• 공업화학
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• 제4권3호
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• pp.616-626
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• 1993

유연성과 강인성이 우수하여 탄성체로 널리 사용되어지고 있는 폴리우레탄(PU)을 이용하여 폴리메틸메타크릴레이트(PMMA)의 물성향상을 검토하여 보았다. PU와 PMMA블렌드의 분자량과 폴리올의 종류가 블렌드의 물성과 상용성에 미치는 영향을 관찰하기 위하여, 분자량 또는 폴리올의 종류가 각기 다른 ether type과 ester type의 PU를 합성하여서, 이를 PMMA와 블렌드 하였다. 블렌드의 인장강도는 Instron을 이용하여서 측정하였고, Scanning Electron Microscopy(SEM)와 Differental Scanning Calorimetry(DSC)를 이용하여서 두 고분자의 상용성의 변화에 따른 형태학과 유리전이온도 변화를 측정하였으며, haze meter를 이용하여 투명성을 측정하였다. 그러나, PU와 PMMA 두 고분자의 본질적인 비상용성으로 인하여 블렌드를 통한 PMMA의 물성 개량은 큰 성과를 얻지 못하였다. 따라서 PU와 유사한 화학구조를 가지고 있으면서, 양말단에 비닐기가 도입된 형태인 폴리우레탄 디메타아크릴레이트(PUD)를 합성하여서 메틸메타크릴레이트와 공중합하여 가교 공중합체를 합성하였으며, 이 가교 공중합체의 기계적 물성을 Instron, Izod type(Cantilever Beam)impact tester와 haze meter 등을 이용하여 측정하였다. 그 결과 PMMA 단독수지의 투명성을 유지하면서 내충격성이 상당히 개선된다는 것을 확인할 수 있었다.

• 한국산학기술학회논문지
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• 제17권9호
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• pp.27-33
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• 2016

페놀수지는 열경화성 수지로서 우수한 내열성 및 기계적 물성을 가지고 있다. 하지만 열경화 특성으로 인해 사용 후 재활용이 어렵고, 전체 생산량의 15~20%가 스프루와 런너 형태로 폐기되고 있다. 4만 톤의 페놀수지 스프루와 런너가 버려지고 있으며 폐기된 페놀 스프루와 런너 처리비용은 연간 200억원으로 추정된다. 본 실험에서는 폐기되는 스프루와 런너를 분쇄하고 폴리에틸렌과의 표면접착력 향상을 위해 실란 표면처리를 하였다. 분쇄된 입자의 크기는 100~1000um의 분체와 1~100um의 미분으로 나누어 실험하였다. 분쇄된 페놀은 실란 작용기에 따른 특성을 평가하기 위해 3-(Methacryloyloxy) propyltrimethoxysilane 과 Vinyltrimethoxy silane으로 처리되었다. 입자의 크기를 분석하기 위해 입도분석기를 사용였다. 열적 특성은 DSC(Differential Scanning Calorimetry)와 HDT(heat deflection temperature)를 통하여 분석하였다. 기계적 물성의 측정은 UTM(universal testing machine)과 notched izod impact tester로 평가하였다. 전처리한 페놀수지 파우더를 첨가시, 고밀도 폴리에틸렌(HDPE)의 열변형온도가 $77^{\circ}C$에서 최대 $96^{\circ}C$까지 향상되었으며, 결정화도와 결정화 온도가 증가하였다. 결론적으로, 실란 전처리 하지 않았을 경우와 비교했을 때 충격강도는 50%가 인장강도는 20%가 상승하였다.

