• 전기화학회지
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• 제14권4호
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• pp.245-252
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• 2011

본 연구에서는 탄소나노튜브를 담지체로 사용하여 연료전지용 백금(Pt) 촉매의 고분산, 고담지를 목적으로 하였다. 탄소나노튜브의 표면처리는 열적산화방식으로 전처리하였다. 25, 50, 90 및 $110^{\circ}C$에서 열처리를 하였을 경우, 온도변화에 따른 작용기의 영향을 FT-IR, XPS를 통해 분석하였다. XPS를 통해 전처리의 온도가 증가할수록 작용기의 농도가 증가하는 것을 확인 하였으며, TGA와 TEM을 통해 Pt의 담지량과 분산도 또한 증가한 것을 확인하였다. 산화과정에서 열적거동은 고담지 Pt 촉매의 제조와 밀접한 관련이 있으며, 본 연구에서 제조된 촉매의 고분산, 고담지에 적절한 합성 온도는 $90^{\circ}C$로 관찰되었으며 단위전지에서 가장 좋은 성능을 나타내었다.

• 한국환경과학회지
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• 제21권1호
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• pp.1-9
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• 2012

A thermal-optical transmittance carbon analyzer has been developed to determine particulate organic (OC) and elemental (EC) carbon. Several analysis factors affecting the sensitivity of OC and EC determination were investigated for the carbon analyzer. Although total carbon (TC) is usually consistent in the determination, OC and EC split is sensitive to adopted analysis protocol. In this study the maximum temperature in oxygen-free He in the analysis was examined as a main cause of the uncertainty. Prior to the sensitivity analysis consistency in OC-EC determination of the carbon analyzer and the uniformity of carbonaceous aerosol loading on a sampled filter were checked to be in acceptable range. EC/TC ratios were slightly decreased with increasing the maximum temperature between $550-800^{\circ}C$. For the increase of maximum temperature from $500^{\circ}C$ to $800^{\circ}C$, the EC/TC ratio was lowered by 4.65-5.61% for TC loading of 13-44 ${\mu}g/cm^2$ with more decrease at higher loading. OC and EC determination was not influenced by trace amount of oxygen in pure He (>99.999%), which is typically used in OC and EC analysis. The facing of sample loaded surface to incident laser beam showed negligible influence in the OC-EC split, but it caused elevated PC fraction in OC for forward facing relative to backward facing.

• 대한기계학회논문집B
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• 제21권2호
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• pp.213-223
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• 1997

Premixed flame is better than diffusion flame to accomplish a high loading combustion. Since the turbulent characteristics of unburned mixture has a great influence on the flame structure, it is general that many researchers realize a high loading combustion with strengthening turbulent intensity of unburned mixture. Because turbulent premixed flame reacts efficiently on the condition of distributed reaction region, we made high turbulent premixed flame in the doubled impingement field. We investigated turbulent characteristics of unburned mixture with increasing shear force and visualized flames with direct and Schlieren photographs. And the combustion characteristics of flame was elucidated by instantaneous temperature measurement with a thermocouple, by ion currents with a micro electrostatic probe, by radical luminescence intensity and local equivalence ratio. Extremely strong turbulent of small scale is generated by impingement of mixture, and turbulent intensity of unburned mixture increased with the mean velocity. As a result of direct photographs, visible region of flame became longer due to increasing central direction flux. But as strengthed turbulent intensity, visible region of flame turned to shorter and reaction occurred efficiently. As strengthened turbulent intensity of mixture with increasing flux of central direction, maximum fluctuating temperature region moved to radial direction and fluctuation of temperature became lower. The reason is influx of central direction which caused flame zone to move toward radial direction, to maintain flame zone stable and to make flame scale smaller.

