• Title/Summary/Keyword: technology absorption capacity

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Development of Carbonization Technology and Application of Unutilized Wood Wastes(I) -Carbonization and It's Properties of Thinned Trees- (미이용 목질폐잔재의 탄화 이용개발(I) -수종의 간벌재 탄화와 탄화물의 특성-)

  • Kim, Byung-Ro;Kong, Seog-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.2
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    • pp.70-77
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    • 1999
  • Objective of this research is to obtain fundamental data of carbonized wood wastes for soil condition, de-ordorization, absorption of water, carrier for microbial activity, and purifying agent for water quality of river. The carbonization technique and the properties of carbonized wood wastes(thinned trees) are analyzed. Proximate analysis shows the thinned wood contains 0.22-0.73% ash, 77-80% volatile matter, and 10-14% fixed carbon. The charcoal yield decreases and the shrinkage rate increases as the carbonization temperature and time increase. The charcoal yields of Larix leptolepis, Pinus rigida and Pinus densiflora are high, whereas those of Pinus koraiensis and Quercus variabilis are low. The shrinkage rate by carbonization has same trend as water removal of wood. The specific gravity after the carbonization decreases about 50% comparing to green wood. The charcoal has 0.89-4.08% ash, 6.31-13.79% volatile matter, and 73.9-83.5% fixed carbon. As the carbonization temperature and time increase, pH of charcoal increases. When the carbonization temperature is $400^{\circ}C$, pH is about 7.5. When the temperature is between 600 to $800^{\circ}C$, pH is about 10 with small difference. The water-retention capacity is not affected by the carbonization temperature and time. The water-retention capacity within 24hr is about 2.5 - 3times of sample weight, and the equivalent moisture content becomes 2-10% after 24 hr.

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Adsorption Characteristic of Brownish Dark Colored Compounds from the Hot Water Extract of Auricularia auricula Fruit Body (흑목이 버섯 자실체의 열수추출물로부터 흑갈색 색소 성분의 흡착 특성)

  • Kim, Hyeon-Min;Hur, Won;Lim, Kun Bin;Lee, Shin-Young
    • Food Engineering Progress
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    • v.13 no.2
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    • pp.138-146
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    • 2009
  • The crude polysaccharide fraction from fruit body of Auricularia auricula were obtained by using hot water extraction and ethanol precipitation. As the crude polysaccharide fraction contained the brownish dark colored compounds, the adsorption study of pigments from the crude polysaccharide using activated carbon was carried out. The pigment compounds showed an absorption characteristic with $\lambda_{max}$ of 230 nm and the absorbance at 230 nm was taken as color intensity. Adsorption capacity of pigment depended on increase of the activated carbon to sample loading ratio. The adsorption capacity increased with increase of pH and temperature in the pH range of 3.0-7.0 and temperature range of 25-40$^{\circ}C$, but decreased in the temperature range of 40-70$^{\circ}C$. The optimum capacity was obtained at addition of 16.7 mg activated carbon per mL sample solution (concentration = 3 mg/mL) at pH of 7.0 and temperature of 40$^{\circ}C$. Treatment for 10 min was sufficient to achieve the 80% decolorization and 1.25 fold purification of polysaccharide. Langmuir isotherm and pseudo second-order kinetic model provided the best fitting for adsorption of the brownish dark colored compounds onto powdered active carbon. The activation energies of adsorption from the Langmuir isotherm parameter in the ranges of 25-40$^{\circ}C$ and 40-70$^{\circ}C$ was -2.54 and 4.38 kcal/g, respectively. The results of low activation energy also indicated that the adsorption process was a physical adsorption which was controlled by diffnsion.

Adsorption of an uranyl ion onto a divinylbenzene amidoxime resin in sodium carbonate solutions (탄산염 용액에서 아미드옥심 수지에 대한 우리닐 이온의 흡착거동)

  • Joe, Kihsoo;Lee, Eil-Hee;Kim, Kwang-Wook;Song, Kyuseok
    • Analytical Science and Technology
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    • v.21 no.4
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    • pp.326-331
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    • 2008
  • Distribution coefficients (Kd) of uranyl ion onto divinylbenzene amidoxime resins were measured in sodium carbonate solution and the Kd values were increased up to about 70 as the resin bead size was decreased. At a condition of 0.0044 M $Na_2CO_3$, the adsorption capacity for uranium was $3.4{\mu}mole$ U/g-resin. The Kd values in the 0.5 M $Na_2CO_3-NaHCO_3$ solution, ranging from pH 9 to pH 11, revealed that they were increased as the pH increased and revealed lower values than those in the pure sodium carbonate solution. The amidoxime resins were characterized by FTIR-ATR showing the absorption bands of the amidoxime functional groups. A species of the uranyltricarbonate complex, $UO_2(CO_3)_3^{-4}$, was confirmed by UV-Vis spectroscopy, revealing four absorption peaks between 400 and 500 nm. Uranium was separated from some fission products by a column operation. However, most of the uranium and fission products were eluted before an adsorption and only a small amount of uranium was adsorbed onto the resin due to the low capacity of the resin.

