• Title/Summary/Keyword: temperature and carbon potential distribution

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Studies on Combustion Synthesis of Carbon Nanotubes Using a Double-faced Wall Stagnation Flow Burner (양면정체유동버너를 이용한 탄소나노튜브 합성에 대한 연구)

  • Hong, Young-Taek;Woo, Sang-Kil;Kwon, Oh-Chae
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2154-2159
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    • 2007
  • The potential of using a double-faced wall stagnation flow burner in mass production of carbon nanotubes was evaluated experimentally and computationally. With nitrogen-diluted premixed ethylene-air flames established on the Nickel-coated stainless steel double-faced wall, the propensities of carbon nanotube formation were experimentally determined using SEM and FE-TEM images and Raman spectroscopy, while the flame structure was computationally predicted using a 3-dimensional CFD code with a reduced reaction mechanism. The uniformity and yields of synthesized carbon nanotubes were evaluated in terms of the flame stretch rates. Results show substantial increase of area on the wall surface where uniform carbon nanotubes are synthesized with using the double-faced wall stagnation flow burner due to enhanced uniformity of temperature distribution along the wall surface and support the potential of using a double-faced wall stagnation flow burner in mass production of carbon nanotubes.

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Nonlinear finite element solutions of thermoelastic flexural strength and stress values of temperature dependent graded CNT-reinforced sandwich shallow shell structure

  • Mehar, Kulmani;Panda, Subrata K.
    • Structural Engineering and Mechanics
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    • v.67 no.6
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    • pp.565-578
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    • 2018
  • This research article reported the nonlinear finite solutions of the nonlinear flexural strength and stress behaviour of nano sandwich graded structural shell panel under the combined thermomechanical loading. The nanotube sandwich structural model is derived mathematically using the higher-order displacement polynomial including the full geometrical nonlinear strain-displacement equations via Green-Lagrange relations. The face sheets of the sandwich panel are assumed to be carbon nanotube-reinforced polymer composite with temperature dependent material properties. Additionally, the numerical model included different types of nanotube distribution patterns for the sandwich face sheets for the sake of variable strength. The required equilibrium equation of the graded carbon nanotube sandwich structural panel is derived by minimizing the total potential energy expression. The energy expression is further solved to obtain the deflection values (linear and nonlinear) via the direct iterative method in conjunction with finite element steps. A computer code is prepared (MATLAB environment) based on the current higher-order nonlinear model for the numerical analysis purpose. The stability of the numerical solution and the validity are verified by comparing the published deflection and stress values. Finally, the nonlinear model is utilized to explore the deflection and the stresses of the nanotube-reinforced (volume fraction and distribution patterns of carbon nanotube) sandwich structure (different core to face thickness ratios) for the variable type of structural parameter (thickness ratio, aspect ratio, geometrical configurations, constraints at the edges and curvature ratio) and unlike temperature loading.

Barriers to Realization of Forestry Mitigation Potential in India

  • Murthy, Indu K;Prasad KV, Devi
    • Journal of Forest and Environmental Science
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    • v.34 no.5
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    • pp.405-411
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    • 2018
  • Implementation of mitigation options on land is important for realisation of the goals of the Paris Agreement to stabilize temperature at $2^{\circ}C$. In India, the Intended Nationally Determined Contribution (INDC) targets include a forestry goal of creation of carbon sinks of 2.5 to 3 billion tonnes by 2030. There are however, multiple barriers to implementation of forestry mitigation options in India. They include environmental, social, financial, technological and institutional barriers. The barriers are varied not just across land categories but also for a land category depending on its regional location and distribution. In addition to these barriers is the impeding climate change that places at risk realisation of the mitigation potential as rising temperatures, drought, and fires associated with projected climate change may lead to forests becoming a weaker sink or a net carbon source before the end of the century.

Seasonal variation of assimilable organic carbon and its impact to the biostability of drinking water

  • Choi, Yonkyu;Park, Hyeon;Lee, Manho;Lee, Gun-Soo;Choi, Young-june
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.501-512
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    • 2019
  • The seasonal effects on the biostability of drinking water were investigated by comparing the seasonal variation of assimilable organic carbon (AOC) in full-scale water treatment process and adsorption of AOC by three filling materials in lab-scale column test. In full-scale, pre-chlorination and ozonation significantly increase $AOC_{P17\;(Pseudomonas\;fluorescens\;P17)}$ and $AOC_{NOX\;(Aquaspirillum\;sp.\;NOX)}$, respectively. AOC formation by oxidation could increase with temperature, but the increased AOC could affect the biostability of the following processes more significantly in winter than in warm seasons due to the low biodegradation in the pipes and the processes at low temperature. $AOC_{P17}$ was mainly removed by coagulation-sedimentation process, especially in cold season. Rapid filtration could effectively remove AOC only during warm seasons by primarily biodegradation, but biological activated carbon filtration could remove AOC in all seasons by biodegradation during warm season and by adsorption and bio-regeneration during cold season. The adsorption by granular activated carbon and anthracite showed inverse relationship with water temperature. The advanced treatment can contribute to enhance the biostability in the distribution system by reducing AOC formation potential and helping to maintain stable residual chlorine after post-chlorination.