• 한국농공학회지
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• 제34권4호
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• pp.69-79
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• 1992

To estimate soil behavior and structural characteristics under the conditions of cyclic loading, freezing & thawing and initial state, several testing was performed and obtained following results. 1.After repeated freezing and thawing processes, original soil structure was destroyed and changed to globular structure from honeycomb or tube in its structure types. Also above processes resulted increasing the soil compression strain while decreasing the failure stress in stress-strain relationship and reached the soil structure into the mode of brittle fracture. Under cyclic loading conditions, soil cluster which was originally dispersed structure colloided with each other, seperated, and finally the soil failed due to the effect of overcompaction. 2.Through the stabilization processes seperated by four steps, the structure of soil skeleton was changed to quite different globular type. The degree of compressibility of soil was decreased in the normally consolidated zone, while the strength against external load increased due to soil particle stabilization. 3.Soil stress-strain chracteristics were largely influenced by repeated up and down processes of temperature. The maximum deformation was obtained in the case of temperature between 0 10˚C by the reseon of particle cluster reformation. 4.Soil compressibility was largely influenced by the optimum moisture content. Under freezing process, swelling could be found and its magnitude was proportional to the density of soil. 5.Density of soil was decreased as increasing the number or repeated freezing and thawing processes and the largest decreasing rate was found at the first turning point from freezing to thawing cycle.

• 대한기계학회논문집A
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• 제34권7호
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• pp.911-917
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• 2010

본 연구에서는 열적-기계적 주기하중을 받고 있는 엔진 배기매니폴드에 대해서 열응력 해석방법과 열피로수명 예측과정을 제시하였다. 즉, 파손현상이 복잡한 배기시스템의 효율적인 유한요소 모델링 방법과 온도 의존성 재료의 시험결과를 이용한 해석 데이터 구성, 그리고 열사이클 하중에 대한 열응력 및 파손 예측방법을 디젤엔진의 배기매니폴드에 대해서 나타내었다. 일반적으로 배기매니폴드의 파손 취약부에서는 고온영역에서 큰 압축소성변형이 발생하고 냉각시에는 인장의 잔류응력이 나타난다. 따라서 이같은 응력과 변형률의 이력곡선으로부터 소성변형의 진폭 또는 소성에너지의 크기를 얻을 수 있으며 이를 통해서 피로수명을 예측할 수 있다.

• 대한기계학회논문집A
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• 제25권7호
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• pp.1082-1088
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• 2001

Nowadays study on recycling disused plastics for automobiles was lively progressed. Rubber and talcum powder was added to retrieve degradation of physical properties caused by recycling disused polypropylene. The effect of the temperature, the fatigue load and the loading speed on DEN(double edged notch) specimen which was made by the pp-rubber composites during fracture was studied by. DEN specimen was made on PP-rubber composites through the injection molding. With increasing temperature the fracture strength was linearly decreased and the fracture energy was increased by $0^{\circ}C$ and after that decreased. In the same temperature the fracture strength during increasing the notch radius was hardly increased. The fracture behaviour at low and high loading speed was different entirely. At high loading speed plastic region was small and fracture behaviour was seen to brittle fracture tendency. With increasing fatigue load fracture energy was first rapidly decreased and subsequently steady when radius of notch tip was 2mm, but Maximum load during fracture scarcely varied. The deformation mechanism of polypropylene-rubber composites during fracture was studied by SEM fractography. A strong plastic deformation of the matrix ahead of the notch/crack occurred. The deformation seem to be enhanced by a thermal blunting of the notch/crack.

• Advanced Composite Materials
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• 제18권3호
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• pp.265-285
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• 2009

Off-axis compressive deformation behavior of a unidirectional CFRP laminate at high temperature and its strain-rate dependence in a quasi-static range are examined for various fiber orientations. By comparing the off-axis compressive and tensile behaviors at an equal strain rate, the effect of different loading modes on the flow stress level, rate-dependence and nonlinearity of the off-axis inelastic deformation is elucidated. The experimental results indicate that the compressive flow stress levels for relatively larger off-axis angles of $30^{\circ}$, $45^{\circ}$ and $90^{\circ}$ are about 50 percent larger than in tension for the same fiber orientations, respectively. The nonlinear deformations under off-axis tensile and compressive loading conditions exhibit significant strain-rate dependence. Similar features are observed in the fiber-orientation dependence of the off-axis flow stress levels under tension and compression and in the off-axis flow stress differential in tension and compression, regardless of the strain rate. A phenomenological theory of viscoplasticity is then developed which can describe the tension-compression asymmetry as well as the rate dependence, nonlinearity and fiber orientation dependence of the off-axis tensile and compressive behaviors of unidirectional composites in a unified manner. It is demonstrated by comparing with experimental results that the proposed viscoplastic constitutive model can be applied with reasonable accuracy to predict the different, nonlinear and rate-dependent behaviors of the unidirectional composite under off-axis tensile and compressive loading conditions.

