• 제목/요약/키워드: technology absorption capacity

검색결과 267건 처리시간 0.029초

Amorphous Vanadium Titanates as a Negative Electrode for Lithium-ion Batteries

  • Lee, Jeong Beom;Chae, Oh. B.;Chae, Seulki;Ryu, Ji Heon;Oh, Seung M.
    • Journal of Electrochemical Science and Technology
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    • 제7권4호
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    • pp.306-315
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    • 2016
  • Amorphous vanadium titanates (aVTOs) are examined for use as a negative electrode in lithium-ion batteries. These amorphous mixed oxides are synthesized in nanosized particles (<100 nm) and flocculated to form secondary particles. The $V^{5+}$ ions in aVTO are found to occupy tetrahedral sites, whereas the $Ti^{4+}$ ions show fivefold coordination. Both are uniformly dispersed at the atomic scale in the amorphous oxide matrix, which has abundant structural defects. The first reversible capacity of an aVTO electrode ($295mAhg^{-1}$) is larger than that observed for a physically mixed electrode (1:2 $aV_2O_5$ | $aTiO_2$, $245mAhg^{-1}$). The discrepancy seems to be due to the unique four-coordinated $V^{5+}$ ions in aVTO, which either are more electron-accepting or generate more structural defects that serve as $Li^+$ storage sites. Coin-type Li/aVTO cells show a large irreversible capacity in the first cycle. When they are prepared under nitrogen (aVTO-N), the population of surface hydroxyl groups is greatly reduced. These groups irreversibly produce highly resistive inorganic compounds (LiOH and $Li_2O$), leading to increased irreversible capacity and electrode resistance. As a result, the material prepared under nitrogen shows higher Coulombic efficiency and rate capability.

Seismic behavior of steel and sisal fiber reinforced beam-column joint under cyclic loading

  • S.M. Kavitha;G. Venkatesan;Siva Avudaiappan;Chunwei Zhang
    • Structural Engineering and Mechanics
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    • 제88권5호
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    • pp.481-492
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    • 2023
  • The past earthquakes revealed the importance of the design of moment-resisting reinforced concrete framed structures with ductile behavior. Due to seismic activity, failures in framed structures are widespread in beam-column joints. Hence, the joints must be designed to possess sufficient strength and stiffness. This paper investigates the effects of fibers on the ductility of hybrid fiber reinforced self-compacting concrete (HFRSCC) when subjected to seismic actions; overcoming bottlenecks at the beam-column joints has been studied by adding low modulus sisal fiber and high modulus steel fiber. For this, the optimized dose of hooked end steel fiber content (1.5%) was kept constant, and the sisal fiber content was varied at the rate of 0.1%, up to 0.3%. The seismic performance parameters, such as load-displacement behavior, ductility, energy absorption capacity, stiffness degradation, and energy dissipation capacity, were studied. The ductility factor and the cumulative energy dissipation capacity of the hybrid fiber (steel fiber, 1.5% and sisal fiber, 0.2%) added beam-column joint specimen is 100% and 121% greater than the control specimen, respectively. And also the stiffness of the hybrid fiber reinforced specimen is 100% higher than the control specimen. Thus, the test results showed that adding hybrid fibers instead of mono fibers could significantly enhance the seismic performance parameters. Therefore, the hybrid fiber reinforced concrete with 1.5% steel and 0.2% sisal fiber can be effectively used to design structures in seismic-prone areas.

건조방법에 따른 표고버섯분말의 흡습특성 (Absorption Characteristcs of Dried Shiitake Mushroom Powder Using Different Drying Methods)