Improvement of thermal buckling response of FG-CNT reinforced composite beams with temperature-dependent material properties resting on elastic foundations

  • Bensaid, Ismail;Kerboua, Bachir
    • Advances in aircraft and spacecraft science
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    • v.6 no.3
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    • pp.207-223
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    • 2019
  • Current investigation deals with the thermal stability characteristics of carbon nanotube reinforced composite beams (CNTRC) on elastic foundation and subjected to external uniform temperature rise loading. The single-walled carbon nanotubes (SWCNTs) are supposed to have a distribution as being uniform or functionally graded form. The material properties of the matrix as well as reinforcements are presumed to be temperature dependent and evaluated through the extended rule of mixture which incorporates efficiency parameters to capture the size dependency of the nanocomposite properties. The governing differential equations are achieved based on the minimum total potential energy principle and Euler-Bernoulli beam model. The obtained results are checked with the available data in the literature. Numerical results are supplied to examine the effects of numerous parameters including length to thickness ratio, elastic foundations, temperature change, and nanotube volume fraction on the thermal stability behaviors of FG-CNT beams.

Physicochemical and Adsorptive Properties of Black Carbon for Radioactive Cesium under Various Combustion Conditions and Tree Species (연소 조건과 수종을 달리한 블랙카본의 물리화학적 성질 및 세슘의 흡착 특성)

  • Jeon, Sodam;Choung, Sungwook;Han, Weon Shik;Jang, Kyoung-Soon;Shin, Woosik;Hwang, Jeonghwan
    • Journal of Korean Society on Water Environment
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    • v.33 no.6
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    • pp.689-695
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    • 2017
  • This study was carried out to investigate the physicochemical and adsorptive characteristics of black carbon (BC) materials for cesium in case of severe nuclear accidents. The BC was prepared with a xylem of oak and pine trees incompletely combusted with different ramp rate and final temperature. Carbon (C), hydrogen (H) and oxygen (O) atomic ratios, BET, pore structure, and zeta potential were characterized for the produced BC. A low cesium concentration ($C_w{\approx}10^{-7}M$) was used for sorption batch experiments. The H/C and O/C ratios of BC decreased with the increase of final temperature, which indicates a carbonization of the wood materials regardless of ramp rate and tree species. However, SEM images showed different pore structures depending on tree species such as steric and plate-like for oak-BC and pine-BC, respectively. The greatest sorption distribution coefficients of $K_{d,Cs}{\approx}1,200{\sim}1,800L\;kg^{-1}$ were observed for the oak-BC produced at $400^{\circ}C$, while comparatively low $K_{d,Cs}$ < $100L\;kg^{-1}$ for pine-BC. In addition, the sorption capabilities of BC declined with the increase of combustion temperature up to $600^{\circ}C$, because high temperature destroyed surface functionalities with the rise of ash components in the BC. Therefore, the sorption processes of BC for radioactive cesium are predominantly controlled by final production temperature of BC as well as raw materials (e.g., tree species).

Analytical solution for buckling analysis of micro sandwich hollow circular plate

  • Mousavi, Mohammad;Mohammadimehr, Mehdi;Rostami, Rasoul
    • Computers and Concrete
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    • v.24 no.3
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    • pp.185-192
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    • 2019
  • In this paper, the buckling of micro sandwich hollow circular plate is investigated with the consideration of the porous core and piezoelectric layer reinforced by functionally graded (FG)carbon nano-tube. For modeling the displacement field of sandwich hollow circular plate, the high-order shear deformation theory (HSDT) of plate and modified couple stress theory (MCST) are used. The governing differential equations of the system can be derived using the principle of minimum potential energy and Maxwell's equation that for solving these equations, the Ritz method is employed. The results of this research indicate the influence of various parameters such as porous coefficients, small length scale parameter, distribution of carbon nano-tube in piezoelectric layers and temperature on critical buckling load. The purpose of this research is to show the effect of physical parameters on the critical buckling load of micro sandwich plate and then optimize these parameters to design structures with the best efficiency. The results of this research can be used for optimization of micro-structures and manufacturing different structure in aircraft and aerospace.

