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Nitric Oxide Detection of Fe(DTC)3-hybrizided CdSe Quantum Dots Via Fluorescence Energy Transfer

  • Chang-Yeoul, Kim
    • Journal of Powder Materials
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    • v.29 no.6
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    • pp.453-458
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    • 2022
  • We successfully synthesize water-dispersible CTAB-capped CdSe@ZnS quantum dots with the crystal size of the CdSe quantum dots controlled from green to orange colors. The quenching effect of Fe(DTC)3 is very efficient to turn off the emission light of quantum dots at four molar ratios of the CdSe quantum dots, that is, the effective covering the surface of quantum dots with Fe(DTC)3. However, the reaction with Fe(DTC)3 for more than 24 h is required to completely realize the quenching effect. The highly quenched quantum dots efficiently detect nitric oxide at nano-molar concentration of 110nM of NO with 34% of recovery of emission light intensity. We suggest that Fe(DTC)3-hybridized CdSe@ZnS quantum dots are an excellent fluorescence resonance energy transfer probe for the detection of nitric oxide in biological systems.

Temperature-dependent Morphology of Self-assembled InAs Quantum Dots Grown on Si Substrates (Si 기판 위에 형성된 InAs 양자점의 열처리에 의한 표면 상태의 변화)

  • Yoo, Choong-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.10
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    • pp.864-868
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    • 2007
  • Effect of high-temperature annealing on morphology of fully coherent self-assembled InAs quantum dots' grown on Si (100) substrates at $450^{\circ}C$ by atmospheric pressure metalorganic chemical vapor deposition(APMOCVD) was investigated by atomic force microscopy(AFM). When the dots were annealed at 500 - 600$^{\circ}C$ for 15 sec - 60 min, there was no appreciable change in the dot density but the heights of the dots increased along with the reduction in the diameters. In segregation from the InAs quantum dots and/or from the 2-dimensional InAs wetting layer which was not transformed into quantum dots looked responsible for this change in the dot size. However the change rates remained almost same regardless of annealing time and temperature, which may indicate that the morphological change due to thermal annealing is done instantly when the dots are exposed to high temperature annealing.

Influence of the Size of Polka Dots on the Image of Clothes -Focused on One-piece Dress- (물방울무늬의 크기가 의복이미지에 미치는 영향 -원피스드레스를 중심으로-)

  • Choi, Hye-Won;Ryoo, Sook-Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.5 s.164
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    • pp.742-752
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    • 2007
  • The purpose of this study is the image of clothing according to the change of the dots' size was analyzed and its influence on the formation of the image of polka dots clothing was investigated. White waterdrop patterns were designed on the 12 kinds of black texture using Photoshop and CAD program in regular arrangement of diamond figure, composed of white waterdrop(0.5cm, 1.0cm, 1.5cm and 2cm in diameter) and interval(diameter : interval-1 : 1, 1 : 2, 1 : 4). Applying above specification, the photograph stimulus of 12 kinds of X-line one-piece dress with wide square neckline and without sleeve or detailed ornament was presented on a screen in the same size as when putting it on. The image of polka dots clothes was investigated by questionnaire survey. The object of the study was 320 females aged between 16 and 29. Factor analysis, one-way ANOVA, $Scheff\acute{e}$ verification and two-way ANOVA using SPSS 10.0 were carried out for data analysis. Followings are the results: 1) The image of polka dots clothing consists of 4 factors as aesthetics, brevity, dynamism and lightweight. 2) The size of the dot has a great influence on the formation of the image of polka dots clothing. 3) The evaluations of the image of polka dots clothing were different depending on the age and physical image, the personal characteristics of the object of investigation.

The Influence of the Interval of Polka Dots on the Image of Clothes - Focused on One-Piece Dress - (물방울무늬의 간격이 의복이미지에 미치는 영향 - 원피스드레스를 중심으로 -)