• Restorative Dentistry and Endodontics
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• 제28권1호
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• pp.80-88
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• 2003

Object The purpose of this study were to evaluate the microtensile bond strength of resin fiber reinforced post to radicular dentin using resin cement according to various dentin surface treatment and to observe the inter face between post and root dentin under SEM Material and Method A total 16 extracted human single rooted teeth were used. A lingual access was made using a #245 carbide bur in a high-speed handpiece with copious air water spray. The post space was mechanically enlarged using H-file(up to #60) and Gates Glidden bures(#3). This was followed by refining of the canal space using the calbrating drill set provided in ER Dentinpost(GEBR, BRASSELER GmbH&Co. KG). The 16 teeth were randomly distributed into 4 group of 4 teeth. Group 1 teeth had their post space prepared using 10% phosphoric acid as root canal surface treatment agent during 20s. The canal was then rinsed with saline and dried with paper point. Group 2 teeth had their post space prepared using 3% NaOCl as root canal surface treatment agent during 30min. The canal was then rinsed with saline and dried with paper point. Group 3 teeth had their post space prepared using 17% EDTA as root canal surface treatment agent during 1min. The canal was then rinsed with saline and dried with paper point. Group 4 teeth had their post space prepared using 17% EDTA as root canal surface treatment agent during 1min. After rinsing with saline, the canal was rinced 10m1 of 3% NaOCl for 30min. After drying with paper point, the post(ER Dentinpost, GEBR, BRASSELER GmbH&Co. KG) was placed in the treated canals using resin cement. Once the canal was filled with resin cement(Super bond C&B sunmedical co. Ltd.), a lentulo was inserted to the depth of the canal to ensure proper coating of the root canal wall. After 24 hours, acrylic resin blocks($10{\cdot}10{\cdot}50mm$) were made. The resin block was serially sectioned vertically into stick of $1{\cdot}1mm$. Twenty sticks were prepared from each group. After that, tensile bond strengths for each stick was measured with Microtensile Tester. Failure pattern of the specimen at the interface between post and dentin were observed under SEM. Results 1. Tensile bond strengths(meen{\pm}SD$) ) were expressed with ascending order as follows group 4, $12.52{\pm}6.60$ ; group 1, $7.63{\pm}5.83$ ; group 2, $4.13{\pm}2.31$ ; group 3, $3.31{\pm}1.44$. 2. Tensile bond strengths of Group 4 treated with 17% EDTA +3%NaOCl were significant higher than those of group 1, 2 and 3 (p<0.05). 3. Tensile bond strengths of Group 1 treated with 10% phosphoric acid were significant higher than those of group 2 (p<0.05). Tensile bond strengths of Group 4 treated with 17% EDTA +3% NaOCl was significant higher than those of other groups.

• 한국광학회지
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• 제31권5호
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• pp.205-212
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• 2020

풍력 터빈 시스템의 성능에서 블레이드는 매우 중요한 역할을 하지만 복잡하고 불규칙적인 하중에 의한 손상에 취약하며 유지 보수 비용도 많이 든다. 따라서 블레이드 제조를 완료한 후에 결함을 찾아내고 일정 기간 사용한 후에 블레이드 손상을 찾아내는 것이 매우 중요하다. 본 연구에서는 풍력 터빈 블레이드의 주재료인 유리섬유와 탄소섬유 패널에서 내부 결함을 검출할 수 있는 새로운 방법을 제안하고자 한다. 블레이드 제조 또는 작동 중에 발생할 수 있는 복합재료의 섬유 파단을 모사하기 위해 적층된 재료의 중간층에 직경 5 mm의 홀을 가공한 후에, 비접촉 측정 기술인 이미지 상관법(digital image correlation, DIC)을 사용하여 내부 결함을 검출하였다. 인장시험기를 사용하여 가공된 시편에 인장 하중을 가하면서 이미지 상관법 시스템으로 변화되는 시편의 이미지를 저장하고 분석하였다. 유리섬유 복합재료 시편에서는 인장 하중 방향으로 5%의 변형률부터 내부 결함이 검출되었으며 탄소섬유의 경우에는 1%의 변형률부터 내부 결함이 검출되었다. 재료 특성에 따라 내부 결함 주변에 일정 수준의 변형률 차이가 발생함에 따라 결함이 검출됨을 이미지 상관법 시스템으로 증명하였다.

