• Title/Summary/Keyword: temperature dependance

Search Result 80, Processing Time 0.028 seconds

A Study on the Formation of Ti-capped NiSi and it′s Thermal Stability (Ti-capped NiSi 형성 및 열적안정성에 관한 연구)

  • 박수진;이근우;김주연;배규식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.07a
    • /
    • pp.288-291
    • /
    • 2002
  • Application of metal silicides such as TiSi$_2$ and CoSi$_2$ as contacts and gate electrodes are being studied. However, TiSi$_2$ due to the linewidth-dependance, and CoSi$_2$ due to the excessive Si consumption during silicidation cannot be applied to the deep-submicron MOSFET device. NiSi shows no such problems and can be formed at the low temperature. But, NiSi shows thermal instability. In this investigation, NiSi was formed with a Ti-capping layer to improve the thermal stability. Ni and Ti films were deposited by the thermal evaporator. The samples were then annealed in the N$_2$ ambient at 300-800$^{\circ}C$ in a RTA (rapid thermal annealing) system. Four point probe, FESEM, and AES were used to study the thermal properties of Ti-capped NiSi layers. The Ti-capped NiSi was stable up to 700$^{\circ}C$ for 100 sec. RTA, while the uncapped NiSi layers showed high sheet resistance after 600$^{\circ}C$. The AES results revealed that the Ni diffusion further into the Si substrate was retarded by the capping layer, resulting in the suppression of agglomeration of NiSi films.

  • PDF

Dependance of thickness on the properties of B doped ZnO:Ga (GZOB) thin film on glass substrate at room temperature (유리기판에 저온 증착한 GZOB 박막의 두께에 따른 특성 변화)

  • Yu, Hyun-Kyu;Lee, Kyu-Il;Lee, Jong-Hwan;Kang, Hyun-Il;Lee, Tae-Yong;Kim, Eung-Kwon;Song, Joon-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.11a
    • /
    • pp.88-88
    • /
    • 2008
  • In this study, effect of thickness on structural, electrical and optical properties of B doped ZnO:Ga (GZOB) films was investigated. GZOB films were deposited on glass substrates by DC magnetron sputtering. The thickness range of films were from 100 nm to 600 nm to identified as increasing thickness, stress between substrate and GZOB film. The average transmittance of the films was over 80 % until 500 nm. Then a resistivity of $9.16\times10^{-4}\Omega$-cm was obtained. We presented that a GZOB film of 400 nm was optimization to obtain a high transmittance and conductivity.

  • PDF

A Study on Equilibrium of $NH_4NO_{3(s, aq)}-HNO_{3(g)}-NH_{3(g)}$ in Urban Atmosphere (도시 대기중에서 $NH_4NO_{3(s, aq)}-HNO_{3(g)}-NH_{3(g)}$의 평형에 관한 연구(II))

  • 천만영;이영재;김희강
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.9 no.2
    • /
    • pp.154-159
    • /
    • 1993
  • Theoretical prediction of the equilibrium of temperature and relative humidity dependance involving $HNO_{3(g)}-NH_{3(g)}$ and $NH_4NH_{3(s, aq)}$ was compared with atmospheric measurement of particulate nitrate$(NO_3^-)$, Ammonia-Nitric Acid partial pressure product $([$NH_{3(g)}][HNO_{3(g)}]ppb^2$) by a triple filter pack sampler from Oct 1991 to July 1992. The measured $HNO_3NH_3$ concentration product K was greater than equilibrium constant $K_p$ calculated from thermodynamic data of $NH_4NO_{3(s, aq)}-HNO_{3(g)}-NH_{3(g)}$ during fall, winter and spring. But K was lower than $K_p$ in summer. K was greater than $K_p$ as the result of supersaturation by air pollution, particularly anthropogenic $NH_3$.The reason of $K < K_p$ was due to removal of particulate nitrate$(NO_3^-)$ by rainout and washout. $NH_4NO_3$ which consists mainly of particulate nitrate is formed by reaction between $HNO_3$ and $NH_3$. As a result of the removal of particulate nitrate$(NO_3^-)$ by rainout and washout, concentrations of $HNO_3$ and $NH_3$ are decreased by equilibrium transfer(Le Chatelier's Law) in atmosphere.

