• Title/Summary/Keyword: the Quaternary

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Determination of Betaine from Saliconia herbacea L. (함초(Saliconia herbacea L.)로부터 베타인 정량)

  • Lee, Chang-Ho;Kim, In-Ho;Kim, Young-Eon;Oh, Se-Wook;Lee, Ho-Jun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.9
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    • pp.1584-1587
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    • 2004
  • The betaine content of Saliconia herbacea L. was determined by reverse-phase high performance chromatog-raphy on a C_(18) column. A 50% methanol extract was passed through a anion exchanger Ambelite IRA 400 (quaternary ammonium type, OH-) column and a strong cation exchanger Ambelite IR 120 (sulfonic acid type, $H^+$) column to remove amino acids, zwitter ions which are interfere with betaine analysis. The betaine extract was derivatized with 18-crown-6-ether and 4-bromophenacyl bromide (PBPB) for UV-labelling. Betaine in Saliconia herbacea L. was analysed on a mobile phase contained 13 mM sodium heptane sulfonic acid and 5 mM $Na_2SO_4$ in deionized water by isocratic elution for 30 min. The recovery ratio of betaine from Saliconia herbacea L. extract was 83.6%. The mean betaine value for Saliconia herbacea L. determined by the described method is 4.85 mg/mL with a standard deviation of 0.127.

Resistive Humidity Sensor from Copolymers Containing Quaternary Ammonium Salt (II): Four Component Copolymers (4차 암모늄염을 포함하는 공중합체를 이용한 저항형 습도센서 (II) : 4원 공중합체)

  • Lee, Dong-Geun;Lim, Tae-Ho;Jeon, Young-Min;Gong, Myoung-Seon
    • Polymer(Korea)
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    • v.31 no.4
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    • pp.302-307
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    • 2007
  • The resistive-type humidity sensors were prepared from the copolymers of [2-[(methacryloyloxy)ethyl]dimethyl]propylamonium bromide (MEPAB), [2-[(methacryloyloxy)ethyl]-2-hydroxyethyl]dimethylammonium bromide (MEHDAB), 2- [(methacryloyloxy)ethyl]trimethylammonium chloride (METAC), and n-butyl methylacrylate (MBA). Four component copolymers MEPAB/BMA/MEHDAB/METAC=4/4/1/1, 3/5/1/1, 2/6/1/1, 1/7/1/1 crosslinked with blocked-isocyanate on Ag/Pd electrode/alumina substrate showed a good durability at high humidities. The various electrical properties such as frequency dependency, temperature dependency, hysteresis, response time and water durability were examined. In the case of copolymer composed of MEPAB/BMA/MEHDAB/METAC=2/6/1/1, the resistance varied from $1.4\;M{\Omega}$ to $2.9\;k{\Omega}$ at $25^{\circ}C$ in the range of $30{\sim}90\;%RH$ and this copolymers showed a good linearity and low hysteresis.

Evaluation for Efficacies of Commercial Sanitizers and Disinfectants against Bacillus cereus Strains

  • Kim, Il-Jin;Ha, Ji-Hyoung;Kim, Yong-Su;Kim, Hyung-Il;Choi, Hyun-Chul;Jeon, Dea-Hoon;Lee, Young-Ja;Kim, Ae-Jung;Bae, Dong-Ho;Kim, Keun-Sung;Lee, Chan;Ha, Sang-Do
    • Food Science and Biotechnology
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    • v.18 no.2
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    • pp.537-540
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    • 2009
  • Bactericidal efficacies of various sanitizers and disinfectants against 10 Bacillus cereus strains isolated from Korean foods and 8 standard B. cereus strains were investigated. The sanitizing capabilities of ethanol, iodine, chloride, quaternary ammonium, hydrogen peroxide, and peroxide acetic acid were investigated using the EN 1276 method based on quantitative suspension testing. The resistance against sanitizers and disinfectants was higher for wild-type than standard strains, and the bactericidal activities decreased in dirty conditions. Ethanol, chlorine, and iodine at the maximum level allowed under Korean food sanitation laws showed a great effectiveness against B. cereus. Hydrogen peroxide at 1,100 ppm showed the lowest bactericidal activity against B. cereus. These results indicate that the legally allowed maximum concentrations of sanitizers and disinfectants in Korea do not reduce all B. cereus strains by at least $5\;{\log}_{10}\;CFU/mL$.