Zeolites: Their Features as Pressure Swing Adsorbents and CO2 Adsorption Capacity (제올라이트: 압력순환형 흡착제로서의 특성과 CO2 흡착성능)

  • Kim, Moon-Hyeon;Cho, Il-Hum;Choi, Sang-Ok;Choo, Soo-Tae
    • Journal of Environmental Science International
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    • v.23 no.5
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    • pp.943-962
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    • 2014
  • Industrial gas drying, dilute gas mixtures purification, air fractionation, hydrogen production from steam reformers and petroleum refinery off-gases, etc are conducted by using adsorptive separation technology. The pressure swing adsorption (PSA) has certain advantages over the other methods, such as absorption and membrane, that are a low energy requirement and cost-effectiveness. A key component of PSA systems is adsorbents that should be highly selective to a gas being separated from its mixture streams and have isotherms suitable for the operation principle. The six standard types of isotherms have been examined in this review, and among them the best behavior in the adsorption of $CO_2$ as a function of pressure was proposed in aspects of maximizing a working capacity upon excursion between adsorption and desorption cycles. Zeolites and molecular sieves are historically typical adsorbents for such PSA applications in gas and related industries, and their physicochemical features, e.g., framework, channel structure, pore size, Si-to-Al ratio (SAR), and specific surface area, are strongly associated with the extent of $CO_2$ adsorption at given conditions and those points have been extensively described with literature data. A great body of data of $CO_2$ adsorption on the nanoporous zeolitic materials have been collected according to pressure ranges adsorbed, and these isotherms have been discussed to get an insight into a better $CO_2$ adsorbent for PSA processes.

The Properties of Concrete with Lightweight Aggregate Impregnated by Phase Change Material (상변화물질 함침 경량골재를 사용한 콘크리트의 특성)

  • Kim, Se-Hwan;Jeon, Hyun-Kyu;Hwang, In-Dong;Seo, Chee-Ho;Kim, Sang-Heon
    • Journal of the Korea Concrete Institute
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    • v.25 no.3
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    • pp.331-338
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    • 2013
  • Under the paradigm of sustainable green growth at the national level, various researches and applications for energy saving in the construction field has been attempted. As a part of energy saving efforts, lightweight concrete was investigated for thermal insulation concrete with phase change material (PCM) which has high heat storage capacity. As a part of energy saving efforts, thermal insulation concrete was investigated and evaluated with lightweight aggregate impregnated by PCM which has high heat storage capacity. As a result, it is found that concrete with lightweight aggregate impregnated by PCM is effective to prevent its quality deterioration by reducing water absorption rate of lightweight aggregate. In addition, it has shown that concretes using lightweight aggregate and impregnated lightweight aggregate improve heat insulation property 33% and 40~43% compared with using normal aggregate, respectively. It is that the lightweight aggregate concrete with impregnated lightweight aggregate has 12~14% lower thermal conductivity than unimpregnated.

The Root Cause of the Rate Performance Improvement After Metal Doping: A Case Study of LiFePO4

  • Park, Chang-Kyoo;Park, Sung-Bin;Park, Ji-Hun;Shin, Ho-Chul;Cho, Won-Il;Jang, Ho
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.921-926
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    • 2011
  • This study investigates a root cause of the improved rate performance of $LiFePO_4$ after metal doping to Fesites. This is because the metal doped $LiFePO_4$/C maintains its initial capacity at higher C-rates than undoped one. Using $LiFePO_4$/C and doped $LiFe_{0.97}M_{0.03}PO_4$/C (M=$Al^{3+}$, $Cr^{3+}$, $Zr^{4+}$), which are synthesized by a mechanochemical process followed by one-step heat treatment, the Li content before and after chemical delithiation in the $LiFePO_4$/C and the binding energy are compared using atomic absorption spectroscopy (AAS) and X-ray photoelectron spectroscopy (XPS). The results from AAS and XPS indicate that the low Li content of the metal doped $LiFePO_4$/C after chemical delithiation is attributed to the low binding energy induced by weak Li-O interactions. The improved capacity retention of the doped $LiFePO_4$/C at high discharge rates is, therefore, achieved by relatively low binding energy between Li and O ions, which leads to fast Li diffusivity.

