• Title/Summary/Keyword: thermal activation

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System Design for Activation of Renewable Energy and Cooperative Renewable Energy Plan Between South and North Korea -Based on the Survey of Renewable Energy Experts- (신.재생에너지 활성화를 위한 제도의 설계와 남북한 신.재생에너지 협력 추진방안 - 전문가 설문에 나타난 신.재생에너지 현황 -)

  • Lim, So-Young;Heo, Eun-Nyeong
    • New & Renewable Energy
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    • v.1 no.3 s.3
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    • pp.24-34
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    • 2005
  • Ministry of Commerce, Industry [MOCIE] has taken it into consideration to introduce a Renewable Portfolio Standard (RPS) that is a purchase obligation program as an alternative plan to the FIT. We conducted a survey of renewable energy companies and experts to ask their opinions about renewable energy policy, the introduction of the RPS, and the scheme for aid of North Korea with renewable energy. Korean renewable energy companies show an impartial opinion about a FIT and a RPS system overall, although they tend to have distinctive opinions by technology each other. With respect to eligible resources for a RPS, the industries want to extend the scope of it as broad as possible. In addition, experts prefer the multi-tiered and energy production based RPS to the sing1e-tiered and installed capacity based RPS. We also conducted a surrey to find the best renewable energy sources. Wind, Geothermal, Solar-thermal, and Photovoltaic were selected to have the best potential capacities to support North Korea by renewable energy experts. However, these energy resources also have several problems to overcome in the aid of North Korea, and thus, the plans for solving them and for giving efficient support to North Korea in the area of Renewable Energy are discussed.

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Formation of N Doped, p-type ZnO Films by Post-annealing in NH3 Ambient (NH3 분위기에서 후속 열처리에 의한 p형 ZnO 형성)

  • Jung, Eun-Soo;Kim, Hong-Seung;Cho, Hyung-Kun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.7
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    • pp.611-617
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    • 2006
  • We report the preparation of N doped, p-type ZnO films by post-annealing in $NH_3$ ambient. The properties were examined by XRD, Hall-effect measurement, PL, and SIMS. ZnO films showed better crystallinity and electron concentration of $10^{15}-10^{17}/cm^3$ with post-annealing in $NH_3$ ambient. These films were converted to p-type ZnO by activation thermal annealing process at $800^{\circ}C$ under $N_2$ ambient. The electrical properties of the p-type ZnO showed a hole concentration of $1.06\times10^{16}/cm^3$, a mobility of $15.8cm^2/V{\cdot}s$, and a resistivity of $40.18\Omega{\cdot}cm$. The N doped ZnO films showed a strong photoluminescence peak at 3.306 eV at 13 K, which is closely related to neutral acceptor bound excitons of the p-type ZnO:N. In the SIMS spectra, the incorporation of nitrogen was confirmed.

Thermal Decomposition of $\beta$$-Sialon by Graphite (이연에 의한 $\beta$$-사이알론의 열분해)

  • 최상흘;이희철;이종진;서규식
    • Journal of the Korean Ceramic Society
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    • v.24 no.5
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    • pp.453-460
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    • 1987
  • β'-sialon(Z=2.7) specimens with <30%wt. graphite as a reducing agent were decomposed at 1350°up to 1,450℃ under the atmosphere of 90% N2-10%H2. The decomposition of β'-sialon was calculated from the change in Z-value, and the formation of new minerals was identified from X-ray diffraction patterns. The decomposition reactions of sialon were considered to yield a stable sialon close to β-silicon nitride and some aluminum compounds according to the following equations; β'-sialon(s)+C(s)+N2(g)→β2-sialon(metastable)+β3-sialon(stalbe phase) β2-sialon(s)+C(s)+N2(g)→β3-sialon(s)+AlN(s)+α-Al2O3(s)+15R(s)+SiO(g)+Al2O(g)+CO(g) Z-value; β2( 3.5)>β'( 2.7)>β3( 0.5) The decomposition rate of sialon was controlled by two mechanisms ; One was characterized by the interface area of contact, corresponding to an apparent activation energy of 50.5Kcal/mol in the initial stage, and the other by the diffusion, corresponding to that of 104.3Kcal/mol in the final stage of the decomposition.

