• 한국대기환경학회지
• /
• 제7권3호
• /
• pp.169-179
• /
• 1991

Atmospheric $O_3$ in the biosphere is formed under the favourable meteorological condition, when the primary pollutants, such as $NO_2, HC, CO, CH_4$, etc., react with over constituents. Observed annual average concentrations for 1989 and 1990 were 11.8 and 10.4 ppb, respectively. THe number of days measured ozone over 80 ppb in Seoul were 36 in 1989 and 39 in 1990. In general, monthly maximum values occurred in May and August. In comparison with 1 $\sim$ 2 maxima of $O_3$ distribution in large cities in other countries, it was found that there were 3 $\sim$ 4 maxima in Seoul and its suburbs. Topographic effects, resulted by wind channelling in the Han River valley and by the blocking of air pollutants in the mountain, appeared to produce multiple centres of $O_3$ maxima in Seoul. Surface $O_3$ values were low with decreasing solar radiation, when the cloudiness increased and precipitation occurred. According to 12 cases examined, 2 cases shown here, $O_3$ values exceeding 80 ppb were occurred when the Korean peninsular was under the influence of the backside airflows with high intensity of solar radiation. Occasionally, sea breezes were observed to occur in warm seasons, and the chanelling effect of the Han River valley appeared to increase the general wind (speed) to the east side of Seoul. In this meso-scale situation $O_3$ in downwind is highly correlated with precursors. The sea breeze of 2 $\sim$ 4 m $s^{-1}$ will take 3 $\sim$ 5 hours to transport photochemical precursors for 20 $\sim$ 50 km. In turn the areas of maximum $O_3$ occurrence in Seoul are in the range of meso-scale transport of air pollutants.

• 에너지공학
• /
• 제26권4호
• /
• pp.45-56
• /
• 2017

Coal power plants produce electricity for the nation's power grid, but they also produce more hazardous air emissions than any other industrial pollution sources. The quantity is staggering, over 386,000 tons of 84 separate hazardous air pollutants spew from over 400 plants in 46 states. In South Korea also, annual coal ash generation from coal-fired power plants were about 6 million tons in 2015. Pollutants containing particulate matter 10, 2.5 (PM10, PM2.5), heavy metals and dioxins from coal-fired power plant. The emissions threaten the health of people who live near these power plants, as well as those who live hundreds of miles away. These pollutants that have long-term impacts on the environment because they accumulate in soil, water and animals. The present study is to investigate the physical and chemical characteristics of coal-fired power plant fly ash and bottom ash contains particulate matter, whose particulate sizes are lower than $PM_{10}$ and $PM_{2.5}$ and heavy metals. There are wide commercial technologies were available for monitoring the PM 2.5 and ultra-fine particles, among those carbonation technology is a good tool for stabilizing the alkaline waste materials. We collected the coal ash samples from different coal power plants and the chemical composition of coal fly ash was characterized by XRF. In the present laboratory research approach reveals that potential application of carbonation technology for particulate matter $PM_{10}$, $PM_{2.5}$ and stabilization of heavy metals. The significance of this emerging carbonation technology was improving the chemical and physical properties of fly ash and bottom ash samples can facilitate wide re use in construction applications.

• 한국환경과학회지
• /
• 제14권11호
• /
• pp.1035-1047
• /
• 2005

By using hourly $NO_2$ concentration data$(1998\~2000)$ at the Busan Metropolitan City air qualify monitoring sites, characteristics of daily mean value of $NO_2$ concentration was discussed in space and time. The correlation between $NO_2$ concentration and other relating air pollutants was analyzed by using SAS program and meteorological parameters as well. After choosing representative 4 areas, this study used hourly concentration data$(1998\~2000)$ from air quality monitoring sites on $NO_2,\;NO,\;O_3,\;CO,\;SO_2\;and\;PM_{10}$. Typical metropolitan characteristics of two peaks in a day was shown in the variation of $NO_2$ concentration of Busan city.

• 한국대기환경학회:학술대회논문집
• /
• 한국대기환경학회 2003년도 추계학술대회 논문집
• /
• pp.247-248
• /
• 2003

Tunable diode laser absorption spectroscopy (TDLAS) has been widely used in environmental monitoring of gaseous species in the past decade. TDLAS is a direct measurement technique for pollutants such as NOx without any interference from other species. Because of its superior spectral purity (～0.001 ­$cm^{-1}$), absorption linewidths with resolvable rotational structure can be studied in the mid infrared region where strong fundamental vibrational transitions of molecules appear. (omitted)

• 한국환경보건학회:학술대회논문집
• /
• 한국환경보건학회 2004년도 International Conference Global Environmental Problems and their Health Consequences
• /
• pp.223-226
• /
• 2004

Building materials emit high concentration volatile organic compounds(VOCs), formaldehyde(HCHO) and other hazardous air pollutants(HAPs) to indoor environment. Average value of VOCs and HCHO emission concentration were $3,770\;{\mu}g/m^3$, $430\;{\mu}g/m^3$ in newly buildings, respectively. VOCs and HCHO emission characteristic are high emission level at initial time and decreased in course of time.

