• Bulletin of the Korean Chemical Society
• /
• v.35 no.9
• /
• pp.2694-2698
• /
• 2014

A multisegmented polystyrene (PS) with pH-cleavable ester and carbamate linkages was successfully synthesized by a combination of atom transfer radical polymerization (ATRP) and Cu(I)-catalyzed 1,3-dipolar cycloaddition of azide and alkynes (click chemistry). ATRP was employed to synthesize polystyrene from hydroxyl-terminated initiator using CuBr/N,N,N',N",N"-pentamethyldiethylenetriamine (PMDETA) as the catalyst. The reaction of the resulting PS with sodium azide yielded the azido-terminated polymer. The hydroxyl group in the other end of the polymer was reacted with 4-nitrophenyl chloroformate (NPC), followed by reaction with propargylamine to produce an alkyne end group with a carbamate linkage. The PS with an alkyne group in one end and an azide group in the other end was then self-coupled in the presence of CuBr/2,2'-bipyridyl (bpy) in DMF to yield a desired multisegmented PS. Molecular weight and molecular weight distribution of the self-coupled polymer increased with time, as in the typical step-growth-type polymerization processes. Finally, we demonstrated that the ester and carbamate linkages of the multisegmented PS were hydrolyzed in the presence of HCl to yield individual PS chains.

• IEMEK Journal of Embedded Systems and Applications
• /
• v.15 no.1
• /
• pp.25-33
• /
• 2020

Multipath routing protocols with unmanned aerial vehicles have been proposed to improve reliability in tactical ad hoc networks. Most of existing studies tend to establish the paths with multiple metrics. However, these approaches suffer from link loss and congestion problems according to the network condition because they apply same metric for both ground and air path or employ the simple weight value to combine multiple metrics. To overcome this limitation, in this study, we propose new routing metrics for path over unmanned aerial vehicles and use the multi-criteria decision making (MCDM) method to determine the weight factors between multiple metrics. For the case studies, we extend the ad-hoc on-demand distance vector protocol and propose a strategy for modifying the route discovery and route recovery procedure. The simulation results show that the proposed mechanism is able to achieve high end-to-end reliability and low end-to-end delay in tactical ad hoc networks.

• Polymer(Korea)
• /
• v.38 no.6
• /
• pp.774-781
• /
• 2014

Acetylenic or phenylethynyl end-capped polyisoimide oligomers ($M_w$ 2500 g/mol, 5000 g/mol) based upon 4,4'-diamino diphenyl ether (4,4'-ODA)/4,4'-oxydiphthalic anhydride (ODPA) and 4,4'-ODA/3,3',4,4'-benzophenone tetracarboxylic acid dianhydride (BTDA) were synthesized by using 4-ethynylaniline (4-EA) or 4-phenylethynyl phthalic anhydride (4-PEPA) as an end capper. The incorporation of ethynyl groups were confirmed by FTIR spectroscopy. The isomerization temperature was influenced by molecular weight as well as the backbone structure of polyisoimides oligomers. Thus, polyisoimide oligomers with molecular weight of 2500 g/mol was found to be imidized at temperature $10^{\circ}C$ lower than that for the oligomers with molecular weight of 5000 g/mol. The crosslinking reaction of ethynyl groups occurred at a higher temperature than that for the isoimide/imide isomerization reaction. These two reactions were totally or partially overlapped on the DSC thermograms for the polyisoimide oligomer end-capped with 4-EA. Kinetics of thermal imidization and crosslinking reactions for the 4,4'-ODA/ODPA polyisoimide oligomers end-capped with 4-PEPA were investigated by performing dynamic DSC experiments at heating rate of $10^{\circ}C/min$. The activation energy and pre-exponential factors were 141 kJ/mol and $1.45{\times}10^{13}min^{-1}$ for the imidization reaction and 177 kJ/mol and $2.90{\times}10^{13}min^{-1}$ for the crosslinking reaction, respectively.

• Journal of Ginseng Research
• /
• v.12 no.2
• /
• pp.145-152
• /
• 1988

Correlations between various morphological characteristics of Panax quinquefolium plants grown in Lytton, British Columbia, Canada were assessed for 1-through 4-year old plants. Root dry weight, the dependent variable, was found to be strongly related to leaf dry weight, leaf length and root length for 1-and 2-year old plants during the middle of the growing season. For 1- and 2-year old plants at the end of the growing season, root dry weight was found to be related to leaf dry weight, leaf length and stem dry weight. For 3 and 4-year old plants, root dry weight was found to be related to leaf dry weight, leaf length and stem dry weight. For 3- and 4-year old plants, root dry weight was found to be related to leaf dry weight. For practical considerations, this latter relationship provides a simple method for selecting superior plants from which seed can be harvested.

