• 제목/요약/키워드: thermal aging

검색결과 622건 처리시간 0.026초

The information system concept for thermal monitoring of a spent nuclear fuel storage container

  • Svitlana Alyokhina
    • Nuclear Engineering and Technology
    • /
    • 제55권10호
    • /
    • pp.3898-3906
    • /
    • 2023
  • The paper notes that the most common way of handling spent nuclear fuel (SNF) of power reactors is its temporary long-term dry storage. At the same time, the operation of the dry spent fuel storage facilities almost never use the modern capabilities of information systems in safety control and collecting information for the next studies under implementation of aging management programs. The author proposes a structure of an information system that can be implemented in a dry spent fuel storage facility with ventilated storage containers. To control the thermal component of spent fuel storage safety, a database structure has been developed, which contains 5 tables. An algorithm for monitoring the thermal state of spent fuel was created for the proposed information system, which is based on the comparison of measured and forecast values of the safety criterion, in which the level of heating the ventilation air temperature was chosen. Predictive values of the safety criterion are obtained on the basis of previously published studies. The proposed algorithm is an implementation of the information function of the system. The proposed information system can be used for effective thermal monitoring and collecting information for the next studies under the implementation of aging management programs for spent fuel storage equipment, permanent control of spent fuel storage safety, staff training, etc.

전력용 변압기의 열화에 의해 생성된 부산물의 분석 (Analysis of Produced By-products Due to Oil/Paper Degradation on Power Transformers)

  • 김재훈;한상옥
    • 전기학회논문지
    • /
    • 제56권9호
    • /
    • pp.1561-1565
    • /
    • 2007
  • According to thermal degradation on power transformers, it is known that electrical, mechanical and chemical characteristics for power transformer's oil-paper are changed. In the chemical property, especially, when the kraft paper is aged, the cellulose polymer chains break down into shorter lengths. It causes decrease in both tensile strength and degree of polymerization of paper insulation. Also the paper breakdown is accompanied by an increase in the content of various furanic compounds within the dielectric liquid. It is known that furanic components in transformer oil come only from the decomposition of insulating paper rather than from the oil itself. Therefore the analysis of furanic degradation products provides a complementary technique to dissolved gas analysis for monitoring transformers when we evaluate the aging of insulating paper by the total concentration of carbon monoxide and carbon dioxide dissolved in oil only. Recently, the analysis of furanic compounds by high performance liquid chromatography(HPLC) using IEC 61198 method for estimating degradation of paper insulation in power transformers has been used more conveniently for assessment of oil-paper. It is know that the main products which is produced by aging are 2-furfuryl alcohol, 2-furaldehyde(furfural), 2-furoic acid, 2-acetylfuran, 5-methyl-2-furaldehyde, and 5-hydroxymethyl-2-furaldehyde. For investigating the accelerated aging process of oil-paper samples we manufactured accelerating aging equipment and we estimated variation of insulations at $140^{\circ}C$ temp. during 500 hours. Typical transformer proportions of copper, silicon steel and iron have been added to oil-paper insulation during the aging process. The oil-paper insulation samples have been measured at intervals of 100 hours. Finally we have analyzed that 2-furoic acid and 2-acetylfuran products of furanic compounds were detected by HPLC, and their concentrations were increased with accelerated aging time.

Breakdown Characteristics and Lifetime Estimation of Rubber Insulating Gloves Using Statistical Models

  • Kim, Doo Hyun;Kang, Dong Kyu
    • International Journal of Safety
    • /
    • 제1권1호
    • /
    • pp.36-42
    • /
    • 2002
  • This paper is aimed at predicting the life of rubber insulating gloves under normal operating stresses from relatively rapid test performed at higher stresses. Specimens of rubber insulating gloves are subject to multiple stress conditions, i.e. combined electrical and thermal stresses. Two modes of electrical stress, step voltage stress and constant voltage stress are used in specimen aging. There are two types of test for electrical stress in this experiment: the one is Breakdown Voltage (BDV) test under step voltage stress and thermal stress and the other is lifetime test under constant voltage stress and temperature stress. The ac breakdown voltage defined as the break-down point of insulation that leakage current excesses a limit value, l0mA in this experiment, is determined. Because the very high variability of aging data requires the application of statistical model, Weibull distribution is used to represent the failure times as the straight line on Weibull probability paper. Weibull parameters are deter-mined by three statistical methods i.e. maximum likelihood method, graphical method and least squares method, which employ SAS package, Weibull probability paper and FORTRAN, respectively. Two chosen models for predicting the life under simultaneous electrical and thermal stresses are inverse power model and exponential model. And the constants of life equation for multistress aging are calculated using numerical method, such as Gauss Jordan method etc.. The completion of life equation enables to estimate the life at normal stress based on the data collected from accelerated aging test. Also the comparison of the calculated lifetimes between the inverse power model and the exponential model is carried out. And the lifetimes calculated by three statistical methods with lower voltage than test voltage are compared. The results obtained from the suggested experimental method are presented and discussed.