• 한국환경보건학회지
• /
• 제31권5호
• /
• pp.349-359
• /
• 2005

In this study, we focused on the geographical and the meterological conditions, the atmospheric examination, the soil contents and compositions in order to establish cultural properties conservation plan in Gyeongju and its surroundings. Also, the transport route with environmental contaminants in Ulsan and Pohang was examined. The results could be summarized as follows ; Air pollutant and environmental contaminant was transported by two types of winds. One is induced by local winds, the other is induced by synoptic winds. Air contaminant transported from coastal regions to inland regions were associated with wind velocity. Gyeongju had good atmospheric conditions, i.e. $SO_2\;0.009{\sim}0.011ppm,\;CO\;0.6{\sim}0.8ppm,\;NO_2\;0.015{\sim}0.020ppm,\;O_3\;0.017{\sim}0.032ppm,\;PM_{10}\;46{\sim}62{\mu}g/m^3\;and\;Pb\;0.034{\sim}0.060{\mu}g/m^3$, which was below environmental air qualify standards and was little lower than those of Pohang and Ulsan. However, Ulsan and Pohang city are located on south-east coast and have many industrial facilities. Hence, air pollution problems become serious issues in Ulsan, Pohang, Busan, Daegu and other cities due to the emission of air pollutants from the various industrial facilities, incinerator and power plants, etc. The soil of Gyeongju had heavy metals conditions, i.e. $Cd\;0.01{\sim}0.08mg/kg,\;Cu\;N.D{\sim}2.39mg/kg,\;As\;N.D{\sim}0.07mg/kg,\;Hg\;N.D{\sim}0.15mg/kg,\;Pb\;0.49{\sim}1.39mg/kg,\;Cr^{+6}\;0.02{\sim}0.42mg/kg,\;Fe\;0.74{\sim}1.55mg/kg,\;Mn\;0.11{\sim}0.49mg/kg\;and\;Zn\;1.11{\sim}3.56mg/kg$. However, pH value of soil had range of $4.12{\sim}7.45$. The results showed that high pH concentration of soil could occur due to air pollution diffusion and environmental contaminant transport at Ulsan and Pohang city.

• 한국환경보건학회지
• /
• 제13권2호
• /
• pp.9-24
• /
• 1987

This study was conducted to measure the diurnal variation and behaviour of atmospheric mercury in an urban area by gold amalgamation and cold vapour atomic absorption spectrophotometry. The results were as follows: 1. The Hg concentration in ambient air averaged. 21.13ng/m$^3$ for 111 determinations (C.V. 78.5) in urban area and 5.91ng/m$^3$ for 140 determinations (C.V. 21.3) in suburban area. The urban area concentration was significantly higher and fluctuated more than its rural counterpart. 2. Regression analysis of the interaction between mercury concentration and other components showed a significant correlation between mercury concentration and sulfur dioxide also, TSP were found. Mercury concentration was shown to have a similar behaviour, on the whole, with other air pollutants. 3. It demonstrated a positive correlation with sunlight (UV-ray), while it had a negative response to wind speed and humidity. Its concentration showed a tendensy to increase during calm weather specifically. 4. The Hg concentration at the Mt. Dok You inland clean area ranged from 1.33ng/m$^3$ to 2.0ng/m$^3$, with a mean value of 1.63ng/m$^3$.

• 한국환경보건학회지
• /
• 제30권2호
• /
• pp.92-97
• /
• 2004

Three methods for VOCs emissions control in indoor air are reduction at the source, ventilation between indoor and outdoor, and removal. The best alternative should be to replace highly emitting sources with sources having low emissions, but the pertinent information on VOCs is not always available from manufactures. Other ways of improving indoor air quality are needed. It is to increase the outside fresh-air flow to dilute the pollutants, but this method would generally provide only a dilution effect without destruction in residence. An ideal alternative to existing technologies would be a chemical oxidation process able to treat large volumes of slightly contaminated air at normal temperature without additional oxidant such as ozone generator and ion generator. Photocatalytic oxidation(PCO) represents such a process. It is characterized by a surface reaction assisted by light radiation inducing the formation of superoxide, hydroperoxide anions, or hydroxyl radicals, which are powerful oxidants. In comparison with other VOCs removal methods, PCO offers several advantages. The purpose of this study was to explore the possibilities for photocatalytic purification of slightly contaminated indoor air by using visible light such as flurescent visible light(FVL). In this study, a PCO of relatively concentrated benzene using common FVL lamps was investigated as batch type and total volatile organic compounds(TVOCs) using a common FVL lamp and penetrated sun light over window. The results of this study shown the possibility of TiO$_2$ photocatalyst application in the area of indoor air quality control.

• 한국환경보건학회지
• /
• 제32권4호
• /
• pp.292-303
• /
• 2006

The Volatile Organic Compounds(VOCs) are emitted from various sources and have lots of different form. Recently human are spending the many times at indoor area and indoor air pollution is issued the important social problem. The emission sources of indoor air pollutants are very various, also indoor building materials are composed of very complex chemical compounds, these indoor building materials discharge very much VOCs and other hazardous compounds. In this study, we performed the small chamber test to investigate the VOCs emission concentration and characteristics involving five kinds of the indoor building materials(furniture material, wooden floor, wall paper, paint and tile) under different conditions of four temperature and relative humidity as account of the air flow rate(AFR), air exchange rate(AER), loading factor and air velocity respectively. As the result, It was showed that building materials are emitted the highest VOCs concentration at the beginning of experiment and furniture material is emitted the highest VOCs concentration. Most of the materials were affected by temperature, but paint and tile material were affected by humidity.

• 한국대기환경학회지
• /
• 제29권4호
• /
• pp.459-476
• /
• 2013

Receptor models have been rapidly developed to manage the ambient air quality and to establish effective emission reduction strategies. The models are used to identify various emission sources and apportion quantitatively the ambient pollutant mass based on various measured physico-chemical properties of the air pollutants at the receptor site. Many types of receptor models have been applied to estimate source contributions since those provide fundamental information when establishing reasonable environmental policies in Korea and Foreign countries. In this paper, we will introduce the basic concept and principal of the receptor model, various types of existing models with discussing strong and weak points for each model, and performance procedure of PMF model as the most popular model in the world. Further the trends of receptor modeling studies in Korea and other countries were provided. Finally, the improvement directions of the modeling works for the national and local air quality management were suggested in this paper.