• 제목/요약/키워드: thermal aging

검색결과 617건 처리시간 0.038초

연료전지 집전판용 주석도금 동판의 열 열화에 따른 금속간화합물 성장 및 비저항 변화 (Resistivity Changes and Intermetallic Growth After Thermal Aging of Matte Tin-Plated Copper Sheet for Current Collector in Fuel Cell)

  • 김재훈;김주한;한상옥;구경완;금영범;정귀성;고행진
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2009년도 제40회 하계학술대회
    • /
    • pp.2067_2068
    • /
    • 2009
  • Resistivity changes and intermetallic growth after thermal aging of Matter tin-plated copper sheet for current collector in fuel cell were investigated to survey the diffusion of Cu into Sn in interface and surface. The results show that the intermetallic growth and resistivity depended on thermal aging temperature and dwell time. In Sn plate on a Cu substrate, $Cu_6Sn_5({\mu})$ and $Cu_3Sn({\varepsilon})$ intermetallics layer were formed at plate/substrate interface. $Cu_6Sn_5({\mu})$ intermetallics layer gradually changed $Cu_3Sn({\varepsilon})$. Moreover Cu get through Sn layer and it was diffused in the surface at $200^{\circ}C$. On the other hand, only $Cu_3Sn({\varepsilon})$ intermetallics layer were formed at plate/substrate interface at $300^{\circ}C$. Consequently, the intermetallics formation, thermal condition and oxidation of surface, causes increase in the resistivity of Tin-plated copper sheet.

  • PDF

해수오염 된 CSPE의 물리·전기적 상태감시에 관한 연구 (A Study on Physical and Electrical Condition Monitoring of Seawater Soaked CSPE)

  • 신용덕;이정우;전황현;김인용
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2015년도 제46회 하계학술대회
    • /
    • pp.1136-1137
    • /
    • 2015
  • The accelerated thermal aging of chlorosulfonated polyethylene (CSPE) was performed for 0 days, 80.82 days, and 161.63 days at $100^{\circ}C$, which is equivalent to 0y, 40y, and 80y of aging, respectively, at $50^{\circ}C$. The volume electrical resistivity of dried CSPE for 570~630 days after seawater and freshwater soaking, are $1.109{\times}10^{14}{\Omega}{\cdot}cm$, $8.546{\times}10^{13}{\Omega}{\cdot}cm$ and $8.466{\times}10^{13}{\Omega}{\cdot}cm$. The applied voltage rising time of 11~12 second and dielectric breakdown time of 9~11 second of the accelerated thermal aged CSPE is shorter than those of 12~13 and 11~13 second of the non-accelerated thermal aged CSPE, respectively. It is shown that oxidation, fragment and crack are formated at hole of dielectric breakdown in CSPE. The apparent density of dried CSPE for 750 days are $1.555g/cm^3$, $1.595g/cm^3$$1.597g/cm^3$ according to accelerated thermal aging year, respectively.

  • PDF

시효 열처리 된 Al-Si-Mg-Cu-(Ti) 합금의 고온 열팽창 계수 변화 (Changes in High-temperature Coefficient of Thermal Expansion of Artificial Aging Heat-treated Al-Si-Mg-Cu-(Ti) Alloys)

  • 최세원
    • 열처리공학회지
    • /
    • 제34권5호
    • /
    • pp.226-232
    • /
    • 2021
  • The relationship between precipitation and coefficient of thermal expansion of Al-6%Si-0.4%Mg-0.9%Cu-(Ti) alloy (in wt.%) after various heat treatments were studied by the thermodynamic analyzer (TMA) and differential scanning calorimetry (DSC). Solution heat treatment of the alloy was carried out at 535℃ for 6 h followed by water quenching, and the samples were artificially aged in the air at 180℃ and 220℃ for 5 h. The coefficient of thermal expansion (CTE) curve showed some residual strain and decreased with increasing aging temperature. The CTE curves changed sharply in the temperature range of 200℃ to 400℃, and the corresponding peak shifted for the aged samples due to the change in the precipitation behavior of the secondary phase. These transformation peaks in the aged sample are related to the volume of the precipitation of the Si phase as determined by DSC analysis. The change in CTE is mainly caused by the precipitation of the Si phase in the Al-Si alloy, and the size of the change occurs simultaneously with the size of the precipitate.

PMN-PZT 세라믹스에 있어서 열에이징 효과 (Effect of Thermal Aging in PMN-PZT Ceramics)

  • 이개명;박창엽
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
    • /
    • pp.17-21
    • /
    • 1995
  • Tw types of Pb(Mn$\sub$1/3/Nb$\sub$2/3/)O$_3$+PZT Ceramics had been fabricated by hot-pressing method. One had cause grain and the other had fine grain doe to Cr$_2$O$_3$ addition. These specimen were poled by applying the DC electric field in various steps. The effects of thermal aging on their piezoelectric characteristics and temperature stability of the frequency were investigated.

