• 제목/요약/키워드: the advanced chemical resistance test method

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장기성능 평가를 위한 토목섬유 화학저항성 시험 고찰 (Consideration of Geosynthetics Chemical Resistance Test for Long-Term Performance Evaluation)

  • 전한용;장연수;공학봉
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2009년도 춘계 학술발표회
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    • pp.222-232
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    • 2009
  • In this study, the real site test conditions were considered and applied to suggest the improved test method for geosynthetics chemical resistance. For this, index and performance tests were done to specify and regulate the more approached test method. Accelerated model by Arrhenius equation was applied to interpretate the experimental data. Through analysis and comparison the overall experimental results, we could suggest the possibility and setup the advanced chemical resistance test method for geosynthetics.

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장기성능 평가를 위한 토목섬유 화학저항성 시험 고찰 (Consideration of Geosynthetics Chemical Resistance Test for Long-Term Performance Evaluation)

  • 전한용;장연수
    • 한국지반공학회논문집
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    • 제25권7호
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    • pp.55-64
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    • 2009
  • 본 연구에서는 실제 현장조건을 고려하여 토목섬유의 화학저항성을 측정하기 위한 개선된 시험방법이 제안되었다. 이를 위하여 시공조건에 가장 근접한 시험법을 규격화하기 위한 인덱스 및 성능시험이 실시되었으며, Arrhenius 식에 의한 가속모델을 적용하여 실험 데이터를 해석하였다. 전반적인 실험 결과를 분석, 비교하여 현장 시공조건에 부합한 개선된 토목섬유의 화학저항성 시험방법을 확립하고 그 가능성을 제시하였다.

알루미늄 6061 합금 양극산화 후 열처리에 따른 표면 특성 관찰 (Effects of Heat Treatment on Surface Properties of Aluminum 6061 Alloy After Anodization)

  • 이승민;정찬영
    • Corrosion Science and Technology
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    • 제21권6호
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    • pp.495-502
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    • 2022
  • Anodization is a representative electrochemical surface treatment method that can improve both heat resistance and corrosion resistance by forming an anodization film on the surface of the aluminum. However, these properties can be changed after an additional heat treatment process. In this study, Al 6061 was subjected to an anodization process at 60 V for 1 hour, 5 hours, or 9 hours. An additional heat treatment process was performed at 500 ℃ for 30 minutes. Field emission scanning electron microscopy (FE-SEM) analysis revealed that the thickness of the anodized film was increased in proportion to the anodization time. Both pore size and pore diameter of the anodized film was also increased after anodization. After an additional heat treatment process, there were no significant changes in the thickness, pore size, or pore diameter of the anodized film. Heat resistance was confirmed through thermal analysis and chemical resistance was evaluated with a potentiodynamic polarization test.

자동차 냉각기 호스용 고무의 전기화학적 복합노화시험 (An Electro-chemical Combined-stress Degradation Test of Rubber for Automotive Radiator Hoses)

  • 곽승범;서부석;최낙삼
    • 한국자동차공학회논문집
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    • 제19권4호
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    • pp.107-113
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    • 2011
  • Coolant rubber hoses for automotive radiators under thermal and mechanical loadings can be degraded and thus failed due to the influences of the locally formed electricity. In this study, an advanced test method was developed to simulate the failure problem of the rubber hose. For carbon black filled EPDM (ethylene-propylene dine monomer) rubber used as a radiator hose material the ageing behaviors by the electro-chemical stresses combined with a tensile strain were analyzed. As the tensile strain increased, the current of the rubber specimen reduced indicating an increase of the internal defects and electrical resistance of the rubber specimen. Elongation at break and IRHD hardness rapidly decreased with increasing the ageing time. Both electro-chemical stress and mechanical tensile stress clearly accelerated the degradation of EPDM rubber.