• Journal of Biosystems Engineering
• /
• v.26 no.4
• /
• pp.331-336
• /
• 2001

This study was to develop a kerosene flame weeder. An air compressor was driven though the PTO of a tractor to provide necessary air for fuel combustion and proper pressure to supply fuel from fuel tank to the nozzle. It was found that the flame was extinguished very easily by wind and vibration of the tractor. This trouble could be solved by attaching a burner cap, which is a modified venturi tube, at the end of the nozzle. The constructed flame weeder was tested for the weeding capability in the prepared field. Weed extinction rate and weight decrease rate were analysed. Measured maximum flame temperature was 1,121$\^{C}$ when the fuel consumption was 13.41 kg/h and fuel supply pressure was 88.2 kPa. The maximum temperature occurred at 20cm from the front end the burner, and it decreased to 46$\^{C}$ as the distance increased to 110cm. The flame length of up to 70cm, where the flame temperature was higher than 372$\^{C}$, would be used for weeding purpose. Weed extinction rate and weight decreasing rate increased as the fuel consumption increased. The flame weeder was evaluated to be a practical weeder through improvement as the weed extinction rate and weight decrease rate were analysed to be 75% and 85%, respectively when the fuel consumption was 116.87kg/ha.

• Nutrition Research and Practice
• /
• v.6 no.2
• /
• pp.126-131
• /
• 2012

The purpose of this study was to determine the effects of beverage temperature and composition on weight retention and fluid balance upon voluntary drinking following exercise induced-dehydration. Eight men who were not acclimated to heat participated in four randomly ordered testing sessions. In each session, the subjects ran on a treadmill in a chamber maintained at $37^{\circ}C$ without being supplied fluids until 2% body weight reduction was reached. After termination of exercise, they recovered for 90 min under ambient air conditions and received one of the following four test beverages: $10^{\circ}C$ water (10W), $10^{\circ}C$ sports drink (10S), $26^{\circ}C$ water (26W), and $26^{\circ}C$ sports drink (26S). They consumed the beverages ad libitum. The volume of beverage consumed and body weight were measured at 30, 60, and 90 min post-recovery. Blood samples were taken before and immediately after exercise as well as at the end of recovery in order to measure plasma parameters and electrolyte concentrations. We found that mean body weight decreased by 1.8-2.0% following exercise. No differences in mean arterial pressure, plasma volume, plasma osmolality, and blood electrolytes were observed among the conditions. Total beverage volumes consumed were $1,164{\pm}388$, $1,505{\pm}614$, $948{\pm}297$, and $1,239{\pm}401$ ml for 10W, 10S, 26W, and 26S respectively ($P$ > 0.05). Weight retention at the end of recovery from dehydration was highest in 10S ($1.3{\pm}0.7kg$) compared to 10W ($0.4{\pm}0.5kg$), 26W ($0.4{\pm}0.4kg$), and ($0.6{\pm}0.4kg$) ($P$ < 0.005). Based on these results, carbohydrate/electrolyte-containing beverages at cool temperature were the most favorable for consumption and weight retention compared to plain water and moderate temperature beverages.

• Asian-Australasian Journal of Animal Sciences
• /
• v.9 no.4
• /
• pp.421-426
• /
• 1996

Comparison of body weight changes of does infected with Haemonchus contortus (treatment groups 2 &3) and uninfected does (control group) was made using weekly body weight measurements over 35 weeks. The animals in treatment group 2 weighted significantly (p < 0.05) less than animals in the control group from the 5th week to the end of the experiment. Does in treatment group 3 had significantly (p < 0.05) lighter body weight than control does from the 13th week to the end of the study. The animals in control group gained an average of 0.75 kg. On the other hand, animals in infected groups 2 and 3 lost an average of 3.90 kg and 4.13 kg body weight, respectively. The animals in groups 2 and 3 also had significantly (p < 0.05) lower preslaughter and hot carcass weights than the controls.