  • Choi, Hye-Won;Ryoo, Sook-Hee
    • Fashion & Textile Research Journal
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    • v.9 no.3
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    • pp.278-285
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    • 2007
  • The purpose of this study is the image of clothing according to the change of the dots' interval was analyzed and its influence on the formation of the image of polka dots clothing was investigated. White waterdrop patterns were designed on the 12 kinds of black texture using Photoshop and CAD program in regular arrangement of diamond figure, composed of white waterdrop(0.5 cm, 1.0 cm, 1.5 cm and 2 cm in diameter) and interval(diameter : interval - 1 : 1, 1 : 2, 1 : 4). Applying above specification, the photograph stimulus of 12 kinds of X-line one-piece dress with wide square neckline and without sleeve or detailed ornament was presented on a screen in the same size as when putting it on. The image of polka dots clothes was investigated by questionnaire survey. The object of the study was 320 females aged between 16 and 29. Factor analysis, one-way ANOVA, Scheff$\acute{e}$ verication and two-way ANOVA using SPSS 10.0 were carried out for data analysis. The research finding are as follows. First, the image of polka dots clothing consists of 4 factors as aesthetics, brevity, dynamism and lightweight. Secondly, the interval of the dot has a great influence on the formation of the image of polka dots clothing. Lastly, the evaluations of the image of polka dots clothing were different depending on the age and physical image, the personal characteristics of the object of investigation.

Characteristic of Yellow Dots that detected on Color Laser Printer (컬러 레이저 프린터에서 검출되는 Yellow Dots의 특성 : HP 컬러 레이저 프린터를 중심으로)

  • Choi, Young-Ho;Lee, Doek-Ho;Yoon, Young-Mi;Hong, Heon-Sich;Shin, Jong-Yeon;Yoon, Kee-Hyung
    • The Journal of the Korea Contents Association
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    • v.12 no.12
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    • pp.639-646
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    • 2012
  • To analyzed the shape of Yellow Dots which appeared on the paper printed HP color laser printer, and analyzed the characteristic of Yellow Dots according to time, month, year and same printers. As a result, documents that printed in same printers had an identical Yellow Dots's shapes according to time, month, year. It was presupposed that was not embedded time and date information in HP Color LaserJet printers against Xerox, and printers which have different serial number had similar shapes but it was not identical Yellow Dots. Finally, it was found to be identical patterns in Yellow Dots of HP Color LaserJet printers used analysis. Depending on the results, it could understand HP's pattern. In the future, it will decipher patterns of Yellow Dots which have other informations to include other printer manufacturer.

Interband optical properties in wide band gap group-III nitride quantum dots

  • Bala, K. Jaya;Peter, A. John
    • Advances in nano research
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    • v.3 no.1
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    • pp.13-27
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    • 2015
  • Size dependent emission properties and the interband optical transition energies in group-III nitride based quantum dots are investigated taking into account the geometrical confinement. Exciton binding energy and the optical transition energy in $Ga_{0.9}In_{0.1}N$/GaN and $Al_{0.395}In_{0.605}N$/AlN quantum dots are studied. The largest intersubband transition energies of electron and heavy hole with the consideration of geometrical confinement are brought out. The interband optical transition energies in the quantum dots are studied. The exciton oscillator strength as a function of dot radius in the quantum dots is computed. The interband optical absorption coefficients in GaInN/GaN and AlInN/AlN quantum dots, for the constant radius, are investigated. The result shows that the largest intersubband energy of 41% (10%) enhancement has been observed when the size of the dot radius is reduced from $50{\AA}$ to $25{\AA}$ of $Ga_{0.9}In_{0.1}N$/GaN ($Al_{0.395}In_{0.605}N$/AlN) quantum dot.

All-optical Polarization Phase Modulation in Coupled Quantum Dots

  • Je, Ku Chul;Kyhm, Kwangseuk
    • Current Optics and Photonics
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    • v.1 no.1
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    • pp.60-64
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    • 2017
  • We have considered optical nonlinearities of coupled quantum dots theoretically, where an exciton dipole-dipole interaction is mediated between the adjacent large and small quantum dots. For increasing a pump pulse area in resonance with the large quantum dot exciton the induced nonlinear refractive index of the small quantum dot exciton has been obtained. As the exciton dipole-dipole interaction depends on the relative orientation of two exciton dipoles, the optical nonlinearities for the directions parallel and perpendicular to the coupling axis of the two quantum dots are compared. The directional imbalance of optical nonlinearities in coupled quantum dots can be utilized for a polarization phase modulator by controlling a pump pulse area and propagation length.

