• Macromolecular Research
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• v.17 no.12
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• pp.1015-1020
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• 2009

The role of the water structure present in hydrogels from nutlets of three species of salvias, S. miltiorrhiza (SM), S. sclarea (SS) and S. viridis (SV), was analyzed by differential scanning calorimetry (DSC). The sharp endothermic peaks that appeared at $5.9^{\circ}C$ (SM), $2.8^{\circ}C$ DC (SS) and $1.8^{\circ}C$ (SV) in each 1.0% hydrogel of 10.4-15.8% were not affected by addition of 0.1 M urea and alkali-metal salts. The order-disorder portions in the network were slightly affected by the distribution of freezable and non-freezable water in the hydrogel networks. The SV hydrogel was further used to investigate the effects of additives (0.1-8.0 M urea and 0.1-5.0 M NaCl) on its melting behavior. At 0.5-4.0 M urea and 1.0-3.0 M NaCl, two endothermic peaks appeared, corresponding to unbound (high temperature) and bound (low temperature) water in the gel networks, and eventually merged into one endothermic peak at 5.0-8.0 M urea and 4.0-4.5 M NaCl. After this merger, the endothermic peak shifted to 3.7, 4.0 and $5.6^{\circ}C$ at 5.0, 6.0 and 8.0 M urea, respectively. In the case of NaCl, a combination of peaks that occurred at 4.0-4.5 M were accompanied by a shift to lower temperature (-14.4 and $15.3^{\circ}C$) and the endothermic peak finally disappeared at 5.0 M NaCl due to the strong binding of water in the gel networks.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.1
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• pp.11-18
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• 2018

A high efficiency integrated reforming system for improving the efficiency of the 5 kW PEMFC system used as the back up power of building was studied. The separated reforming system consisted of three parts - A steam reformer with two stage concentric circular shape, a heat exchanger type steam generator and a CO shift reactor. Temperature and steam carbon ratio (SCR) were control variables during operation. The operating conditions were optimized based on the thermal efficiency of the steam reformer as reformate gas composition changes at different temperature. In experiments, water was fully vaporized in the steam generator up to SCR 3.5 and the maximum thermal efficiency was achieved at the operating temperature around $700^{\circ}C$ in the steam reforming reactor. With the results of the separated reforming system research, we improved the shape of high efficiency integrated reformer. The performance evaluation of the integrated reformer was based on optimized operating conditions in SCR 3.5. As a result, the developed integrated reforming system maintained an efficiency of 76% and constant performance over 3,000 hours.

• Journal of the Korean Society of Clothing and Textiles
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• v.22 no.7
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• pp.826-832
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• 1998

In order to understand the influences of wearing clothings with different thermal insula-tions when men were exposed from $25^{\circ}C$ environment to 18$^{\circ}C$ environment, thermoregulatory responses were measured on 4 healthy female college students. Subjects rested wearing T-shirts, trousers, and socks called LC(total weight 541g) at 25$\pm$1$^{\circ}C$, 50$\pm$5% R.H. and then exposed to the room conditioned in 18$\pm$1$^{\circ}C$, 50$\pm$5$^{\circ}C$ R.H. with LC as it was(LC Type) or with T-shirts, trousers, socks, training wear upper garment, the training wear lower garment called HC (total weight 1368g)(HC Type) for 120 min. The results can be summarized as follows: 1) When subjects were exposed from $25^{\circ}C$ environment to 18$^{\circ}C$ environment, decrease of rectal temperature was significantly smaller in LC Type than in HC Type. 2)Increase of heat production and weight loss had no significant difference between two types of clothing. 3)Internal thermal conductance was higher in HC Type and external thermal conductance was higher in LC Type. Therefore total thermal conductance was higher in LC Type than in HC Type. 4)Decrease of skin temperature was greater in LC Type than in HC Type. 5)Subjects felt colder with LC Type than with HC Type, but did not feel differently in comfort sensation between two types of clothing. It was suggested that less decrease of rectal temperature in LC type inspite of more dry heat loss from body might be ascribed to a shift of blood from the shell area to the core area originating in the vasoconstriction and the lowered internal thermal conductance. In conclu-sion, the importance of the state of internal heat distribution in the homeostasis seemed to be reaffirmed.

• Progress in Superconductivity and Cryogenics
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• v.17 no.4
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• pp.30-33
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• 2015

We report the synthesis of Ni-doped $BaFe_2Se_3$ single crystals by using a flux method. X-ray diffraction (XRD) of $Ba(Fe_{1-x}Ni_x)_2Se_3$ shows a gradual peak shift with an increase in the nominal Ni-doping rate, x = 0, 0.05, and 0.10, due to a decrease in unit-cell volume. All samples show a spin glass transition, and temperature dependence of magnetic susceptibility shows a negligible change in the spin-glass transition temperature ($T_g$) with Ni concentration x. The temperature dependence of electrical resistivity for $BaFe_2Se_3$ shows an insulating behavior, and the resistivity value at 295 K and the activation energy ($E_a$) obtained from the Arrhenius plot decrease with increasing x. These results suggest that the Ni doping can be effectively worked as a dopant for electron charge carriers, but is less efficient in controlling the magnetic property, such as spin glass transition, in the $BaFe_2Se_3$ compound.