  • 고재우;이원영;이준호;하영선;최용희
    • 한국식품과학회지
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    • 제31권1호
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    • pp.128-137
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    • 1999
  • 현재 조미료 및 부침가루로 사용되고 있는 표고버섯분말을 사용하여 열풍건조, 진공건조, 동결건조를 이용하여 건조를 행하였다. 각 건조 방법별로 표고버섯분말은 조직구조 및 물리적 특성치인 pore size도 다르게 나타났다. 또한 건조 방법별로 품질 분석을 한 결과 일반성분에서는 초기 수분함량에서 다소 차이가 있었으나 전체적인 차이는 크게 나지 않았다. 또한 건조 표고버섯의 맛 성분인 핵산을 분석한 결과에서도 큰 차이를 나타내지 않았으며, 총페놀 함량에서도 유사한 결과를 나타냈다. 이러한 결과를 토대로 표고버섯 분말의 흡습특성을 조사한 결과 pore size가 가장 큰 동결건조에서 가장 높은 흡습량을 가져왔으며, pore size의 크기에 따라 진공건조, 열풍건조 순으로 흡습량이 많았다. 그리고 저장 온도별로는 가장 낮은 온도인 $5^{\circ}C$에서 가장 높은 흡습을 보여주었으며, $35^{\circ}C$에서는 흡습량이 상대적으로 낮았다. 그러나 $35^{\circ}C$ 상대 습도 84%의 저장온도에서는 진공건조 및 동결건조 시료에서 저장 11일만에 곰팡이가 생겨났으므로 평형수분함량을 측정하지 못하였다. 저장 적정 수분함량을 구하기 위해 단분자층 수분함량을 구한 결과는 동결건조한 시료가 다른 시료보다 높은 값을 나타내었고, 흡습 엔탈피는 동결건조한 것이 가장 높은 값을 보여주었다. 또한 표고버섯분말의 평형수분함량 예측을 위해 현재까지 가장 적합성이 높다는 여러 가지 식으로 적합성을 살펴본 결과 단백질 함량이 비슷한 Khun식과 Mizrahi 식이 적합성이 가장 높았다. 그러나 이러한 식들은 상대습도만으로 구한 값이므로 상대습도뿐만 아니라 온도 및 공극을 변수로 넣어 회귀식을 도출한 결과 $R^2$가 0.989의 적용도가 높은 식을 구하였다.

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Seismic behavior of stiffened concrete-filled double-skin tubular columns

  • Shekastehband, B.;Mohammadbagheri, S.;Taromi, A.
    • Steel and Composite Structures
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    • 제27권5호
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    • pp.577-598
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    • 2018
  • The imperfect steel-concrete interface bonding is an important deficiency of the concrete-filled double skin tubular (CFDST) columns that led to separating concrete and steel surfaces under lateral loads and triggering buckling failure of the columns. To improve this issue, it is proposed in this study to use longitudinal and transverse steel stiffeners in CFDST columns. CFDST columns with different patterns of stiffeners embedded in the interior or exterior surfaces of the inner or outer tubes were analyzed under constant axial force and reversed cyclic loading. In the finite element modeling, the confinement effects of both inner and outer tubes on the compressive strength of concrete as well as the effect of discrete crack for concrete fracture were incorporated which give a realistic prediction of the seismic behavior of CFDST columns. Lateral strength, stiffness, ductility and energy absorption are evaluated based on the hysteresis loops. The results indicated that the stiffeners had determinant role on improving pinching behavior resulting from the outer tube's local buckling and opening/closing of the major tensile crack of concrete. The lateral strength, initial stiffness and energy absorption capacity of longitudinally stiffened columns with fixed-free end condition were increased by as much as 17%, 20% and 70%, respectively. The energy dissipation was accentuated up to 107% for fixed-guided end condition. The use of transverse stiffeners at the base of columns increased energy dissipation up to 35%. Axial load ratio, hollow ratio and concrete strength affecting the initial stiffness and lateral strength, had negligible effect of the energy dissipation of the columns. It was also found that the longitudinal stiffeners and transverse stiffeners have, respectively, negative and positive effects on ductility of CFDST columns. The conclusions, drawn from this study, can in turn, lead to the suggestion of some guidelines for the design of CFDST columns.