Recent Developments in Synthesis of Colloidal Quantum Dots (콜로이드 양자점 합성의 다양한 연구 개발 동향)

  • Jung, Jae-Yong;Hong, Jong-Pal;Kim, Young-Kuk
    • Journal of Powder Materials
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    • v.25 no.4
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    • pp.346-354
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    • 2018
  • Over the last decade, the study of the synthesis of semiconductor colloidal quantum dots has progressed at a tremendous rate. Colloidal quantum dots, which possess unique spectral-luminescent characteristics, are of great interest in the development of novel materials and devices, which are promising for use in various fields. Several studies have been carried out on hot injection synthesis methods. However, these methods have been found to be unsuitable for large-capacity synthesis. Therefore, this review paper introduces synthesis methods other than the hot injection synthesis method, to synthesize quantum dots with excellent optical properties, through continuous synthesis and large capacity synthesis. In addition, examples of the application of synthesized colloid quantum dots in displays, solar cells, and bio industries are provided.

Colloidal synthesis of IR-Iuminescent HgTe quantum dots (콜로이드 합성법에 의한 HgTe 양자점의 제조와 특성 분석)

  • Song, Hyun-Woo;Cho, Kyoung-Ah;Kim, Hyun-Suk;Kim, Sang-Sig
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.31-34
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    • 2002
  • HgTe quantum dots were synthesized in aqueous solution at room temperature by colloidal method. The synthesized materials were identified to be zincblende cubic structured HgTe quantum dots by X-ray diffraction and transmission electron microscopy image revealed that these quantum dots are agglomerate of a individual particle. The colloidally prepared HgTe quantum dots have the sphere-like shape with a diameter of approximately 4 nm. The optical properties of the HgTe quantum dots were investigated with photoluminescence(PL). The PL appears in the near-infrared region, which represent a dramatic shift from bulk HgTe behavior. The analytic results revealed that HgTe quantum dots have the broad size distribution, as PL emission spectrum covers the spectral region from 900 to 1400 nm. In this study, the factors affecting PL of HgTe quantum dots and particle size distributiont are described.會Ā᐀䁇?⨀젲岒Ā㰀會Ā㰀顇?⨀끩Ā㈀會Ā㈀?⨀䡪ఀĀ᐀會Ā᐀䡈?⨀Ā᐀會Ā᐀ꁈ?⨀硫ᜀĀ저會Ā저?⨀샟ගऀĀ저會Ā저偉?⨀栰岒ఀĀ저會Ā저ꡉ?⨀1岒Ā저會Ā저J?⨀惝ග؀Ā؀會Ā؀塊?⨀ග嘀Ā切會Ā切끊?⨀⣟ගĀ搀會Ā搀ࡋ?⨀큭킢Ā저會Ā저恋?⨀桮킢Ā저會Ā저롋?⨀⣅沥ࠀĀࠀ會Āࠀ၌?⨀샅沥Ā저會Ā저桌?⨀壆沥ሀĀ저會Ā저쁌?⨀o킢瀀ꀏ會Āᡍ?⨀棤좗ĀĀĀ會ĀĀ灍?⨀å좗ĀĀĀ會ĀĀ졍?⨀飥좗ĀĀĀ會ĀĀ⁎?⨀?ꆟᤀ

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The Fluorescence Immunoassay of lung Cancer Serum Diomarkers using Quantum dots

  • Kang, Ji-Min;Ahn, Jin-Seok;Kim, Jin-Hoon;Kong, Won-Ho;Park, Keun-Chil;Kim, Won-Seog;Seo, Soo-Won
    • Journal of Biomedical Engineering Research
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    • v.30 no.2
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    • pp.122-128
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    • 2009
  • Cancer serum biomarkers have advanced our ability to more accurately predict tumor classification, prognostic/metastatic potential, and response potential to novel chemotherapies. Serum amyloid A (SAA) and Vascular endothelial growth factor (VEGF) have potential utility as a serum biomarker for lung cancer. Quantum dots, nanometer-sized crystals, have a high quantum yield, sensitivity, and pronounced photostability. The properties of quantum dots can be efficiently applied to the detection of serum biomarkers in immunoassays as fluorescent probe. We used quantum dots as fluorescent probes in immunoassays and attempted to detect serum amyloid A and vascular endothelial growth factor as serum biomarkers of lung cancer. This fluorescence immunoassay based on the properties of quantum dots is applicable to the detection of serum biomarkers for lung cancer. The fluorescence immunoassay with quantum dots should allow the efficient and specific detection of serum amyloid A (SAA) for the possible diagnosis of lung cancer.