티타늄 금속 기반의 파이로테크닉 물질에 대한 열분석 및 반응특성 추출을 통한 열·수분 노화 메커니즘 구축 (Establishment of Hygrothermal Aging Mechanism via Thermal Analysis and Extraction of Reaction Kinetics of Ti Metal-based Pyrotechnic Materials)

  • 오주영;여재익
    • 한국항공우주학회지
    • /
    • 제49권9호
    • /
    • pp.759-769
    • /
    • 2021
  • 발사체 추진 시스템에서 Titanium Hydride Potassium Perchlorate (THPP)는 에너지를 인가받으면 gas를 발생시키는 pyrotechnic initiator로써 혹은 NASA Standard Initiator (NSI)의 supplement charge로써 흔히 사용되는 물질이다. 하지만 금속으로 이루어진 복합 화약이 오랫동안 보관이 되면 노화라는 문제에 직면하게 된다. 본 연구에서는 열분석 및 표면분석을 통하여 다양한 습도환경에서 노화된 THPP에 대하여 열역학적 특성의 변화를 확인하였고, 이를 바탕으로 THPP에 대한 전반적인 노화 메커니즘을 구축해내었다. 우선, THPP가 노화됨에 따라 산화제 표면의 균열빈도가 증가하고 길이가 길어졌는데, 이는 열·수분 노화가 공통적으로 산화제의 분해를 초래함을 보여준다. 이때 열 노화된 경우 Viton의 열화 현상이, 수분 노화된 경우 연료의 산화가 더욱 두드러졌다. 또한 실험을 통해 계산된 반응률에 대한 THPP의 화학반응인자의 경우 습도에 따라 크게 달라졌는데, 이는 수분이 THPP의 연소에 상당한 변화를 미쳐 결국에는 수명의 감소로 이어지게 될 것을 시사한다.

대용량 발전기 고정자 바의 유전정접 특성 (Characteristics of Dissipation Factor in Large Generator Stator Bars)

  • 김희동;공태식;주영호
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
    • /
    • pp.402-403
    • /
    • 2009
  • Accelerated aging tests were conducted under laboratory conditions on two generator stator bars. Electrical stress is applied in No. 1 model stator bar. Electrical and thermal stresses are applied in No. 2 model stator bar. As aging times increased from 0 to 11460h, dissipation factor($tan{\delta}$) test was performed on No. 1 and No.2 model stator bars. The ${\Delta}tan{\delta}$ of No. 1 and No. 2 stator bars increased with increased in aging time.

  • PDF

대용량 발전기 고정자 권선의 절연열화 특성 (Characteristics of Insulation Aging in Large Generator Stator Windings)

  • 김희동;이영준;주영호
    • 전기학회논문지
    • /
    • 제58권7호
    • /
    • pp.1375-1379
    • /
    • 2009
  • Insulation tests have been performed on two generator stator bars under accelerated aging under a laboratory environment. Electrical stress was applied to stator bar No.1, and electrical and thermal stresses were applied to stator bar No.2. Nondestructive stator insulation tests including the ac current, dissipation factor($tan{\delta}$), and partial discharge tests have been performed on both bars as the bars were aged for 11460 hours. Experimental test results show that ${\Delta}I$, ${\Delta}tan{\delta}$, and partial discharge of No. 1 and No.2 stator bars increased with increased in aging time. It has been concluded from the test that the stator insulation of the two generators are in good condition.

시료에 따른 Sn1.8Bi0.8Cu0.6In솔더의 미세구조 (Micorstructure of Sn1.8Bi0.8Cu0.6In alloy during thermal aging)

  • 이재식;전주선;박종우;정재필
    • 한국마이크로전자및패키징학회:학술대회논문집
    • /
    • 한국마이크로전자및패키징학회 2003년도 기술심포지움 논문집
    • /
    • pp.94-98
    • /
    • 2003
  • The microstructure of Sn1.8Bi0.8Cu0.6In alloys was evaluated at various aging time. The bumps of Sn1.8Bi0.8Cu0.6In alloys after reflowed at $250^{\circ}C$ were well-formed and had 260um height. The craters on the bumps, however, were observed. Intermetallic compounds formed on the interface between so]der and Cu/Ni UBM were consist of $(Cu,Ni)_6Sn_5$. As aging goes on up to 1000hours, the composition of Ni changed from $6.63\%$ at initial stage(as-reflowed) to $13.47\%$ at final stage(1000hours aging ). In addition, after 500hours aging, the floating of IMC to the solder was observed.