Fabrication of poly(ethylene oxide)/clay nanocomposites using supercritical fluid process (초임계 공정을 이용한 폴리에틸렌옥사이드/클레이 나노복합체 제조)

  • Kim, Yong-Ryeol;Jeong, Hyeon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.143-150
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    • 2014
  • Recently, supercritical fluid process has been widely used in material synthesis and processing due to their remarkable properties such as high diffusivity, low viscosity, and low surface tension. Supercritical carbon dioxide is the most attractive solvent owing to their characteristics including non-toxic, non-flammable, chemically inert, and also it has moderate critical temperature and critical pressure. In addition, supercritical carbon dioxide would dissolve many small organic molecules and most polymers. In this study, we have prepared the poly (ethylene oxide)/clay nanocomposites using supercritical fluid as a carbon dioxide. Commercialized Cloisites-15A and Cloisites-30B used in this study, which are modified with quaternary ammonium salts. The nanocomposites of polymer/clay were characterized by XRD, TGA and DSC. Poly (ethylene oxide)/clay nanocomposites by supercritical fluid show higher thermal stability than nanocomposites prepared by melt process. In addition, supercritical fluid process would be increased dispersibility of the nanoclay in the matrix.

Rate of Sediment Accumulation and Geochemical Characteristics of Muddy Sediment in the Central Yellow Sea (황해 중앙부 해역 니질 퇴적물의 지화학적 특성 및 퇴적률)

  • 윤정수;김여상
    • The Korean Journal of Quaternary Research
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    • v.16 no.1
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    • pp.1-16
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    • 2002
  • A total of 4 muddy sediment samples collected from the Central Yellow Sea were analyzed for chemical composition. The results are compared with the previously published Huanghe, Changjiang and Keum River geochemical data in order to understand provenance and sedimentation of fine-grained mud, and the sediment accumulation rates estimated. The sandy sediment facies is distributed in the eastern area, a patch of fine-grained mud exists in the western central prat, and the sandy mud and clay sedimentary facies shot. north to south zonal distribution in the central region. The content of calcium carbonate ranges from 2.8 to 10.5%, and its distributional trends to be more concentrated on the western muddy sediments near toward the China side rather than on the eastern sandy sediments. The accumulation rates obtained using Pb-210 geochronologies for the muddy sediments in the Central Yellow Sea showed ranges from 0.21 to 0.68 cm/yr or 0.176 to 0.714 g/$\textrm{cm}^2$. yr. The sedimentation rate from core CY96010 located in the eastern near side of Shandong Peninsula which is affected by the Huanghe River shows 0.68 cm/yr or 0.714 g/$\textrm{cm}^2$ . yr. The sediment cores CY96008 and CY96002 in the Central Yellow Sea, the estimated of sediment accumulation rates shows 0.21~0.23cm1yr or 0.176~0.220 9/$\textrm{cm}^2$.Vr respectively, which are much lower than above samples. These indicate that the muddy sediments in central area of the Yellow Sea may have received influence of the sediment discharge from the Huanghe River. The concentrations of Ca, Na, Sr, Ho, La, Tb, Ta and Ca/Ti ratio of the muddy sediments in the Central Yellow Sea are higher than those of the Changjiang sediments and lower than those of the Huanghe sediments. However, these element values showed similar concentration patterns than those of the Huanghe sediment. The element contents such as Fe, Ti, Nl, Co, Cr, Cu, Pb, Sc, Ce, Nd, Sm, Eu, Cd and Dy in the study area are higher than those of the Huanghe sediments and lower than the Changjiang River sediments, but these values showed close to resemblance content trends those of the Changjiang sediment. The concentration of Mn, K and Sr in sediments of the study area are similar to those of the Keum River and eastern Yellow Sea sediment. They are rich in Zn, Rb, Cd, U, Cs and Li than those of the other comparison legions. Therefore, the terrigenous materials sources of the muddy sediment in the Central Yellow Sea comes mainly from Huanghe River in the past and present, and also have party derived from the Changjiang and Keum River, while the biological deposit in this area are carried by the Yellow Sea Warm Current.

