• Journal of Environmental Science International
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• v.23 no.3
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• pp.359-368
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• 2014

The aim of our research was to apply experimental design methodology in the optimization of N, N-Dimethyl-4-nitrosoaniline (RNO, which is indictor of OH radical formation) degradation using gas mixing-circulation plasma process. The reaction was mathematically described as a function of four independent variables [voltage ($X_1$), gas flow rate ($X_2$), liquid flow rate ($X_3$) and time ($X_4$)] being modeled by the use of the central composite design (CCD). RNO removal efficiency was evaluated using a second-order polynomial multiple regression model. Analysis of variance (ANOVA) showed a high coefficient of determination ($R^2$) value of 0.9111, thus ensuring a satisfactory adjustment of the second-order polynomial multiple regression model with the experimental data. The application of response surface methodology (RSM) yielded the following regression equation, which is an empirical relationship between the RNO removal efficiency and independent variables in a coded unit: RNO removal efficiency (%) = $77.71+10.04X_1+10.72X_2+1.78X_3+17.66X_4+5.91X_1X_2+3.64X_2X_3-8.72X_2X_4-7.80X{_1}^2-6.49X{_2}^2-5.67X{_4}^2$. Maximum RNO removal efficiency was predicted and experimentally validated. The optimum voltage, air flow rate, liquid flow rate and time were obtained for the highest desirability at 117.99 V, 4.88 L/min, 6.27 L/min and 24.65 min, respectively. Under optimal value of process parameters, high removal(> 97 %) was obtained for RNO.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.6 no.1
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• pp.50-56
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• 2010

Fatigue has been known as a major degradation mechanism of ASME class 1 components in nuclear power plants. Fatigue damage could be accelerated by combined interaction of several loads and environmental factors. However, the environmental effect is not explicitly addressed in the ASME S-N curve which is based on air at room temperature. Therefore many studies have been performed to understand the environmental effects on fatigue behavior of materials used in nuclear power plants. As a part of efforts, we performed low cycle fatigue tests under various environmental conditions and analyzed the environmental effects on the fatigue life of SA508 Gr. 1a low alloy steel by comparing with higuchi's model. Test results show that the fatigue life depends on water temperature, dissolved oxygen and strain rate. But strain rate over 0.4%/s has little effect on the fatigue life. To find the cause of different fatigue life with ANL's and higuchi's model, another test performed with different heat numbered and heat treated materials of SA508 Gr. 1a. On a metallurgical point of view, the material with bainite microstructure shows much longer fatigue life than that with ferrite/pearlite microstructure. And the characteristics of crack propagation as different microstructure seem to be the main cause of different fatigue life.

• Transactions of the Korean Society of Automotive Engineers
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• v.18 no.5
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• pp.115-123
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• 2010

Cool-down performance after soaking is important because it affects passenger's thermal comfort. The cooling capacity of HVAC system determines initial cool down performance in most cases, the performance is also affected by location, and shape of panel vent, indoor seat arrangement. Therefore, optimal indoor designs are required in developing a new car. In this paper, initial cool down performance is predicted by CFD(computational fluid dynamics) analysis. Experimental time-averaging temperature data are used as inlet boundary condition. For more reliable analysis, real vehicle model and human FE model are used in grid generation procedure. Thermal and aerodynamic characteristics on re-circulation cool vent mode are investigated using CFX 12.0. Thermal comfort represented by PMV(predicted mean vote) is evaluated using acquired numerical data. Temperature and velocity fields show that flow in passenger's compartment after soaking is considerably unstable at the view point of thermodynamics. Volume-averaged temperature is decreased exponentially during overall cool down process. However, temperature monitored at different 16 spots in CFX-Solver shows local variation in head, chest, knee, foot. The cooling speed at the head and chest nearby panel vent are relatively faster than at the knee and foot. Horizontal temperature contour shows asymmetric distribution because of the location of exhaust vent. By evaluating the passenger's thermal comfort, slowest cooling region is found at the driver's seat.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.3
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• pp.219-236
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• 2009