• 한국의류학회지
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• 제19권4호
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• pp.684-695
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• 1995

The purpose of this study was to investigate the influence of the mechanical properties on drapability in the peach skin-like finished fabrics. For this study, the samples used were 50 kinds of peach skin-like finished fabrics. The mechanical properties such as tensile, shearing, bending, compressional, surface characteristic values, thickness and weight were measured with a KES-F system and drupe coefficient by drape tester. The relationship between the characteristic values and drape coefficicients of the peach skin-like finished fabrics results were obtained. 1. Peach skin-like finished fabric had $\pm$2o range of shearing, bending, compression, surface. properties, thickness and weight as compared with Japanese women's thin fabrics. The characteristic mixing values were better with the values of WC/T, W/T, etc. as compared with that of japanese women's thin fabrics. Accordingly, the peach skin-like finished fabrics had a little volume, excellent hanging and drapability as compared with japanese women's thin fabrics. 2. The drape coefficient of peach skin-like finished fabric had a high level of correlation between 2HB, G, WC, MIU, WT, MMD, 2HG, RT, W, B etc. of the mechanical properties. The blocked properties that contributed to the drape coefficient of peach skin-like finished fabrics were in the order of the bending> tensile> thickness> weight properties. This drape coefficients(DC) were found by measuring the mechanical properties according to the obtained regress on equate on. DC=99.0179+17.9023 log G -17.0543 log 2HG5+17.2104 log 2HG+35.7685 log 2HB+ 4.6082 log B-30.5906 log T+4.2308 log W 3. The contribution to the drape coefficient of the characteristic mixing values of peach skin-like finished fabric was in the order of > 2HB/W> 2HB/B> B/W The drape coefficients were found by measuring the characteristic mixing values according to the obtained regression equation. 4. The drape coefficients of peach skin-like finished fabrics were influenced by the differences between the bending of warp direction, bending of weft direction, shearing etc which in turn determine the level of hanging. The regression equation was as follows; 5. The drape coefficients of peach skin.like finished fabrics had a highly positive correlation with the node index. It has an negative correlation with number of nodes.

• 전기학회논문지
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• 제63권4호
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• pp.495-501
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• 2014

Piezoresistive-type, capacitive-type, and optical-type sensors have mainly been used for measuring a strain. However, in building a sensor network for remote monitoring using these conventional sensors there are disadvantages such as the complexity of a measuring system including wireless communication circuitry and high cost. In this paper, we demonstrates a highly-sensitive surface acoustic wave (SAW) strain sensor which is advantageous to harsh environments and wireless network. We designed and fabricated the SAW strain sensor. The SAW strain sensor attached on a specimen was tested with a tensile tester. The strain on the sensor surface was measured with a commercial strain gauge and compared with that obtained from strain analysis. The central frequency shift of the SAW sensor was measured with a network analyzer. The sensitivity of the SAW strain sensor is 134 $Hz/{\mu}{\varepsilon}$ which is high compared to previous results.

• 한국도로학회논문집
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• 제11권2호
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• pp.111-120
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• 2009

본 연구는 배수성 아스팔트 포장의 표면을 아크릴 수지로 코팅 처리할 경우 내구성 측면 및 기능적 측면에서 어떠한 효과가 있는가를 실내시험을 통해 평가하는 기초적인 연구이다. 포장의 내구성 측면에서는 칸타브로 및 휠트래킹, 수분손상 간접 인장 피로 시험 등을 실시하였다. 시험결과 시편을 수지로 코팅을 한 경우 칸타브로 손실률이 3배 정도 감소되었고 균열에 대한 저항성도 대폭 향상되었으나 수분손상 및 소성변형의 저항성은 큰 차이가 없는 것으로 나타났다. 기능적인 측면에서는 코팅 전 후의 투수계수 및 공극률 BPT(British Pendulum Tester)를 사용한 미끄럼 저항성의 변화를 측정하였다. 시험결과 공극률 및 투수계수는 약간 저하되나 기능상의 문제는 없을 것으로 판단되며, 미끄럼 저항성은 규사를 살포하지 않을 경우 미끄럼 저항성이 감소되나 규사를 살포할 경우 코팅 전 수준 이상의 미끄럼 저항성을 확보하는 것으로 나타났다.