인히비터 첨가용액의 침지에 의한 용융아연도금 강판의 내식성 개선에 관한 전기화학적 연구 (An Electrochemical Study on the Corrosion Resistance Improvement of Galvanizing Steel by Dipping to Solution with Inhibitor)

  • 문경만;조황래;강태영;이명훈;김윤해
    • Journal of Advanced Marine Engineering and Technology
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    • 제31권2호
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    • pp.173-181
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    • 2007
  • Recently, galvanizing method is predominantly being used not only a economical point of view but also due to it s stability and long life. For example, guard rail of high way, all kinds of structures for ship etc. were protected with galvanizing and demand of galvanized structural materials was being increased with more and more. However, galvanized structures were inevitably being deteriorated with time eventually because they were corroded with solution of galvanizing film and exfoliation of it s film in the present severe corrosive environment. Therefore, it is necessary to improve the corrosion resistance of the galvanizing film through various methods such as variation of chemical composition of galvanizing bath, chromate treatment and coating treatment. In this study, three test specimens such as pure galvanizing, galvarium, and chromate treatment were submerged at tap water with inhibitor addition. And the effect of their corrosion resistance improvement was comparatively investigated with electrochemical method. Corrosion current density of the galvanized steel was the largest among three specimens, however, the galvarium steel showed the lowest corrosion current density. Futhermore, these three kinds of test specimens indicated considerably excellent corrosion resistance by dipped at tap water with inhibitor addition. Especially, the galvanized steel showed the best effect of corrosion resistance improvement than other test specimens.

막 오염 저항성이 우수한 분리막을 이용한 MBR 시스템의 실증화 기술개발 (Development of MBR System Commercialization Technology Using a Membrane with a Good Fouling Resistance)

  • 최정환;이정빈;김인철
    • 멤브레인
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    • 제18권1호
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    • pp.35-43
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    • 2008
  • 본 연구를 통하여 나노입자를 분리막의 표면에 함침시킴으로써 MBR 공정상에서 가장 큰 문제인 막 오염 문제를 해결하고자 하였고 실제 제작된 분리막의 현장적용 테스트를 거쳐서 개발된 분리막의 막 오염 저항성질을 확인하였다. 실험과정은 본 연구를 통한 티타니아가 함침된 분리막 제품과 국외의 타사 제품과의 장시간 현장적용 테스트를 통해 본 연구 제품의 우수성을 확인할 수 있었다. 본 연구 제품은 활성슬러지의 농도가 $7,000{\sim}13,000mg/L$의 고농도인 조건에서 $20{\sim}25L/m^2{\cdot}hr$의 투과유량을 꾸준하게 유지하는 것을 확인할 수 있었다. 이와 아울러 막과 막사이의 배치거리, 막과 산기관의 배치거리, 산기관의 홀 크기, 세정액의 농도 및 처리 방법 등에 따른 분리막의 투과유량의 거동 등을 살펴보았다. 즉 이들 부수적인 변수들의 최적화를 통해 분리막의 물성을 극대화할 수 있는 방법을 모색해 보았다.

교류임피던스법에 의한 Nimonic 80A 초내열합금 시효열처리재의 부식거동 고찰 (The Corrosion Behavior Study by AC Impedance Method for the Aging Heat Treated Nimonic 80A Superalloy)

  • 백신영
    • Journal of Advanced Marine Engineering and Technology
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    • 제23권6호
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    • pp.761-769
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    • 1999
  • In this paper the effect of aging heat treatment to the Corrosion behavior for the Nimonic 80A superalloy was studied by AC Impedance methods. Tested solution was 3.5% with tempera-ture $25^{\circ}C$ Electro-chemical corrosion test were carried out for the Nimonic 80A super-alloy which solution heat treated at $1080^{\circ}C$ for 8 hours followed by aging heat treated at $650^{\circ}C,\;700^{\circ}C,\;750^{\circ}C\;800^{\circ}C$ and $850^{\circ}C$ with 16hours under vacuum environment. The obtained results were as follows; 1. Base metal and solution-treated materials were exhibited similar corrosion tendency as Ran-dle equivalent cell. The value of passive film resistance was 579 ohms for the base metal and 124,770 ohms for the solutionized metal such a difference was arose by the ${{\gamma}_^'}$ precipitate on the metal surface during heat treatment. 2. The measure value of $R_p$ for heat-treated at $650^{\circ}C,\;700^{\circ}C,\;800^{\circ}C$and $850^{\circ}C$ were 97,943, 93, 111, 26,961, 15,798 and 11,780ohm respectively. Which indicated that the passive film resistance Rp was reduced as aging temperature increased due to the growth of grain size and sensitization at the grain boundary. 3. The similar tendency was exhibited for corrosion behavior of the electro-chemical corrosion polarization method and AC impedance method and confirmed that AC impedance method was useful tool for corrosion research.