  • PDF

Thermal Aging Embrittlement in LWR Primary Pressure Boundary Components

  • Kim, Sunki;Kim, Yongsoo;Wonmok Jae
    • 한국원자력학회:학술대회논문집
    • /
    • 한국원자력학회 1995년도 춘계학술발표회논문집(2)
    • /
    • pp.635-640
    • /
    • 1995
  • Two techniques for the verification of the phase separation in ferrite phase of primary pressure bounary component materials, the primary cause of thermal aging embrittlement, are presented. Data base of room-temperature Charpy V-notch impact energy during reactor service was estimated as a measure of the degree of embrittlement. The serviceable period of CF-3 and CF-8 alloys as the primary pressure boundary components may be acceptably extended for 60 years of lifetime. However, the integrity of CF-8M alloys can be degraded seriously after several years of service in the nuclear reactor.

  • PDF

금 합금 도금층의 접촉저항에 미치는 합금원소의 영향 (Effect of alloying elements on the contact resistance of electrodeposited gold films)

  • 이지웅;손인준
    • 한국표면공학회:학술대회논문집
    • /
    • 한국표면공학회 2013년도 춘계학술대회 논문집
    • /
    • pp.184-184
    • /
    • 2013
  • 본 연구에서는 금 합금 도금층의 접촉저항에 미치는 첨가 합금원소의 영향을 조사하였다. 또한 표면실장을 위한 솔더링 공정에서 도금층에 가해지는 열이력이 접촉저항 값에 미치는 영향을 조사하기 위해서, $260^{\circ}C$에서 thermal aging을 실시한 후, 접촉저항을 측정하였다. 합금원소의 종류에 따라서 thermal aging후의 접촉저항 값이 변하는 요인을 조사하기 위해서 XPS를 이용하여 표면분석을 실시하였다.

  • PDF

열처리를 통한 Si 고용 및 석출 반응이 Al-Si 합금의 열확산도에 미치는 영향 (Effect of Precipitation and Dissolution of Si on the Thermal Diffusivity in the Al-Si Alloy System)

  • 김유미;김영찬;최세원
    • 한국재료학회지
    • /
    • 제30권9호
    • /
    • pp.474-479
    • /
    • 2020
  • The effect of precipitation and dissolution of Si on the thermal diffusivity in the Al-Si alloy system is reported in this study and solution heat treatment followed by aging treatment is carried out to determine the effects of heat treatment on the thermal characteristics. The solution treatment is performed at 535 ℃ for 4 and 10 h and then the specimens are cooled by rapid quenching. The samples are aged at 300 ℃ for 4 h to precipitate Si solute. The addition of 9 wt% silicon contents makes the thermal diffusivity decrease from 78 to 74 mm/s2 in the cases of solid solution treated and quenched samples. After quenching and aging, the Si solute precipitates on the Al matrix and increases the thermal diffusivity compared with that after the quenched state. In particular, the increase of the thermal diffusivity is equal to 10 mm/s2 without relation to the Si contents in the Al-Si alloy, which seems to corresponded to solute amount of Si 1 wt% in the Al matrix.

플라즈마 용사 열차폐 코팅의 박리수명 평가에 관한 연구 (Evaluation on the Delamination Life of Isothermally Aged Plasma Sprayed Thermal Barrier Coating)

  • 김대진;신인환;구재민;석창성;김문영
    • 대한기계학회논문집A
    • /
    • 제33권2호
    • /
    • pp.162-168
    • /
    • 2009
  • In this study, disk type of thermal barrier coating system for gas turbine blade was isothermally aged in the furnace changing exposure time and temperature. The aging conditions that delamination occurs were determined by the extensive microscopic analyses and bond tests for each aging condition. The delamination map was drawn from the time-temperature matrix form which summarize the delamination conditions. Finally, a method to draw the delamination life diagram of a thermal barrier coating system by using the delamination map was suggested.

PV 모듈에서 온도 영향에 의한 micro-crack 성장과 전기적 특성 분석 (The analysis of growth and electrical characteristics of micro-crack with thermal effect in PV module)

  • 송영훈;강기환;유권종;안형근;한득영
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2011년도 제42회 하계학술대회
    • /
    • pp.1318-1319
    • /
    • 2011
  • In this paper, we analyzed of growth and electrical characteristics of micro-cracks with thermal effect in PV module. The micro-cracks are increasing the breakage risk over the whole value chine from the wafer to the finished module, because the wafer or cell is exposed to mechanical stress. we experimentally analyze the direct impact of micro-cracks on the module power and the consequences after artificial aging. The first step, we made micro-cracks in PV module by mechanical load test according to IEC 61215. Next, PV modules applied the thermal cycling test, because microcracks accelerated aging by thermal cycling test. according to IEC61215. Before every test, we checked output and EL image of PV module.

  • PDF

XLPE 절연체에서의 열이력에 의한 전기, 물리적 특성 평가 (Estimation of Electrical & Physical Characteristics by Thermal History in XLPE Insulation)

  • 이상진;심성익;전승익
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2008년도 Techno-Fair 및 합동춘계학술대회 논문집 전기물성,응용부문
    • /
    • pp.183-184
    • /
    • 2008
  • The aim of this study is to find out the effects of thermal aging condition on dielectric strength and degree of crtstallinity of XLPE insulation. Thermal properties of XLPE insulation were investigated by DSC(differential scanning calorimetry) and dielectric strength were analyzed using AC BDV tester. Aging of XLPE samples were conducted through different four conditions. The degree of crtstallinity and AC BDV were changed by thermal history. From these results, it can be suggested that DSC and AC BDV test are suitable for diagnostic method of extra high voltage XLPE cable.

  • PDF