• 한국세라믹학회지
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• 제39권11호
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• pp.1063-1068
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• 2002

Polyimide와 silica에 물리적 또는 화학적으로 결합된 Polyimide/silica(PI/silica) 혼성체들을 졸-겔법을 통하여 Polyamic Acid(PAA) 또는 end-capped PAA 용액에 tetraethoxysilane을 가수 분해 및 축 중합시켜서 제조하였다. PAA 용액은 dimethylacetamide 용액 내에서 pyromellitic dianhydride와 oxydianiline 단량체들을 개환 반응으로 합성하였다. End-capped PAA 용액은 PAA 용액에 3-aminopropyltriethoxysilane을 첨가하여 제조하였다. 적외선 분광기, 시차 열분석기, X-선 회절 분석기, 주사 전자현미경 및 인장 강도 시험기를 통하여 PI/silica 혼성체 시편들의 특성을 분석하였다. 혼성체 시편들의 물성은 PI와 silica간의 결합형 및 silica의 함량에 의해 영향을 받는다는 것을 확인하였다.

• 한국의류산업학회지
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• 제2권2호
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• pp.150-158
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• 2000

This study investigated mechanical properties, drape coefficients and node indices of stretch fabrics. We applied mechanical properties to exhibited tailorability control in HESC and evaluated making-up. The mechanical properties such as tensile, bending, shearing, compression, surface characteristic values, thickness and weight were measured by the KES-F system and drape coefficient by drape tester. The summarized results of this study were as follows; First, stretch fabrics, almost, shown high stretch in weft inserted polyurethane yarn fabric and had a ${\pm}2{\sigma}$(sigma) range of shearing, compression, surface and thickness, except bending and weight, as compared with Japanese women's thin dress fabrics. Second, bending had a positive correlation in stiffness, anti-drape and flexibility & softness. Shearing had a negative correlation in crispness and scroop. Surface properties had a high contribution in fullness & softness. Third, The drape coefficient was found by measuring the mechanical properties according to the obtained regression equation. Forth, many problems are expected in overfeed and cutting operations in sewing process. In the decision of the good external appearance using TVA, only 26 of 55 samples are included in the range of the good external appearance. Fifth, in the regard of the result for sewing control, warp values are not necessary to control in the all kind of items. But weft value in the RT and EM are out of non-control zone. So we need a special management during sewing process.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2006년도 추계학술대회
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• pp.352-355
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• 2006

As the stainless steel has good corrosion resistance, mechanical property and ease of manufacture, it has been studied as the candidate material of metallic bipolar plate for automotive PIMFC. But, metal is dissolved under fuel cell operating conditions Dissolved ions contaminate a membrane electrode assembly (MEA) and, decrease the fuel cell performance. In addition, metal oxide formation on the surface of stainless steel increases the contact resistance in the fuel cell. These problems have been acted as an obstacle in the application of stainless steel to bipolar plate. Therefore, many kinds of coating technologies have been examined in order to solve these problems. In this study, stainless steel was coated in order to achieve high conductivity and corrosion resistance by several methods. Contact resistance was measured by using a tensile tester and impedance analyzer Corrosion characteristics of coated stainless steel were examined by Tafel-extrapolation method from the polarization curves in a solution simulating the anodic and cathodic environment of PEMFC. Fuel cell performance was also evaluated by single cell test. We tested various coated metal bipolar plate and conventional and graphite were also tested as comparative samples. In the result, coated stainless steel bipolar plate exhibited better cell performance than graphite to bipolar plate.