한국산 밀가루의 이화학적(理化學的) 특성(特性)과 쿠키 제조적성(製造適性) (Relation of Physicochemical Properties and Cookie Baking Potentialities of Korean Wheat Flours)

  • 장학길;신효선;김상순
    • 한국식품과학회지
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    • 제16권2호
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    • pp.149-152
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    • 1984
  • 한국산 소맥육성계통(小麥育成系統)에 대한 소맥분(小麥粉)의 이화학적(理化享的) 특성(特性)과 쿠키제조적성에 관하여 검토하였다. AWRC는 침전가(沈澱價). Pelshenke value 및 단백질함량과는 각각 $r=0.50^{**}$, $r=0.45^{**}$$r=0.47^{**}$의 정(正)의 유의상관(有意相關)이 있었고, 구키직경과 AWRC 및 단백질함량은 각각 $r=-0.98^{**}$$r=-0.46^{**}$의 부(負)의 상관(相關)이 있었다. Fa-ninograph absorption과 AWRC 및 쿠키직경과는 $r=0. 77^{**}$$r=-0.73$의 고도(高度)의 유의성(有意性)이 있었으며,Farino graph band width와 AWRC는 $r=-0.49^{**}$,쿠키직경과는 $r=0.44^{**}$의 상관(相關)이 있었다.

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폐타이어 분말을 혼입한 몰탈의 단열특성 (An Adiabatic Characteristic on the Waste tyre Powders Mortar-Containing)

  • 최재남;손기상
    • 한국안전학회지
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    • 제20권2호
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    • pp.105-112
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    • 2005
  • This is to find out that cement mortar mixed with waste tie particle can be applied for recycling it and enhanced to have shock absorption capacity. Therefore, architectural material specification and its related references for the disposal of it are based on for the study. Test has been performed with procedure, based on the Korea Standard insulation mortar and Compressive Strength Test has been done at K remicon factory approved by Korea Government in Korea, in order to decrease any possible error in mixing procedure. Test molds far insulation capacity and cohesive strength have been delivered to the expert agency for having more exact results. The result from the above test shows that waste tyre mixed with cement mortar has almost equal to the common concrete. This means that the recycling of the waste t)re will be demanded more and more in case of having continued development for this recycling area. And also waste t)to-using construction material can be more applied for construction area than existing material. Thus, this recycling method can be very usefully applied for solving environmental problem and for establishing economic aspect.

Influence of special plaster on the out-of-plane behavior of masonry walls

  • Donduren, Mahmut Sami;Kanit, Recep;Kalkan, Ilker;Gencel, Osman
    • Earthquakes and Structures
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    • 제10권4호
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    • pp.769-788
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    • 2016
  • The present study aimed at investigating the effect of a special plaster on the out-of-plane behavior of masonry walls. A reference specimen, plastered with conventional plaster, and a specimen plastered with a special plastered were tested under reversed cyclic lateral loading. The specimens were identical in dimensions and material properties. The special plaster contained an additive, which increased the adherence strength of the plaster to the wall. The amount of the additive in the mortar was adjusted based on the preliminary material tests. The influence of the plaster on the wall behavior was evaluated according to the initial cracking load, type of failure, energy absorption capacity (modulus of toughness), and crack pattern of the wall. Despite having limited contribution to the ductility, the special plaster increased the ultimate load capacity of the wall about 25%. The failure mode of the wall with special plaster resembled the plastic failure mechanism of a reinforced concrete slab in the formation of yielding lines along the wall. The deflection at failure and the modulus of toughness of the wall with special plaster were measured to be in order of 60% and 75% of the corresponding values of the reference wall.

루우핀콩 단백질 농축물(LPC)의 식품기능성 (Functional Properties of Lupinseed Protein Concentrate)