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Geology and Metallic Mineral Resources of Sinaola State in Mexico (멕시코 시나올라주의 지질 및 금속광물자원)

  • Nam, Hyeong-Tae;Heo, Chul-Ho
    • Economic and Environmental Geology
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    • v.46 no.3
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    • pp.257-266
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    • 2013
  • The geology of Sinaola state consists of Precambrian metamorphic rocks(Sonobari Complex), two Paleozoic units(lower non-differentiated metamorphic rocks and upper Carboniferous sedimentary rocks), five Mesozoic units(metavolcanic, clastic, and calcareous rocks), Cenozoic volcanic rocks, and Quaternary clastic sediments and volcanic flows. The Sinaola state is potentially rich in metallic mineral resources with lower degree of non-metallic mineral resources. They are related to a variety of geological environments and are mainly physiographically located on the Sierra Madre Occidental. Mainly known mineral deposits are of gold and silver followed by zinc, lead, copper and some iron. The state also has deposits of molybdenum, tungsten and bismuth that have been occasionally exploited. There is a reference of nickel and cobalt mineralization, but these deposits have been exploited only at a small scale.

Antimicrobial Efficacies of Citra-Kill®, Disinfectant Solution against Salmonella Typhimurium and Brucella Ovis

  • Cha, Chun-Nam;Lee, Yeo-Eun;Son, Song-Ee;Yoo, Chang-Yeul;Kim, Suk;Lee, Hu-Jang
    • Journal of Environmental Health Sciences
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    • v.37 no.6
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    • pp.482-487
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    • 2011
  • Salmonellosis and brucellosis have caused a considerable danger of farmed animals and economic loss in animal farming industry. In this study, the disinfection efficacy of Citra-Kill$^{(R)}$, a commercial disinfectant, composed to quaternary ammonium chloride and citric acid was evaluated against S. typhimurium and Brucella ovis. A bactericidal efficacy test by broth dilution method was used to determine the lowest effective dilution of the disinfectant following exposure to test bacteria for 30 min at $4^{\circ}C$. Citra-Kill$^{(R)}$ and test bacteria were diluted with distilled water (DW), hard water (HW) or organic matter suspension (OM) according to treatment condition. On OM condition, the bactericidal activity of Citra-Kill$^{(R)}$ against S. typhimurium and Brucella ovis was lowered compared to that on HW condition. As Citra-Kill$^{(R)}$ possesses bactericidal efficacy against animal pathogenic bacteria such as S. typhimurium and Brucella ovis, this disinfectant solution can be used to control the spread of animal bacterial diseases.

Pressure Sensitive Adhesive Properties of Blends of Acrylic Quarternary Copolymer with Vinyl Chloride-Vinyl Propionate Copolymers (아크릴계 4원 공중합체와 염화비닐-비닐프로피오네이트 공중합체와의 블렌드의 점착물성)

  • Oh, Dae-Hee;Seo, Kwan-Ho
    • Elastomers and Composites
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    • v.34 no.4
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    • pp.360-365
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    • 1999
  • In this study, the blends of acrylic quaternary polymer (PEBEV) which was co- polymerized from 2-ethylhexyl acrylate (2-EHA), n-butyl acrylate (BA) and ethyl acrylate (EA), vinyl acetate (VAc), and poly(vinyl chloride-co-vinyl propionate) (PVCVP) were prepared by solution blending. Pressure sensitive adhesive (PSA) properties of PEBEV/PVCVP blends were compared with those of PEBEV/poly(vinyl chloride-co-vinyl acetate) (PVCVAc) blends. Compatibility of PEBEV/PVCVP was better than that of PEBEV/PVCVAc. Tackiness of both blend systems were similar, but holding power began to decrease at 15wt% or higher PVCVAc contents in PEBEV/PVCVAc blends. On the other hands, holding power of PEBEV/PVCVP increased as the contents of PVCVP increased. Failure modes of the blends were adhesive failure except 5wt% of PVCVP was blended.