Particle-phase organic tracers (molecular markers) have been shown to be an effective method to assess and quantify the impact of sources of carbonaceous aerosols. These molecular markers have been used in chemical mass balance (CMB) models to apportion primary sources of organic aerosols in regions where the major organic aerosol source categories have been identified. As in the case of all CMB models, all important sources of the tracer compounds must be included in a Molecular Marker CMB (MM-CMB) model or the MMCMB model can be subject to biases. To this end, the application of the MM-CMB models to locations where reasonably accurate emissions inventory of organic aerosols are not available, should be performed with extreme caution. Of great concern is the potential presence of industrial point sources that emit carbonaceous aerosols and have not been well characterized or inventoried. The current study demonstrates that emissions from industrial point sources in the St. Louis, Missouri area can greatly bias molecular marker CMB models if their emissions are not correctly addressed. At a sampling site in the greater St. Louis Area, carbonaceous aerosols from industrial point sources were found to be important source of carbonaceous aerosols during specific time periods in addition to common urban sources (i.e. mobile sources, wood burning, and road dust). Since source profiles for these industrial sources have not been properly characterized, method to identify time periods when point sources are impacting a sampling site, needs to avoid obtaining biases source apportionment results. The use of real time air pollution measurements, along with molecular marker measurements, as a screening tool to identify when point sources are impacting a receptor site is presented.

• Atmosphere
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• v.25 no.2
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• pp.353-366
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• 2015

The impact of land and ocean initial condition on coupled general circulation model seasonal predictability is assessed in this study. The CGCM used here is Pusan National University Couple General Circulation Model (PNU CGCM). The seasonal predictability of the surface air temperature and ocean potential temperature for boreal winter are evaluated with 4 different experiments which are combinations of 2 types of land initial conditions (AMI and CMI) and 2 types of ocean initial conditions (DA and noDA). EXP1 is the experiment using climatological land initial condition and ocean initial condition to which the data assimilation technique is not applied. EXP2 is same with EXP1 but used ocean data assimilation applied ocean initial condition. EXP3 is same with EXP1 but AMIP-type land initial condition is used for this experiment. EXP4 is the experiment using the AMIP-type land initial condition and data assimilated ocean initial condition. By comparing these 4 experiments, it is revealed that the impact of data assimilated ocean initial is dominant compared to AMIP-type land initial condition for seasonal predictability of CGCM. The spatial and temporal patterns of EXP2 and EXP4 to which the data assimilation technique is applied were improved compared to the others (EXP1 and EXP3) in boreal winter 2m temperature and sea surface temperature prediction.

• Journal of Environmental Impact Assessment
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• v.21 no.5
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• pp.757-765
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• 2012

The purpose of this study was to estimate the spatial-temporal NPP(Net Primary Productivity) and SCS(Soil Carbon Storage) of forest ecosystem under climate change in the capital area of South Korea using Mapss-Century1 (MC1), one of Dynamic Global Vegetation Models (DGVMs). The characteristics of the NPP and SCS changes were simulated based on a biogeochemical module in this model. As results of the simulation, the NPP varies from 2.02 to 7.43 tC $ha^{-1}\;yr^{-1}$ and the SCS varies from 34.55 to 84.81 tC $ha^{-1}$ during 1971~2000 respectively. Spatial mean NPP showed a little decreasing tendency in near future (2021~2050) and then increased in far future (2071~2100) under the condition of increasing air temperature and precipitation which were simulated by the A1B climate change scenario of Intergovernmental Panel on Climate Change (IPCC). But it was estimated that the temporal change of spatial mean NPP indicates 4.62% increasing tendency in which elevation is over 150m in this area. However, spatial mean SCS was decreased in the two future periods under same climate condition.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.21 no.3
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• pp.35-43
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• 2007

In this paper, the inductive power collector using electromagnetic induction for vehicle such as the PRT(Personal Rapid Transit) system is suggested and son ideas for power collector design to improve tile power transfer performance are presented. And also, the analysis of the inductive power transfer system in conjunction with series resonant converter operating variable high frequency is shown. Of particular interest is the sensitivity of the complete system to variations in operational frequency and parameters. In inductive power transfer system electrical power is transferred from a primary winding in the form of a coil or tract to one or more isolated pick-up coils that my relative to the primary. The ability to transmit power without contact enables high reliability and easy maintenance that allows inductive power transfer system to be implemented in hostile environments. This technology has found application in many fields such as electric vehicles, PRT(Personal Rapid Transit) etc. But, low output power is generated due to a loosely coupled characteristic of the large air-gap. Therefore, we will show you various characteristic of inductive power transfer system as double layer construction of secondary winding, which was divided in half to increase both output current and output voltage, a model of power collector and parallel winding structure, a model of concentration/ decentralization winding and the effects of parameter and operational frequency variation.