  • PDF

열화처리에 따른 고무와 강선코드간 접착계면의 변화 (Changes in Adhesion Interface between Rubber and Steel Cord with Aging Treatment)

  • 서곤;손봉영
    • 공업화학
    • /
    • 제5권4호
    • /
    • pp.630-636
    • /
    • 1994
  • 열화처리 후 고무와 황동이 피복된 강선코드의 접박계면 변화를 오제 광전자 분광기와 주사 전자현미경으로 조사하였다. 열열화 후에는 접착층의 부분 산화와 추가 성장이, 습윤열화 후에는 접착층과 황동의 부분 소실이, 동적열화 후에는 접착층의 파괴와 철심의 부식이 관찰되었다. 이러한 접착계면의 변화를 인장시험에서 측정된 접착 성질과 관련지어 고찰하였다.

  • PDF

NKN 무연압전 액추에이터의 신뢰성 연구 (An Investigation on the Aging Properties of NKN Lead-free Piezoelectric Multi-layer Ceramic Actuators)

  • 채문순;이규탁;고중혁
    • 한국전기전자재료학회논문지
    • /
    • 제24권10호
    • /
    • pp.803-806
    • /
    • 2011
  • 1 mol% $Li_2O$ excess $0.9(Na_{0.52}K_{0.48})NbO_3-0.1LiTaO_3$ lead-free piezoelectric multilayer ceramic actuators were investigated to determine their aging properties. To reduce the thermal aging behavior, we applied a rectified unipolar electric field of 5 kV/mm to the specimen to accelerate the electric aging behavior. By employing a rectified unipolar electric field for the piezoelectric actuators, we could remove undesirable heating from the relaxation current in the motion of the ferroelectric domain. To accelerate the aging test, the applied electric fields had a frequency of 900 Hz. To have enough time for charging and discharging, we employed an accurate time constant to design the equivalent circuit model for the aging tester. To extract exact aging behavior, we measured the pseudo-piezoelectric coefficient before and after the aging process. We also measured the electro-mechanical coupling coefficient, the frequency-dependent dielectric permittivity, and the impedance to compare with fresh and aged specimen.

Cu pillar 범프 내의 금속간화합물 성장거동에 미치는 시효처리의 영향 (Effect of Thermal Aging on the Intermetallic compound Growth kinetics in the Cu pillar bump)

  • 임기태;이장희;김병준;이기욱;이민재;주영창;박영배
    • 마이크로전자및패키징학회지
    • /
    • 제14권4호
    • /
    • pp.15-20
    • /
    • 2007
  • 시효처리에 따른 Cu pillar 범프 내 다양한 계면에서의 금속간화합물 성장거동을 각각 120, 150, $165^{\circ}C$의 온도에서 300시간동안 시효처리하면서 연구하였다. 분석 결과 Cu pillar와 SnPb 계면에서는 $Cu_6Sn_5$$Cu_3Sn$이 관찰되었고, 시효처리 시간이 경과함에 따라 parabolic 형태로 성장하였다. 또한 시효처리 온도가 높을수록 시간에 따른 $Cu_6Sn_5$$Cu_3Sn$의 성장속도는 더욱 빨랐다. kirkendall void는 Cu Pillar와 $Cu_3Sn$ 사이의 계면과 $Cu_3Sn$ 내부에서 형성되었고, 시효처리 시간이 경과함에 따라 성장하였다. 리플로우 후에 SnPb와 Ni(P)사이의 계면에서는 $(Cu,Ni)_6Sn_5$가 형성되었고, 시효처리 시간에 따른 $(Cu,Ni)_6Sn_5$거 두께 변화는 관찰되지 않았다. 시효처리 온도와 시간에 따른 금속간화합물의 두께 변화를 이용하여 전체$(Cu_6Sn_5+Cu_3Sn)$금속간화합물과 $Cu_6Sn_5,\;Cu_3Sn$ 금속간화합물의 성장에 대한 활성화 에너지를 구해본 결과 각각 1.53, 1.84, 0.81 eV의 값을 가지고 있었다.

  • PDF