AGING USING $FOCAS^{(R)}$-A BURNER BASED SYSTEM SIMULATING AN ENGINE

  • Bykowski, B.B.;Bartley, G.J.J.;Webb, C.C.;Zhan, R.;Burrahm, R.W.
    • International Journal of Automotive Technology
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    • 제7권3호
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    • pp.245-249
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    • 2006
  • Accelerated aging of engine exhaust system components such as catalytic converters are traditionally performed using an engine/dynamometer test stand. $SwRI^{(R)}'s\;FOCAS^{(R)}$ system reduces or eliminates many of the engine based aging limitations. This paper will describe several studies. These include: 1) replication of engine based catalyst aging cycles with added precision and dependability; 2) catalyst aging with and without lubricating oil effects; 3) effects of lubricant phosphorus on catalyst performance; and 4) the potential to thermally age components beyond the capabilities of engine based systems. The first study includes the development of the SwRI FOCAS system to run programmed aging conditions with or without lubricating oil. A description of the subsystems is given. The second two studies used the SwRI FOCAS system to age catalysts. One study compared thermal-only aging using of the SwRI FOCAS system with equivalent aging on a traditional engine/dynamometer test stand. The other study examined the effect on catalyst performance of two lubricating oils containing different levels of phosphorus, and compared the results to field data generated using the same oils in a fleet of vehicles.

강제열화에 따른 종이의 색상변화 (Effects of thermal aging on variations in paper color)

  • 김선경;최은연;이용규;조병욱
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2011년도 춘계학술발표회 논문집
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    • pp.235-241
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    • 2011
  • Effects of thermal aging on color variations of various papers were evaluated. With thermal aging, most of papers showed a special trend in $a^*$-$b^*$ plane: $a^*$ (red-green) values of the samples were reduced at beginning and after a turning point it was increased while $b^*$ (blue-yellow) was kept increased (yellowing of paper). In case of filter paper which consists of chemical pulps, the changes in $a^*$ value was occurred late compared with other samples. In case of the copy paper with optical brightening agent, the turning point in $a^*$ was not observed while a constant increase in $b^*$ was observed. In case of color paper, no specific trends in $a^*$-$b^*$ were found.

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우레탄 도막 방수재의 열열화 특성 (Influence of Thermal Aging on the Properties of Polyurethane Coating of Waterproof.)

  • 김성래;신홍철;신주재;김영근
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.931-934
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    • 2008
  • 폴리우레탄은 방수재로 널리 사용되며 구조물에 발생되는 균열 및 거동에 의해 항상 외력을 받고있을 뿐만 아니라 사용 환경에 따라 각종 환경열화 인자에 노출되어 있다. 환경 열화인자로서는 자외선, 오존, 열, 수분 등이 잘 알려져 있다. 그 중에서 모든 열화의 기본이 되는 열의 영향, 특히 고온에서의 영향이 중요하다. 따라서, 노출형인 우레탄 고무계 1류 도막 방수재의 경우는 80$^{\circ}C$에서, 비노출형의 경우는 70$^{\circ}$C에서 촉진 열열화 시험을 3주간 실시하였다. 결과는 방수재의 기본물성과 인장 강도 및 신장율 모두 저하되는 경향을 보였으며, 특히 온도 60$^{\circ}$C에서 측정할 경우 급격히 물성 저하가 발생되었다.

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용제 용해형 고분자를 이용한 열화한지의 보강처리 (Strengthening Treatment of Aged Hanji with Solvent Soluble Polymers)

  • 김강재;이민형;엄태진
    • 펄프종이기술
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    • 제44권1호
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    • pp.1-9
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    • 2012
  • In this study, 5 solvent soluble polymers were treated on Hanji. Mechanical properties, morphology and oxidation index with thermal aging were measured on the aged Hanji, dewaxed Hanji and polymer treated Hanji. Synthetic polymers(such as polylactic acid, polybutylene succinate, polystyrene) treated Hanji had higher strength and thermal stability than cellulose derivatives(such as cellulose nitrate and cellulose acetate) treated Hanji. Polymer treated Hanji showed a little bit of color change. The oxidation index of PS treated Hanji did not increase with thermal aging because it did not have a carboxyl group in chemical structure. Finally, polystyrene was found to be the most efficient method for strengthening the dewaxed Hanji. The best aging safety and thermal stability were obtained at the polystyrene 3% solution.

Thermal Properties of DGEBHA/MDA/SN/zeolite System Degraded by Moisture Absorption

  • Kim, You-Jeong;Lee, Hong-Ki;Kim, Sang-Wook
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.479-482
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    • 1999
  • Cured epoxy resins are extensively used for the electrical insulation in high-voltage equipments. The bisphenol A-based epoxy resins lured with azine show, especially, good thermal properties and mechanical resistances. For the technical and economic reasons, varing amount of inorganic fillers are added to endow the required special properties. In the large generators and motors of power plants, epoxy insulation is disclosed to the harsh conditions like the superheated steam and abrupt temperature variation. Hygrothermal aging at elevated temperatures tends to induce degradation in epoxy resins. To predict the effect of this degradation in DGEBA/MDA/SN/zeolite system, we proceeded the forced moisture absorption experiment using the autoclave. The thermal properties of the untreated and treated specimens were analyzed by DSC and TGA under the nitrogen flowing condition. The moisture absorption results showed a weight increase during hygrothermal aging at 1207. At the initial aging period, the system leaded to more or less postcuring but more prolonged environmental aging leaded the discoloration of specimen and lowering the T$_{g}$./.

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