• Fashion & Textile Research Journal
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• v.18 no.1
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• pp.120-129
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• 2016

This study aimed to develop an optimal sizing system and a draping pattern for hip protector based on an analysis of anthropometric characteristics of Korean older women. A hip protector is a specialized form of pants or underwear containing pads along the outside of each hip. The 3D body scan data of Korean older women were analyzed to identify their anthropometric characteristics and a four-size system with 93% of population accommodation was developed by clustering analysis based on key dimensions derived from factor analysis. The sizing system consists of small/short, large/short, small/tall, and large/tall. A 3D physical model and hip pads were fabricated; then, a hip protector was draped on the 3D model and hip pads. The sizing system of hip protector was analyzed in terms of size and shape and a draping pattern was compared on back center, back side, front side, front center and pad. Lastly, the pattern deformation and clothing pressure were analyzed using the virtual clothing system CLO. Virtual system have disadvantage of not to suggest the objective value. In the future research the wearing comfort and impact absorption of the hip protector needs to be tested and then a hip protector design will be finalized by considering the hip protector's size, material, comfort testing results, aesthetic appeal, protection effectiveness, and practical utility of everyday use.

• Proceedings of the SAREK Conference
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• 2008.11a
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• pp.561-566
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• 2008

The reciprocating compressor is widely used in the industry field, because it has simple principle and high efficiency. In this work, in order to improve design of discharge passage line in hydrogen compression system Numerical analysis was conducted. General information about an internal gas flow is presented by numerical analysis approach. Relating with hydrogen compressing system, which have an important role in hydrogen energy utilization, this should be a useful tool to observe the flow quickly and clearly. Flow characteristic analysis, including velocity, pressure and turbulence kinetic energy distribution of hydrogen gas going out from the cylinder to discharge-path line are presented in this paper. Discharge-passage model is designed based on real model of hydrogen compressor. Pressure boundary conditions are applied considering the real condition of operating system. The result shows velocity, pressure and turbulent kinetic energy are not distributed uniformly along the passage of the Hydrogen system. Path line or particles tracks help to demonstrate flow characteristics inside the passage. The existence of vortices and flow direction can be precisely predicted. Based on this result, the design improvement might be done.

• Bulletin of the Korean Chemical Society
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• v.21 no.10
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• pp.969-972
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• 2000

[Fe II Fe III $BPLNP(OAc)_2](BPh_4)_2$ (1), a new model for the reduced form of the purple acid phosphatases, has been synthesized by using a dinucleating ligand, 2,6-bis[((2-pyridylmethyl)(6-methyl-2-pyridylmethyl)ami-no)methyl]-4-nitrophenol (HBPLNP) . Complex 1 has been studied by electronic spectral, NMR, EPR, SQUID, and electrochemical methods. Complex 1 exhibits two strong bands at 498 nm $(\varepsilon=$ 2.6 ${\times}10^3M-^1cm-^1)$ and 1363 nm $(\varepsilon=$ 5.7 ${\times}10^2M-^1cm-^1)$ in $CH_3CN.$ These are assigned to phenolate-to-FeIII and intervalence charge-transfer transitions, respectively. NMR spectrum of complex 1 exhibits sharp isotropically shifted resonances, which number is half of those expected for a valence-trapped species, indicating that electron transfer between FeⅡ and FeⅢ centers is faster than NMR time scale at room temperature. Complex 1 undergoes quasireversible one-electron redox processes. The $FeIII_2/FeIIFeIII$ and $FeIIFeIII/FeII_2$ redox couples are at 0.807 and 0.167 V ver-sus SCE, respectively. It has Kcomp = 5.9 ${\times}$10 1s(acetato) ligand combination sta-bilizes a mixed-valence FeIIFeIII complex in the air. Interestingly, complex 1 exhibits intense EPR signals at g = 8.56, 5.45, 4.30 corresponding to mononuclear high-spin FeⅢ species, which suggest a very weak magnetic coupling between the iron centers. Magnetic susceptibility study shows that there is a very weak antiferromag-netic coupling (J = $-0.78cm-^1$, H = $-2JS_1${\times}$S_2)$ between FeII and FeIII centers. Thus, we can suggest that complex 1 has a very weak antiferromagnetic coupling between the iron centers due to the electronic effect of the nitro group in the bridging phenolate ligand.