  • PDF

Dependance of thickness on the properties of B doped ZnO:Al (AZOB) thin film on polycarbonate (PC) substrate at room temperature (PC 기판에 저온 증착한 AZOB 박막의 두께에 따른 특성 변화)

  • Yu, Hyun-Kyu;Lee, Kyu-Il;Lee, Jong-Hwan;Kang, Hyun-Il;Lee, Tae-Yong;Oh, Su-Young;Song, Joon-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.06a
    • /
    • pp.138-138
    • /
    • 2008
  • In this study, effect of thickness on structural, electrical and optical properties of B doped ZnO:Al (AZOB) films was investigated. AZOB films were deposited on PC substrates by DC magnetron sputtering. The thickness range of films were from 300 nm to 800 nm to identified as increasing thickness, stress between substrate and AZOB film. The. average transmittance of the films was over 80 % until 500 nm. Then a resistivity of $1.58\times10^{-3}\Omega$-cm was obtained. We presented that a AZOB film of 500 nm was optimization to obtain a high transmittance and conductivity.

  • PDF

CHEMICAL ABUNDANCE ANALYSIS OF M31 AND M33 BASED ON THE SPECTRUM OF HII REGIONS (HII 영역 분광자료를 통한 M31과 M33의 화학원소 결정)

  • HAN SOO RYEON;HYUNG SIEK;PARK HONG-SUH;LEE WOO-BAlK
    • Journal of The Korean Astronomical Society
    • /
    • v.34 no.2
    • /
    • pp.67-80
    • /
    • 2001
  • Chemical evolution of galaxies can be understood by studying the spatial distribution of heavy elements. We selected two nearby galaxies, M31 and M33 and investigated spectrum of their HII regions: a) the elec-tron densities have been derived from the [S II] 6717/6731 ratio along with the most recent atomic constants (Hyung & Aller 1996); b) the electron temperatures were determinated from the Pagel's empirical method. Nebula Model (Hyung 1994) has been employed to predict the spectral line intensities which gives the proper chemical abundances. The model would predict the line intensities correctly only when various input parameters such as the effective central star temperatures, gravity log g, model atmosphere as well as the geometry and the nebula physical condition are appropriate. Thus, the determination of chemical abundances of O, S, N of the two nearby galaxies M31 and M33 has been done, which shows a radial dependance of O/H and N/H: decrease with the distance, or increasing electron temperature due to the elemental deficiency. Abundances of M31 appear to be enhanced than those of M33.

  • PDF

Inducdance Effects of Zeromagnetostrictive Amorphous Magnetic Films. (영자왜 마몰퍼스 자성박막의 인덕턴스효과)

  • 서강수;임재근;정승우;신용진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1997.11a
    • /
    • pp.136-139
    • /
    • 1997
  • In this paper, we inveatigate frequency dependance of inductance effects of FeCoB amorphous magnetic films. First, amorphous magnetic film having near zero magnetostriction is the basic composition of (Fe$_{1-x}$ / $Co_{x}$)$_{79}$Si$_2$B$_{19}$ with x=0.94, 0.95 and in order to decrease magnetio . anisotropy, the film was annealed in 28$0^{\circ}C$/30min, 40$0^{\circ}C$/30min, 40$0^{\circ}C$/1hr with near crystallization temperature under non-magnetic field. As result of investigation, in case of x=7.95 than x=0.94, we could have obtained high values, which inductance ratios in the low frequency was 488%. And Quality factor Q was under 0.7 in all sample, in case of annealed in 28$0^{\circ}C$/30min, we could have obtained highest value, which x=0.9fl is about 0.62 in 400[kHz], and in case of x=0.95 was about 0.35 in 1[MHz].z].].

  • PDF

Control of Electromagnetic Properties of High Initial Permeability Mn-Zn Ferrite with the Microstructure Control (미세구조 조절에 의한 고투자율 Mn-Zn Ferrite의 특성제어)

  • 도세욱;류지태;김정희;강태현;허원도
    • Resources Recycling
    • /
    • v.7 no.4
    • /
    • pp.50-54
    • /
    • 1998
  • In order to obtain desired electromagnetic propertieι high initial permeability and good frequency dependance of initial p permeability, the adding effects of sevral seeds were experimented in Mn-Zn ferrite system. As adding seed grams, calcined at sintering temperature, abnormal grains were disappeared clearly but the density and the initial permcability of sintered Mn-Zn ferrite body were decreased. On the contrary, in case of adding seed rains which were calcined below the calcination temperatnre of matrix particle, abnormal grains remained but the initial permeability was increas$\xi$d with proper s$\xi$ed content. W With proper seed content, the initial permeability was increased by 10-20% but tbe $\alpha$ltoff frequency was not changed.