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Growth and photoluminescence of the strained ZnTe/ZnMnTe single quantum well (스트레인을 받는 ZnTe/ZnMnTe 단일양자우물의 성장과 광발광 특성)

    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.6
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    • pp.269-269
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    • 2002
  • ZnTe/ZnMnTe single quantum well of high quality was grown by hot-wall epitaxy, in which ZnMnTe layer was used as a barrier. It was found that ZnTe well layer was under severe strain. Very sharp luminescent peaks of the heavy-hole exciton (el-hhl) and the light-hole exciton (el-lhl) were observed from the photoluminescence (PL) measurement. As the well layer thickness increases, the peaks associated with excitons of (el-hhl) and (el-lhl) were shifted toward the lower energy side. The temperature dependence of the PL peak intensity was well explained by the thermal activation theory.

Growth and photoluminescence of the strained ZnTe/ZnMnTe single quantum well (스트레인을 받는 ZnTe/ZnMnTe 단일양자우물의 성장과 광발광 특성)

  • 최용대
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.6
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    • pp.267-271
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    • 2002
  • ZnTe/ZnMnTe single quantum well of high quality was grown by hot-wall epitaxy, in which ZnMnTe layer was used as a barrier. It was found that ZnTe well layer was under severe strain. Very sharp luminescent peaks of the heavy-hole exciton (el-hhl) and the light-hole exciton (el-lhl) were observed from the photoluminescence (PL) measurement. As the well layer thickness increases, the peaks associated with excitons of (el-hhl) and (el-lhl) were shifted toward the lower energy side. The temperature dependence of the PL peak intensity was well explained by the thermal activation theory.

A Study on Fabrication and Characteristics of $CaSO_4:Tb$ TLD ($CaSO_4:Tb$ TLD의 제작과 특성에 관한 연구)

  • Park, Myeong-Hwan
    • Journal of radiological science and technology
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    • v.22 no.1
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    • pp.55-60
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    • 1999
  • In this study, the highly sensitive $CaSO_4:Tb$ glass capsule type TLDs are fabricated and their trap parameters are determined. The optimum conditions of fabricating of $CaSO_4:Tb$ phosphor was obtained to be in impurity concentration of Tb 1.0 mol% and sintering of $600^{\circ}C$, 2 hr. The glow curve of $CaSO_4:Tb$ consists of three glow peaks and these peaks are isolated by thermal bleaching method. Activation energy of the three glow peaks measured by the initial rise, the peak shape and the heating rate method are 0.70, 0.87, and 1.03 eV. The frequency factors are $1.76{\times}10^9,\;1.74{\times}10^9$, and $9.77{\times}10^8\;s^{-1}$, and the kinetic orders are 1.12, 1.46, and 1.34, respectively. The isolated glow peaks are fitted by least square method and optimum temperature range of the main peak for radiation dosimetry is $230{\sim}295^{\circ}C$.

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Combustion Characteristics of High Moisture Indonesia Coal as a Pulverized Fuel at Thermal Power Plant (미분탄 화력발전소 연료로서 고수분 인도네시아탄의 연소특성)