• Journal of Nutrition and Health
• /
• v.16 no.4
• /
• pp.263-272
• /
• 1983

Effects of dietary protein qualify, energy restriction, and subsequent rehabilitation were studied in the weanling rats. Rats were devided into the six experimental diet groups. Rats in AC (casein- containing diet ), AS (soyprotein-containing diet), and AG(gluten-containing diet) group consumed their diets ad libitum, and rats in PC, PS, PG groups were pair-fed in 60% of the of amounts eaten by corresponding rats in the AC, AS, AG groups, respectively. After 3 weeks of nutritional restriction, all rats were switched to the AC diet for 14 days. At the end of restriction period, body weight, weight gain, food intake, and FER were higher in casein- fed rats than other groups of rats. The differences were, however, disappeared with rehabilitation diet, except body weights which were not fully recovered until the end of experiment. The weights of liver, gastrocnemius muscle, kidney, small intestine, spleen, and lung were the highest in the casein group, and the lowest in gluten group at the end of restriction period. The recovery with rehabilitation diet were differ in different organs. The muscle and liver seemed to be the most affected organs by dietary protein quality and energy restriction. There were no differences in brain weights among the experimental groups during the restriction period, however, after 2 weeks of rehabilitation, rats in AC group showed lower brain weight compared to AC and AS groups, and the brain weight of PC group was lower than AC group. Protein contents in liver and muscle showed the same trends as their weights. Gluten-fed rats showed low serum protein concentration, but recovered fully with rehabilitation diet for 3 days.

• Journal of Ginseng Research
• /
• v.37 no.2
• /
• pp.187-193
• /
• 2013

The effect of Korean red ginseng (KRG) on diabetic renal damage was investigated using streptozotocin (STZ)-induced diabetic rats. The diabetic rats showed loss of body weight gain, and increases in kidney weight and urine volume, whereas the oral administration of KRG at a dose of 100 or 250 mg/kg of body weight per day for 28 d prevented these diabetes-induced physiological abnormalities. Among the kidney function parameters, elevated plasma levels of urea nitrogen and creatinine in diabetic control rats tended to be lowered in KRG-treated rats. In addition, administration of KRG at a dose of 100 mg/kg body weight in the diabetic rats showed significant decreases in serum glucose and tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$), implying that KRG might prevent the pathogenesis of diabetic complications caused by impaired glucose metabolism and oxidative stress. KRG also significantly reduced advanced glycation end product (AGE) formation and secretion from kidney of diabetic rats. Furthermore, KRG decreased the levels of N-(carboxymethyl) lysine and expression of AGE receptor. KRG also reduced the overexpression of cyclooxygenase-2 and inducible nitric oxide synthase in the kidney via deactivation of nuclear factor-kappa B. We also found that KRG prevented STZ-induced destruction of glomerular structure and significantly suppressed high glucose-induced fibronectin production. Taken together, KRG ameliorates abnormalities associated with diabetic nephropathy through suppression of inflammatory pathways activated by TNF-${\alpha}$ and AGEs. These findings indicate that KRG has a beneficial effect on pathological conditions associated with diabetic nephropathy.

• Clinical Endoscopy
• /
• v.56 no.3
• /
• pp.333-339
• /
• 2023

Background/Aims: Intragastric balloon (IGB) is the only available endoscopic bariatric and metabolic therapy in Korea. End-ball (Endalis) has the longest history of clinical use among the IGBs available in Korea. However, little clinical data on this system have been reported. In this study, we aimed to evaluate the efficacy and safety of End-ball in Korea. Methods: We performed a retrospective cohort study of patients who underwent IGB insertion (End-ball) from 2013 to 2019. Demographic and anthropometric data were collected. The efficacy and safety of IGB treatment were analyzed. Results: In total, 80 patients were included. Mean age was 33.7 years and 83.8% were female. Initial body mass index was 34.48±4.69 kg/m². Body mass index reduction was 3.72±2.63 kg/m² at the time of IGB removal. Percent of total body weight loss (%TBWL) was 10.76%±6.76%. Percentage excess body weight loss was 43.67%±27.59%. Most adverse events were minor, and 71.4% of participants showed nausea, vomiting, or abdominal pain. Conclusions: IGB treatment showed good efficacy and safety profile in Korean patients with obesity. In terms of %TBWL and percentage excess body weight loss, the efficacy was similar to that in the Western population.