  • PDF

Carboxylic Acids Produced from Hydrothermal Treatment of Organic Wastes (유기성 폐기물의 고온고압수 반응에 의한 카르복시산 생성)

  • 강길윤;오창섭;김용하
    • Journal of Energy Engineering
    • /
    • v.13 no.3
    • /
    • pp.228-233
    • /
    • 2004
  • This paper reports production of low-molecular weight carboxylic acids from the hydrothermal treatment of representative organic wastes and compounds with or without oxidant (H$_2$O$_2$). Organic acids such as acetic, formic, succinic and lactic acids were obtained. This result increased to 42mg/g dry waste fish entrails in the presence of H$_2$O$_2$. Experiments on glucose representing cellulosic wastes were also carried out, getting acetic acid of about 29mg/g glucose. Studies on temperature dependance of formation of organic acids showed thermal stability of acetic acid, whereas, formic acid decomposed readily under hydrothermal conditions. In general. results demonstrated that the presence of oxidants favored formation of organic acids with acetic acid being the major product.

Determination of Convection Heat Transfer Coefficient Considering Curing Condition, Ambient Temperature and Boiling Effect (양생조건·외기온도·비등효과를 고려한 콘크리트 외기대류계수의 결정)

  • Choi Myoung-Sung;Kim Yun-Yong;Woo Sang-Kyun;Kim Jin-Keun
    • Journal of the Korea Concrete Institute
    • /
    • v.17 no.4 s.88
    • /
    • pp.551-558
    • /
    • 2005
  • The setting and hardening of concrete is accompanied with nonlinear temperature distribution caused by development of hydration heat of cement. Especially at early ages, this nonlinear distribution has a large influence on the crack evolution. As a result, in order to predict the exact temperature history in concrete structures it is required to examine thermal properties of concrete. In this study, the convection heat transfer coefficient which presents thermal transfer between surface of concrete and air, was experimentally investigated with variables such as velocity of wind, curing condition and ambient temperature. At initial stage, the convection heat transfer coefficient is overestimated by the evaporation quantity. So it is essential to modify the thermal equilibrium considered with the boiling effect. From experimental results, the convection heat transfer coefficient was calculated using equations of thermal equilibrium. Finally, the prediction model for equivalent convection heat transfer coefficient including effects of velocity of wind, curing condition, ambient temperature and boiling effects was theoretically proposed. The convection heat transfer coefficient in the proposed model increases with velocity of wind, and its dependance on wind velocity is varied with curing condition. This tendency is due to a combined heat transfer system of conduction through form and convection to air. From comparison with experimental results, the convection heat transfer coefficient by this model was well agreed with those by experimental results.

Studies on the amino acid metabolism of young rice root (Part 4) -Properties of glutamic oxalacetic transaminase isozymes of rice root- (수도근(水稻根)의 Amino 산(酸) 대사(代謝)에 관(關)한 연구(硏究) -제(第) 4 보(報) 수도근(水稻根)의 Glutamic Oxalacetic Transaminase Isozyme의 성질(性質))

  • Kim, Kwang Sik;Kim, Young Ung
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.7 no.4
    • /
    • pp.209-213
    • /
    • 1974
  • The isozymes of glutamic oxalacetic transaminase from young rice root were isolated by DEAE-cellulose column chromatography, and investigated some of their enzymic properties. Obtained results were summarized as follows: 1. 93 percent of GOT activity in rice root existed in supernatant fraction, and their specific activity exibited the same pattern. 2. The rice root contained two types of GOT isozyme; cationic and anionic GOT. It seemed that both of them were distributed in supernatant fraction. 3. GOT isozymes of rice root on the pH dependance showed their maximum activity at 7.4. 4. On the stability of GOT isozymes for temperature, anionic GOT was more unstable than cationic GOT. 5. Apparent Michaelis constant for L-aspartate of GOT isozymes from rice root showed 12-14mM in the cationic GOT and 16mM in the anionic GOT, respectively.

  • PDF