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카테콜기가 도입된 헤파린의 표면고정화에 의한 아데노연관바이러스의 발현 억제에 관한 연구 (Significant Attenuation of Aden-associate Virus Gene Expression by Catechol-conjugated Heparin Surface Coating)

  • 도민재;이슬기림;장재형;이해신
    • 접착 및 계면
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    • 제17권4호
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    • pp.149-154
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    • 2016
  • 일반적으로, 화학 물리적 변성이 수반되는 멸균방법을 적용하지 못하는 경우 필터여과에 의한 멸균 방법을 주로 사용한다. 하지만 바이러스의 경우 100 nm의 작은 크기로 인해 박테리아 제거에 사용되는 필터여과에 의한 멸균 방법을 적용하기가 어렵다. 본 논문에서는 화학 물리적 변성 없이 바이러스를 비활성화하는 물질 개발을 위하여, 카테콜기가 도입된 헤파린 고분자(Hep-C)를 합성하였다. Hep-C의 바이러스 비활성화 효과를 알아보기 위해서 표면이 노르에피네프린으로 코팅된 조직배양접시에 아데노연관바이러스(Adeno-associated virus; AAV)를 고정화하였으며, 그 위에 다시 Hep-C를 코팅하여 녹색형광단백질(GFP) 유전자를 전달할 수 있는 AAV의 비활성화 정도를 유세포분석기(FACS)를 이용하여 분석하였다. 그 결과 AAV에 Hep-C를 도포하면 99%에 달하는 비활성화 효과를 보였으며, 헤파린 고분자를 도포한 결과에 비해 강한 염 저항성을 확인할 수 있었다. 이러한 결과로 미루어 보아 제조된 Hep-C는 AAV 바이러스 제거의 효과적 방법으로 충분한 가능성을 가짐을 증명하였다.

자동차 냉각기 호스용 EPDM 고무의 전기화학적 복합노화시험 및 고장메커니즘 (Electrochemical Combined-Stress Degradation Test and Failure Mechanisms of EPDM Rubber for Automotive Radiator Hoses)

  • 곽승범;최낙삼;신세문
    • 대한기계학회논문집A
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    • 제37권1호
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    • pp.1-8
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    • 2013
  • 자동차용 냉각기 고무호스는 열과 기계적 하중을 받으면서 국부적으로 형성된 전기적 영향으로 인해 노화와 고장이 발생한다. 본 연구에서는 개선된 시험방법을 이용하여 고무호스의 파괴거동을 재현하였다. 냉각기 고무호스 재료인 카본블랙이 함유된 EPDM 고무를 사용하여 인장응력과 전기화학적 복합 스트레스를 가하여 노화거동을 분석하였다. 노화 시간에 따른 전류 및 저항의 변화거동을 관찰하였으며 인장 변형 스트레스와 전압 및 노화온도 조건에 따른 노화거동을 분석하였다. 고무 시험편을 수직면으로 정밀하게 절단하여 시험편 표면 및 내부의 변화거동을 분석하여 전기화학적 노화거동과 고장메커니즘을 규명하였다.

액상소결법에 의한 탄화규소 제조시 소결조제와 온도의 영향 (Influence of Sintering Additives and Temperature on Fabrication of LPS-SiC)

  • 정헌채;윤한기
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.266-270
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    • 2004
  • SiC materials have been extensively studied for high temperature components in advanced energy system and advanced gas turbine because it has excellent high temperature strength, low coefficient of thermal expansion, good resistance to oxidation and good thermal and chemical stability etc. However, the brittle characteristics of SiC such as low fracture toughness and low strain-to fracture still impose a severe limitation on practical applications of SiC materials. For these reasons, SiC/SiC composites can be considered as a promising for various structural materials, because of their good fracture toughness compared with monolithic SiC ceramics. But, high temperature and pressure lead to the degradation of the reinforcing jiber during the hot pressing. Therefore, reduction of sintering temperature and pressure is key requirements for the fabrication of SiC/SiC composites by hot pressing method. In the present work, monolithic Liquid Phase Sintered SiC (LPS-SiC) was fabricated by hot pressing method in Ar atmosphere at $1800^{\circ}C$ under 20MPa using $Al_2O_3,\;Y_2O_3\;and\;SiO_2$ as sintering additives in order to low sintering temperature and sintering pressure. The starting powder was high purity $\beta-SiC$ nano-powder with all average particle size of 30mm. The characterization of LPS-SiC was investigated by means of SEM and three point bending test. Base on the composition of sintering additives-, microstructure- and mechanical property correlation, tire compositions of sintering additives are discussed.

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