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The Late Quaternary Pollen Analysis of Gokgyo River Basin in Asan-City, Korea - Focused on Vegetation and Climate Environment between the Last Glacial Maximum and the Late Glacial - (충남 아산 곡교천 유역의 제4기 후기 화분분석 - 최종빙기 최성기~만빙기 식생 및 기후환경에 주목하여 -)

  • PARK, Ji-Hoon;KIM, Sung-Tae
    • Journal of The Geomorphological Association of Korea
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    • v.20 no.1
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    • pp.11-20
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    • 2013
  • The pollen analysis was performed targeting the valley plain alluvium of Jangjae-ri, Asan area in order to clarify the climate and vegetation environment of the Last glacial maximum and the Late glacial in terms of Gokgyo River Watershed In Asan-City, Korea. The sample collection point gets included in the current deciduous broadleaf forest zone (south cool temperate zone). The results are as follows. (1) The vegetation environment of about 19,300-14,100yrB.P. at the investigation area is mainly classified into YJ-I period and YJ-II period while YJ-Ia period is classified once again into YJ-Ia period and YJ-Ib period. YJ-Ia period (19,300-17,500yrB.P.) is correlated with the Last Glacial Maximum while the vegetation at the time has relatively a little wide distribution area of grassland compared to the forest and the forest vegetation of this time period is the mixed conifer and deciduous broad-leaved forest. YJ-Ib period (15,400-14,750yrB.P.) is correlated with the Late glacial (or the Last Glacial Maximum) and the distribution area of grassland became wider compared to the forest. While the forest vegetation of this time period is the mixed conifer and deciduous broad-leaved forest, a difference exists in terms of the dominant tree species. YJ-II period (about 14,650-14,100yrB.P.) is correlated with the Last glacial while the distribution area of grassland became even wider than the forest compared to the YJ-Ib in case of the vegetation at the time and the forest vegetation of this time period is the coniferous forest. (2) Both YJ-I period and YJ-II period were relatively cold and dry compared the End of Late Glacial (about 12,000-10,000yrB.P.)~Early Holocene (10,000-8,500yrB.P.), Also, YJ-II period was relatively colder than the YJ-I period and the YJ-Ib period was relatively more humid than the YJ-Ia period.

Study on the Distributional Characteristics and Classification of Quaternary Monogenetic Volcanoes in Jeju Island, Korea (제주도에 분포하는 제4기 단성화산체의 형태적 분류 및 분포 특성 연구)

  • Lee, Jeong-Hyun;Yun, Sung-Hyo
    • The Journal of the Petrological Society of Korea
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    • v.21 no.4
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    • pp.385-396
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    • 2012
  • Jeju island is the biggest volcanic island in Korea and there are over 455 Quaternary monogenetic volcanoes, of which approximately 373 volcanoes(82.0%) are cinder cones. Other volcanic forms in the island include sharp-pointed lava cone without crater(9 volcanoes; 2.0%), shield volcanoes(27 volcanoes; 5.9%), tuff rings(17 volcanoes; 3.7%), tuff cones(3 volcanoes; 0.7%), a maar(1 volcano; 0.2%) and lava domes(25 volcanoes; 5.5%). The monogenetic volcanoes include 15 small nested cinder cones(aloreum). The monogenetic volcanoes are more abundant in the eastern part of the island than in the western part. If the main cause of the weathering such as precipitation affected the shape of the monogenetic volcanoes, more monogenetic volcanoes(BC, CC, DC, etc.) are supposed to be present in the southern part that have more precipitation than in the northern part. But the distribution of the monogenetic volcanoes shows no difference between the southern and the northern parts. So we suggest that the difference of the climatic conditions did not affect the distribution or the shape of cinder cones. Tuff rings, tuff cones and a maar are distributed beneath the island or in the low-altitude areas along the shore although cinder cones are distributed in the interior of the island. This means that the volcanic activity which formed the monogenetic volcanoes resulted from either phreatomagmatic eruption or magmatic (hawaiian or strombolian) eruptions depending on the reaction with water (underground water or shallow waters). The distribution of the monogenetic volcanoes according to the altitude shows that 253(55.6%) volcanoes occur in low-lying coastal areas at an altitude below 300 m, 110(24.2%) in a middle mountainous area at an altitude between 300~600 m and 92(20.2%) in a high mountainous area at an altitude above 600 m. So more than half of monogenetic volcanoes are distributed in low-lying coastal areas.