• 대한토목학회논문집
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• 제26권3D호
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• pp.435-444
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• 2006

본 논문은 AREA법을 사용하는 줄눈 콘크리트포장의 평가에 3차원 유한요소모델을 사용하는 경우 나타나는 특성을 조사하는데 목적이 있다. 이를 위해 실제 콘크리트포장을 거동을 반영할 수 있는 3차원 유한요소모델을 구축하였고 2차원 모델과 비교한 후 민감도 분석을 수행하였다. ILLISLAB을 사용한 2차원 모델과 비교하였고 하중형태의 영향 보다 하중재하 지점의 자체수축과 기층모델에 따른 영향을 더 많이 받는 것으로 나타났다. 3차원 모델에서 비선형 온도구배를 선형 온도구배로 변화시키는 경우 발생하는 영향을 조사하였고 큰 차이를 보이지는 않았으나 지반 탄성계수가 작아질수록 더 많은 차이를 보였다. 동적하중에 의한 처짐을 구하였고 정적하중에 의한 처짐과 비교한 결과 낮은 지반 탄성계수에서는 동적하중에 의한 처짐이 작게 나타났으나 높은 지반 탄성계수에서는 동적하중에 의한 처짐이 크게 나타났다. 동적하중에 의한 처짐 이력을 구하고 AREA법을 이용하여 동적지지력과 탄성계수를 역산하였으며 이를 정적 처짐에 의한 결과와 비교하였다. 그 결과 동적지지력의 경우 정적 해석에 의한 값보다 동적해석에 의한 값이 낮게 나타났고 탄성계수의 경우 반대의 경향을 나타내어 현장에서 AREA법을 사용하는 경우 나타나는 평가결과의 특성을 설명하는 것으로 판단되었다.

• 한국식품저장유통학회지
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• 제9권3호
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• pp.282-286
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• 2002

양파 간이저장시 무분별한 야적에 의해 발생하는 부패를 감소시켜 양파의 상품성 향상 및 안전저장을 목적으로 적재 방법에 따른 저장성을 조사한 결과는 다음과 같다. 평균기온은 4열 8단에 비해 1열 6단은 1.6~3.2$^{\circ}C$, 1열 8단은 0.5~3.5$^{\circ}C$, 2열 6단은 1.3~.6$^{\circ}C$, 2열 8단은 0.1~2.4$^{\circ}C$, 4열 6단은 0.1~1.8$^{\circ}C$가 낮았고 상대습도는 열수가 많을수록 높았다. 부패율은 4열 8단 16.6%에 비해 1열 6단 11.4%, 2열 6단 11.6%, 4열 6단 12.4%, 1열 8단 14.6%, 2열 8단 13.9%로 열수 및 단수가 많을수록 부패는 많았고 중량감모도 열수 및 단수가 많을수록 높았다. 저장중 발생하는 부패원인균의 경우 Fusarium sp.은 7월 중순과 8월 상순, Aspergillus sp.은 7월 하순에서 8월 중순까지, Bacteria는 7월 중순과 9월 상순에 발생이 많았다.

• 대한기계학회논문집A
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• 제24권1호
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• pp.156-162
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• 2000

Sensitized STS 304 stainless steel crack growth rate(CGR) in high temperature water was investigated under trapezoidal wave loading test using fracture mechanics techniques. The CGR, due to stress corrosion cracking(SCC), were systematically measured as a function of the stress intensity factor and stress. holding time under trapezoidal wave loading. In high temperature water, CGR was enhanced by a synergistic effects in combination with an aggressive environment and mechanical damage. The CGR, $(da/dN)_{env}$ was basically described as a summation of the environmentally assisted crack growth rate $(da/dN)_{SCC}$, $(da/dN)_{CF}$ and fatigue crack growth rate in air $(da/dN)air,. The CGR, $(da/dN)_{env}$, increased linearly with increasing stress holding time. The CGR, $(da/dN)_{SCC}$ decreased linearly with increasing stress holding time. Fracture surface mode varied from trans-granular cracking to inter-granular cracking with increasing stress holding time.