  • Kim, Jae-Kwan;Lee, Hyun-Dong
    • Journal of the Korean Society of Combustion
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    • v.14 no.3
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    • pp.16-23
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    • 2009
  • It is strongly desired for coal-fired power plants to utilize not only low-rank coals with high moisture contents, but also lowering cost with diversifying fuel sources. In this study, combustion characteristics of low rank coal with high moisture, and standard pulverized coals are experimentally investigated using TGA (Thermogravimetric Analysis) and DTF (drop tube furnace). The coals tested are three kinds of coal with moisture content ranging from 8.32 to 26.82%. The results show that under the air combustion condition, the burn-out time at TGA rises as moisture content increases, and standard pulverized coal with 8.32% moisture content showed the lowest activation energy of 55.73 kJ/mol. In case of the high amount of moisture, the combustion efficiency decreases due to evaporation heat loss, and unburned carbon in ash produced at combustion process in DTF increased. Aslo, initial deformation temperature of slag attached in alumina tube of DTF decreased with lowering the crytallinity of anorthite and augite. To improve the combustion reactivity and efficiency, it is effective to upgrade through drying the high moisture coal to moisture level (less than 10%) of standard pulverized coal.

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Optimum Reaction Kinetics Model of Heat-resistant and Flame-Retardant Polymethyl Methacrylate (내열 및 난연성 Polymethyl Methacrylate의 최적 반응속도 모델에 관한 연구)

  • Kim, Dong-Keun;Seul, Soo-Duk;Sohn, Jin-Eon
    • Elastomers and Composites
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    • v.22 no.4
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    • pp.324-332
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    • 1987
  • The thermal degradation of the homopolymer poly(methyl methacrylate) (PMMA) and flame-retardant tetrabrormobisphenol-A(TBBA) as well as of their blends were carried out using the thermogravimetric method in the stream of nitrogen gas with 60ml/min at various heating rate from 1 to $20^{\circ}C/min$. Friedman and Ozawa mathematical methods were used to obtain the value of activation energy.

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Effects of SO2 Mixture in Inlet Air on Combustion and Exhaust Emission Characteristic in diesel engine (디젤엔진에 있어서 흡기 중에 SO2혼입이 연소 및 배기배출물 특성에 미치는 영향)

  • Yoo, Dong-Hoon
    • Journal of Power System Engineering
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    • v.19 no.2
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    • pp.64-69
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    • 2015
  • Marine diesel engines with high thermal efficiency and fuel diversity used for propulsive power have been taking charge of important position on marine transport. However, marine environment has recently focused on emissions such as nitrogen oxide and sulfur oxide which is generated from combustion of low grade fuels. EGR(Exhaust gas recirculation) system is one of effective methods to reduce the nitrogen oxide emission from marine diesel engines. In general, it is considered that recirculating gas influences fuel combustion and emissions in diesel engines. However, along with positive effects of EGR, the EGR system using fuels of including high sulfur concentration should be considered about re-combustion and activation of sulfur dioxide in recirculating gas. Therefore, in experimental study, an author investigates effects of sulfur dioxide mixture concentration in intake air on combustion and exhaust emission characteristics in a direct injection diesel engine. In results, change of sulfur dioxide concentrations in intake air had negligible impact on combustion chamber pressure, rate of heat release and emissions compared with effects of oxygen decreasing and carbon dioxide increasing of EGR.

Study on high performance cathode on YSZ electrolyte for intermediate-temperature solid oxide fuel cells(IT-SOFC) (중온형 고체산화물 연료전지를 위한 YSZ 전해질에서의 고성능 공기극 연구)

  • Lee, Chang-Bo;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.368-371
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    • 2006
  • [ $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ ] cathode as a high performance cathode on YSZ electrolyte was studied by analyzing impedance spectra. It was shown that cathode property of $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ is bet ter than that of$La_{0.8}Sr_{0.2}CoO_3$. At $700^{\circ}C$ in air environment, $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_3$ cathode on CGO- layered YSZ electrolyte showed very low area specific resistance of $0.14{\Omega}cm^2$, which is low enough for intermediate-temperature sol id oxide fuel cells. This is because material properties of ionic conductivity and thermal expansion compatibility with electrolyte were optimized. Judging from activation energy and oxygen part i al pressure dependance of cathode property, it was noted that oxygen surface exchange kinetics is dominantly influential on cathode property in higher temperature region than $700^{\circ}C$ and oxygen self-diffusion in cathode material is more influential in lower temperature region.

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