• Title/Summary/Keyword: thermal aging

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Estimation of Thermal Aging Embrittlement of LWR Primary Pressure Boundary Components

  • Kim, Sunki;Kim, Yongsoo
    • Nuclear Engineering and Technology
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    • v.30 no.6
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    • pp.609-616
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    • 1998
  • Cast duplex stainless steels are extensively used for primary pressure boundary components. These components are, however, embrittled due to the precipitation of $\alpha$' phase by spinodal decomposition and other processes when exposed to reactor operating temperature for a design lifetime or life extension conditions. This report presents a procedure for estimating the current condition and the residual life of safety-related stainless steel components by using ANL database and correlations. The database of Charpy impact energy suggests that CF-8M grade is the most susceptible to thermal aging and CF-3 grade is the least. Thus, the integrity of CF-8M alleys may be degraded seriously and the degree of deterioration may exceed acceptance limit after several years of service in the nuclear reactors.

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Effects of Combined Environmental Factors on Mechanical and Thermal Analysis Properties of Graphite/Epoxy Composites (복합적인 환경인자가 탄소섬유강화 복합재의 기계적 및 열분석 특성에 미치는 영향)

  • Lee, Sang-Jin;Lee, Jong-Keun;Yoon, Sung-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.7
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    • pp.1416-1425
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    • 2002
  • In this study, the effects of combined environmental factors on mechanical and thermal analysis properties of graphite/epoxy composites were evaluated by the use of an accelerated aging test. Environmental factors such as temperature, moisture. and ultraviolet were considered. A xenon-arc lamp was utilized for ultraviolet light. and exposure times of up to 3000 hours were applied. Several types of specimens - tensile. bending, and shear specimens those are transverse to the fiber direction, and bending specimens those are parallel to the tiber direction - were used to investigate the effects of environmental factors on mechanical properties of the composites. Also, glass transition temperature, storage shear modulus, loss shear modulus, and tan ${\delta}$ were measured as a function of exposure times through a dynamic mechanical analyzer. In addition. a suitable testing method for determining the effect of environmental factors on mechanical properties is suggested by comparing the results from using two different types of strain measuring sensors. Finally, composite surfaces exposed to environmental factors were examined using a scanning electron microscope.

Cure Characteristics, Mechanical Properties, Abrasion Property and Thermal Properties of EVM/EPM Blends Containing Flame Retardants

  • Sung, Il Kyung;Lee, Won Ki;Park, Chan Young
    • Elastomers and Composites
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    • v.52 no.2
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    • pp.105-113
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    • 2017
  • The curing behavior, mechanical properties, hot-air aging resistance, abrasion properties,thermal properties, etc., of EVM/EPM/APP (ammonium polyphosphate)/DPER (dipentaerythritol)/EG (expandable graphite) and EVM/EPM/ATH (aluminium trihydroxide) flame retarding systems in ethylene vinyl acetate rubber (EVM) blends with EPM (ethylene propylene rubber) were sequentially examined. For both flame retarding systems, the torque values increased with the content of EPM rubber and with the vulcanization time. As the content of EPM rubber increased, the scorch time became shorter, whereas the optimum cure time followed an increasing trend. For the EVM/EPM/APP/DPER/EG flameretarding system, as the content of EPM rubber increased, the hardness did not change,whereas the tensile strength and elongation at break decreased. A hot-air aging resistance test at $150^{\circ}C$ showed that the heat resistance decreased with the EPM content regardless of the kinds and contents of flame retardants. As the EPM content increased, the abrasion rate became higher and the abrasion resistance of the EVM/EPM/APP/DPER/EG flame retarding systems exceeded that of the EVM/EPM/ATH flame retarding counterparts. In comparison with the EVM/EPM/ATH flame retarding systems, the thermal stability of the EVM/EPM/APP/DPER/EG flame retarding system showed an increasing tendency.

Studies on the Developement of Active Components and their Charactrization of 3-Way Catalysts for Autombile Emission Control -Studies on the surface Characterstics Changes of Pd/$\gamma$-Alumina Catalysts by Addition of WO$_3$ and La$_2$O$_3$ as Promoters- (자동차 배기정화용 3원촉매정화기의 국산화 시도를 위한 촉매성분의 개발과 그 촉매 특성에 관한 연구 -WO$_3$ 및 La$_2$O$_3$조촉매성분들의 첨가에 따른 Pd/$\gamma$-Alumina 촉매들의 표면특성 변화-)

  • 이상윤;정석진;박경석
    • Journal of the Korean institute of surface engineering
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    • v.23 no.2
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    • pp.30-38
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    • 1990
  • For the purpose of suggesting the thermal resistant catalyst for automobile emission control, various catalysts, Pd-WO3 and PD-La2O3 systems, were charactrized before and after thermal aging. It was found that La2O3 formed amorphous surface compound on the support by strong metal-support interaction(SMSI). And by Temperature Programmed Desorption (TPD) expeiment, it was found that the distribution of acid site which is strong acid sites by adding the promoters. After thermal aging, it was observed that the acidity of Pd-WO3 system was decreased largely because of losing acid site by metal vaporization. On the other hand, there was pretty small change in the properties of matter of Pd-La2O3 system. Therefore, it could be considered that La2O3 formed heat resisting amorphous surface compound on the support by SMSI.

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Influences of Precipitation of Secondary Phase by Heat Treatment on Thermal Properties of Al-4.5%Cu Alloy (열처리에 따른 제2상 석출이 Al-4.5%Cu 합금의 열 물성에 미치는 영향)

  • Choi, Se-Weon
    • Korean Journal of Materials Research
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    • v.30 no.8
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    • pp.435-440
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    • 2020
  • The relationship between the precipitation of secondary phase and the thermal properties of Al-4.5%Cu alloy (in wt.%) after various heat treatments has been studied. Solid solution treatment of alloy was performed at 808 K for 6 hours, followed by warm water quenching; then, the samples were aged in air at 473 K for different times. The thermal diffusivity of the Al-4.5%Cu alloy changed with the heat treatment conditions of the alloy at temperatures below 523 K. The as-quenched specimen had the lowest thermal diffusivity, and as the artificial aging time increased, the thermal diffusivity of the specimen increased in the temperature range between 298 and 523 K. For the specimen aged for five hours, the thermal conductivity was 12% higher than that of the as-quenched specimens at 298 K. It is confirmed that the thermal diffusivity and thermal conductivity of the Al-4.5%Cu alloy significantly depend on their thermal history at temperatures below 523 K. The precipitation and dissolution of the Al2Cu phase were confirmed via DSC for the alloys, and the formation of coefficient of thermal expansion peaks in TMA was caused by precipitation. The precipitation of supersaturated solid solution of Al-4.5%Cu alloys had an additional linear expansion of ≈ 0.05 % at 643 K during thermal expansion measurement.