  • 김영욱;이철호
    • 한국식품과학회지
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    • 제19권6호
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    • pp.499-505
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    • 1987
  • 루우핀콩 단백질 농축물(LPC-50, LPC-70)을 제조하여 이들의 식품기능성들을 분리대두단백질 및 카제인 과 비교 검토하였다. LPC-50은 2상용매 추출법에 의해 제조한 단백질 함량 50% 수준의 유백색 물질이며 LPC-70은 LPC-50의 탄수화물 일부를 가수분해 효소로 처리해서 제거하여 단백질 농도를 70% 수준으로 높인 것이다. LPC-50의 건물 수율은 73.7%였으며 LPC-70은 55.7%였다. 또한 단백질 수율면에서는 LPC-50이 91% 였고 LPC-70이 87.4%였다. LPC-50과 LPC-70의 단백질 용해도는 증류수에서는 SPI와 비슷한 경향이 보였으나, NaCl 첨가시 pH $4.0{\sim}6.0$ 범위에서는 SPI보다 높았다. LPC-50과 LPC-70의 흐름성질은 8% 농도에서 강한 의가소성을 보였으며. 겉보기 점도는 6%부터 지수적으로 증가하였으며 그 증가 패턴은 카제인과 비슷한 경향이었다. 유화력은 단백질 농도가 증가할수록 커졌으며, LPC-70은 우수한 유화력을 나타내었고 특히 NaCl 첨가시 SPI와 비슷한 유화력을 나타내었다. LPC-50과 LPC-70의 기포 형성력은 SPI의 기포 형성력과 비슷하였으나, 안정성이 pH 7.0에서 비교적 낮은 결과를 보였다. 루우핀콩 단백질 농축물들은 우수한 수분 및 유지 흡착력을 나타냈으며, 특히 LPC-70은 매우 높은 유지 흡착력을 보였다.

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Optimized design of dual steel moment resisting system equipped with cross-anchored self-centering buckling restrained chevron brace

  • Khaneghah, Mohammadreza Ahadpour;Dehcheshmaeh, Esmaeil Mohammadi;Broujerdian, Vahid;Amiri, Gholamreza Ghodrati
    • Earthquakes and Structures
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    • 제23권2호
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    • pp.139-150
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    • 2022
  • In most self-center braces, decreasing residual deformation is possible only by increasing pretension force, which results in lower energy dissipation capacity. On the other hand, increasing energy dissipation capacity means higher values of residual deformation. The goal of this research was to find the best design for a self-centering buckling restrained brace (SC-BRB) system by balancing self-centering capability and energy dissipation. Three, six, and nine-story structures were investigated using OpenSees software and the TCL programming language to achieve this goal. For each height, 62 different SC-BRBs were considered using different values for the pretension force of cables, the area of the buckling restrained brace (BRB) core plate, and the yield stress of the core plate. The residual deformation and dissipated energy of all the models were calculated using nonlinear analyses after cyclic loading was applied. The optimum design for each height was determined among all the models and was compared to the structure equipped with the usual BRB. The residual deformation of the framed buildings was significantly reduced, according to the findings. Also the reduction of the energy dissipation was acceptable. The optimum design of SC-BRB in 6-story building has the most reduction percent in residual deformation, it can reduce residual deformation of building 83% while causing only a 57% of reduction in dissipated energy. The greatest reduction in residual deformation versus dissipated energy reduction was for the optimum SC-BRB design of 9-story building, results indicated that it can reduce residual deformation of building 69% while causing only a 42% of reduction in dissipated energy.

Influence of high temperature on mechanical properties of concrete containing recycled fine aggregate

  • Liang, Jiong-Feng;Wang, En;Zhou, Xu;Le, Qiao-Li
    • Computers and Concrete
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    • 제21권1호
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    • pp.87-94
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    • 2018
  • This paper presents the results of an experimental study to investigate the influences of high temperatures on the mechanical properties of concrete containing recycled fine aggregate. A total of 150 concrete prisms ($100{\times}100{\times}300mm$) and 150 concrete cubes ($100{\times}100{\times}100mm$) are cast and heated under five different temperatures ($20^{\circ}C$, $200^{\circ}C$, $400^{\circ}C$, $600^{\circ}C$, $800^{\circ}C$) for test. The results show that the mass loss, compressive strength, elastic modulus, splitting tensile strength of concrete specimens containing recycled fine aggregate decline significantly as the temperature rise. At the same temperature, the compressive strength, splitting tensile strength, elastic modulus of concrete specimens containing recycled coarse aggregate and recycled fine aggregate (RHC) is lower than that of concrete specimens containing natural coarse aggregate and recycled fine aggregate (RFC). The shape of stress-strain curves of concrete specimens at different temperatures is different, and the shape of that become flatter as the temperature rises. Normal concrete has better energy absorption capacity than concrete containing recycled fine aggregate.