• Journal of the Korean Magnetics Society
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• v.10 no.1
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• pp.16-21
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• 2000

Magnetic properties and crystallographic properties of $Cu_{0.95}Ge_{0.95}Fe_{0.1}O_3$ were studied by using x-ray diffraction, superconducting quantum interference device (SQUID) and Mossbauer spectroscopy. Our sample has orthorhombic structure and the lattice constants are a = 4.795 $\AA$, b = 8.472 $\AA$, c = 2.932 $\AA$. The spin-Peierls (SP) transition temperatures of our sample is 13 K. The Mossbauer spectra consisted with two Zeeman sextets and one doublet due to $Fe^{3+}$ions. The Zeeman sextets come from tetrahedral $Fe^{3+}$ions and the doublets come from octahedral $Fe^{3+}$ions. The jump up of magnetic hyperfine field of 2nd Zeeman sextet and the increasing of the values of quadrupole splitting and isomer shift of doublet below SP transition temperature could be interpreted related with the atomic displacements. The N el temperature is 715 K, the Debye temperature are 540 K for octahedral site and 380 K for tetrahedral site, respectively.

• Journal of the Korean Wood Science and Technology
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• v.36 no.4
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• pp.52-57
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• 2008

In this study, the effects of carbonization temperature on the physico-chemical properties of porous wood charcoal are studied by FT-IR and Raman spectroscopies. IR studies showed that cellulose and hemicellulose are mostly decomposed in the precarbonization stage at $500^{\circ}C$, while the decomposition reaction of relatively more stable lignin lasts up to $700^{\circ}C$. Above $900^{\circ}C$, the peak at $1575cm^{-1}$ disappears and a new peak at $1630cm^{-1}$, which seems to be related to the new carbon deposit phase, is evolved. The results of Raman studies, which show the red-shift of D-band and the increase in the relative intensity of D- to G-band, indicate that the size of the crystalline becomes smaller with increasing the carbonization temperature.

• Journal of the Korean Magnetics Society
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• v.15 no.2
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• pp.137-141
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• 2005

The CMR properties and magnetic properties of sulphospinels $Zn_xFe_{1-x}Cr_2S_4$ have been explored by X-ray diffraction, magnetoresistance measurement, and $M\ddot{o}ssbauer$ spectroscopy. The crystal structures in the range of x=0.05, 0.1, 0.2 are cubic at room temperature. Magnetoresistance measurement indicates that these system is semiconducting below about 160 K. The temperature of maximum magnetoresistance is almost consistent with Curie temperature. The Zn substitutions for Fe occur to increase the Jahn-Teller relaxation and the electric quadrupole shift. CMR properties could be explained with Jahn-Teller effect, and half-metallic electronic structure, which is different from both the double exchange interactions of manganite La-Ca-Mn-O system and the triple exchange interactions of chalcogenide $Cu_xFe_{1-x}Cr_2S_4$.

• Korean Journal of Optics and Photonics
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• v.30 no.6
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• pp.226-229
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• 2019

We investigated an interrogation system for fiber Bragg gratings by using a 50-GHz 96-channel array waveguide grating. Linearity of the sensitivity (the wavelength shift in response to the change in strain or temperature) is achieved for a Bragg grating of sufficiently wide bandwidth. The present wavelength-monitoring system could measure the change in Bragg wavelength with a resolution of 0.01 nm, at intervals of 10 seconds. When this interrogation system was used for a linear array of 12 acrylaterecoated fiber gratings, the wavelength sensitivity changed from 0.018 nm/℃ to 0.01 nm/℃ when the operating temperature changed from -25℃ to 85℃.

• Current Optics and Photonics
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• v.1 no.2
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• pp.143-149
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• 2017

LED arrays with pixel numbers of $3{\times}3$, $4{\times}4$, and $5{\times}5$ have been studied in this paper in order to enhance the optical output power and decrease heat dissipation of an AlGaInP-based light emitting diode display device (pixel size of $280{\times}280{\mu}m$) fabricated by micro-opto-electro-mechanical systems. Simulation results showed that the thermal resistances of the $3{\times}3$, $4{\times}4$, $5{\times}5$ arrays were $52^{\circ}C/W$, $69.7^{\circ}C/W$, and $84.3^{\circ}C/W$. The junction temperature was calculated by the peak wavelength shift method, which showed that the maximum value appears at the center pixel due to thermal crosstalk from neighboring pixels. The central temperature would be minimized with $40{\mu}m$ pixel pitch and $150{\mu}m$ substrate thickness as calculated by thermal modeling using finite element analysis. The modeling can be used to optimize parameters of highly integrated AlGaInP-based LED arrays fabricated by micro-opto-electro-mechanical systems technology.

• Macromolecular Research
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• v.10 no.1
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• pp.34-39
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• 2002

Cure behavior of an epoxy resin was investigated at different cure temperatures (110, 120, 130, 140, and 150 $^{\circ}C$) and cure times in the presence of 2 wt% of an N-benzylpyrazinium hexafluoroantimonate (BPH) cationic catalyst by means of differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). The glass transition temperature ( $T_{g}$) and chemical conversion (x) at the different temperatures were determined from DSC thermograms. The $T_{g}$ and x vs. In time data were superposed up to $T_{g}$ = 10$0^{\circ}C$ and x = 0.70 by shifting horizontally at a reference temperature of $T_{g}$ = 13$0^{\circ}C$. It is interesting that the $T_{g}$ and x of the superposed data increase rather slowly in the early stage of cure and rapidly thereafter. Therefore, the increase of the $T_{g}$ and x can be divided into two regions; $R_{I}$= -18.4(= $T_{go}$ ) ~5$^{\circ}C$ and $R_{II}$ = 5 ~ 10$0^{\circ}C$ in $T_{g}$, and $R_{I}$ : 0~0.24 and $R_{II}$ : 0.24~0.70 in x. The $R_{I}$ is closely related to the initiation reactions between BPH and epoxy and between hydroxy group and epoxy in this epoxy/catalyst system. From the kinetic analysis of the $T_{g}$-shift, activation energy was 12.5 kcal/mol. The relationship between $T_{g}$ and x was also considered. The gelation and vitrification times for different cure temperatures were obtained from DMA curves.urves. DMA curves.urves.