Experimental study of failure mechanisms in elliptic-braced steel frame

  • Jouneghani, Habib Ghasemi;Haghollahi, Abbas;Beheshti-Aval, S. Bahram
    • Steel and Composite Structures
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    • v.37 no.2
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    • pp.175-191
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    • 2020
  • In this article, for the first time, the seismic behavior of elliptic-braced moment resisting frame (ELBRF) is assessed through a laboratory program and numerical analyses of FEM specifically focused on the development of global- and local-type failure mechanisms. The ELBRF as a new lateral braced system, when installed in the middle bay of the frames in the facade of a building, not only causes no problem to the opening space of the facade, but also improves the structural behavior. Quantitative and qualitative investigations were pursued to find out how elliptic braces would affect the failure mechanism of ELBRF structures exposed to seismic action as a nonlinear process. To this aim, an experimental test of a ½ scale single-story single-bay ELBRF specimen under cyclic quasi-static loading was run and the results were compared with those for X-bracing, knee-bracing, K-bracing, and diamond-bracing systems in a story base model. Nonlinear FEM analyses were carried out to evaluate failure mechanism, yield order of components, distribution of plasticity, degradation of structural nonlinear stiffness, distribution of internal forces, and energy dissipation capacity. The test results indicated that the yield of elliptic braces would delay the failure mode of adjacent elliptic columns and thus, help tolerate a significant nonlinear deformation to the point of ultimate failure. Symmetrical behavior, high energy absorption, appropriate stiffness, and high ductility in comparison with the conventional systems are some of the advantages of the proposed system.

Investigation of Oxidation Methods of Organic Radical Polymer for Cathode Material in Lithium Ion Batteries (리튬이차전지 양극재인 유기라디칼 고분자의 산화법에 대한 연구)

  • Lee, Ilbok;Kim, Younghoon;Moon, Ji-Yeon;Lee, Chul Wee;Kim, Daeun;Ha, Kyoung-Su;Lee, Dong Hyun;Son, Hyungbin;Yoon, Songhun
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.827-831
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    • 2014
  • An organic radical polymer (ORP) was prepared by radical polymerization and following oxidation into nitroxyl radical. Two different oxidation methods were employed and their radical concentrations were measured using electroparamagnetic resonance spectroscopy (EPR) and UV-visible absorption (UV-vis) spectroscopy. From these measurements, $H_2O_2-Na_2WO_4$ oxidation method exhibited a complete oxidation, which resulted in 97.6% spin concentration. Also, it was revealed that convenient and cheap UV-vis measurement was useful for preliminary radical concentration comparison. After applied as a cathode material in lithium ion batteries, ORP electrode showed a high initial capacity ($110mAh\;g^{-1}$), a good initial efficiency (96%), a very high rate performance (70% charging during 1.2 min) and stable cycle performance.

Computer based estimation of backbone curves for hysteretic Response of reinforced concrete columns under static cyclic lateral loads

  • Rizwan, M.;Chaudhary, M.T.A.;Ilyas, M.;Hussain, Raja Rizwan;Stacey, T.R.
    • Computers and Concrete
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    • v.14 no.2
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    • pp.193-209
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    • 2014
  • Cyclic test of the columns is of practical relevance to the performance of compression members during an earthquake loading. The strength, ductility and energy absorption capabilities of reinforced concrete (RC) columns subjected to cyclic loading have been estimated by many researchers. These characteristics are not normally inherent in plain concrete but can be achieved by effectively confining columns through transverse reinforcement. An extensive experimental program, in which performance of four RC columns detailed according to provisions of ACI-318-08 was studied in contrast with that of four columns confined by a new proposed technique. This paper presents performance of columns reinforced by standard detailing and cast with 25 and 32 MPa concrete. The experimentally achieved load-displacement hysteresis and backbone curves of two columns are presented. The two approaches which work in conjunction with Response 2000 have been suggested to draw analytical back bone curves of RC columns. The experimental and analytical backbone curves are found in good agreement. This investigation gives a detail insight of the response of RC columns subjected to cyclic loads during their service life. The suggested analytical procedures will be available to the engineers involved in design to appraise the capacity of RC columns.

MODELING OF NONLINEAR CYCLIC LOAD BEHAVIOR OF I-SHAPED COMPOSITE STEEL-CONCRETE SHEAR WALLS OF NUCLEAR POWER PLANTS

  • Ali, Ahmer;Kim, Dookie;Cho, Sung Gook
    • Nuclear Engineering and Technology
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    • v.45 no.1
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    • pp.89-98
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    • 2013
  • In recent years steel-concrete composite shear walls have been widely used in enormous high-rise buildings. Due to high strength and ductility, enhanced stiffness, stable cycle characteristics and large energy absorption, such walls can be adopted in the auxiliary building; surrounding the reactor containment structure of nuclear power plants to resist lateral forces induced by heavy winds and severe earthquakes. This paper demonstrates a set of nonlinear numerical studies on I-shaped composite steel-concrete shear walls of the nuclear power plants subjected to reverse cyclic loading. A three-dimensional finite element model is developed using ABAQUS by emphasizing on constitutive material modeling and element type to represent the real physical behavior of complex shear wall structures. The analysis escalates with parametric variation in steel thickness sandwiching the stipulated amount of concrete panels. Modeling details of structural components, contact conditions between steel and concrete, associated boundary conditions and constitutive relationships for the cyclic loading are explained. Later, the load versus displacement curves, peak load and ultimate strength values, hysteretic characteristics and deflection profiles are verified with experimental data. The convergence of the numerical outcomes has been discussed to conclude the remarks.