Effect of Distribution System Materials and Water Quality on Heterotrophic Plate Counts and Biofilm Proliferation

  • CHANG , YOUNG-CHEOL;JUNG, KWEON
    • Journal of Microbiology and Biotechnology
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    • v.14 no.6
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    • pp.1114-1119
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    • 2004
  • The biofilms on pipe walls in water distribution systems are of interest since they can lead to chlorine demand, coliform growth, pipe corrosion, and water taste and odor problems. As such, the study described in this paper is part of an AWWARF and Tampa Bay Water tailored collaboration project to determine the effect of blending different source waters on the water quality in various distribution systems. The project was based on 18 independent pilot distribution systems (PDS), each being fed by a different water blend (7 finished waters blended in different proportions). The source waters compared were groundwater, surface water, and brackish water, which were treated in a variety of pilot distribution systems, including reverse osmosis (RO) (desalination), both membrane and chemical softening, and ozonation-biological activated carbon (BAC), resulting in a total of 7 different finished waters. The observations from this study consistently demonstrated that unlined ductile iron was more heavily colonized by a biomass than galvanized steel, lined ductile iron, and PVC (in that order) and that the fixed biomass accumulation was more influenced by the nature of the supporting material than by the water quality (including the secondary residual levels). However, although the bulk liquid water cultivable bacterial counts (i.e. heterotrophic plate counts or HPCs) did not increase with a greater biofilm accumulation, the results also suggested that high HPCs corresponded to a low disinfectant residual more than a high biofilm inventory. Furthermore, temperature was found to affect the biofilms, plus the AOC was important when the residual was between 0.6 and 2.0 mg $Cl_2/l$. An additional aspect of the current study was that the potential of the exoproteolytic activity (PEPA) technique was used along with a traditional so-called destructive technique in which the biofilm was scrapped off the coupon surface, resuspended, and cultivated on an R2A agar. Both techniques indicated similar trends and relative comparisons among the PDSs, yet the culturable biofilm values for the traditional method were several orders of magnitude lower than the PEPA values.

RF and Optical properties of Graphene Oxide

  • Im, Ju-Hwan;Rani, J.R.;Yun, Hyeong-Seo;O, Ju-Yeong;Jeong, Yeong-Mo;Park, Hyeong-Gu;Jeon, Seong-Chan
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.68.1-68.1
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    • 2012
  • The best part of graphene is - charge-carriers in it are mass less particles which move in near relativistic speeds. Comparing to other materials, electrons in graphene travel much faster - at speeds of $10^8cm/s$. A graphene sheet is pure enough to ensure that electrons can travel a fair distance before colliding. Electronic devices few nanometers long that would be able to transmit charge at breath taking speeds for a fraction of power compared to present day CMOS transistors. Many researches try to check a possibility to make it a perfect replacement for silicon based devices. Graphene has shown high potential to be used as interconnects in the field of high frequency electrical devices. With all those advantages of graphene, we demonstrate characteristics of electrical and optical properties of graphene such as the effect of graphene geometry on the microwave properties using the measurements of S-parameter in range of 500 MHz - 40 GHz at room temperature condition. We confirm that impedance and resistance decrease with increasing the number of graphene layer and w/L ratio. This result shows proper geometry of graphene to be used as high frequency interconnects. This study also presents the optical properties of graphene oxide (GO), which were deposited in different substrate, or influenced by oxygen plasma, were confirmed using different characterization techniques. 4-6 layers of the polycrystalline GO layers, which were confirmed by High resolution transmission electron microscopy (HRTEM) and electron diffraction analysis, were shown short range order of crystallization by the substrate as well as interlayer effect with an increase in interplanar spacing, which can be attributed to the presence of oxygen functional groups on its layers. X-ray photoelectron Spectroscopy (XPS) and Raman spectroscopy confirms the presence of the $sp^2$ and $sp^3$ hybridization due to the disordered crystal structures of the carbon atoms results from oxidation, and Fourier Transform Infrared spectroscopy (FTIR) and XPS analysis shows the changes in oxygen functional groups with nature of substrate. Moreover, the photoluminescent (PL) peak emission wavelength varies with substrate and the broad energy level distribution produces excitation dependent PL emission in a broad wavelength ranging from 400 to 650 nm. The structural and optical properties of oxygen plasma treated GO films for possible optoelectronic applications were also investigated using various characterization techniques. HRTEM and electron diffraction analysis confirmed that the oxygen plasma treatment results short range order crystallization in GO films with an increase in interplanar spacing, which can be attributed to the presence of oxygen functional groups. In addition, Electron energy loss spectroscopy (EELS) and Raman spectroscopy confirms the presence of the $sp^2$ and $sp^3$ hybridization due to the disordered crystal structures of the carbon atoms results from oxidation and XPS analysis shows that epoxy pairs convert to more stable C=O and O-C=O groups with oxygen plasma treatment. The broad energy level distribution resulting from the broad size distribution of the $sp^2$ clusters produces excitation dependent PL emission in a broad wavelength range from 400 to 650 nm. Our results suggest that substrate influenced, or oxygen treatment GO has higher potential for future optoelectronic devices by its various optical properties and visible PL emission.

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