• 폴리머
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• 제25권5호
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• pp.679-690
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• 2001

폴리에테르형 기포개방제를 사용한 고탄성 폴리우레탄 발포체의 제조에서 기포개방제의 농도변화가 계의 반응속도, 유변학적 성질, 발포체의 구조적인 안정성, 형태학적 성질 및 개방기포의 함량 등에 미치는 영향을 조사하고 이를 통하여 기포개방에서 기포개방제의 역할을 알아보았다. 또한 기포개방제의 농도에 따른 발포체의 기계적 물성을 관찰하였다. 기포개방제의 높은 친수성으로 인해 우레아 생성반응이 지연됨을 관찰하였다. 유변학적 성질의 관찰을 통하여 기고개방제의 농도 증가에 따라 계의 점도저하와 tan $\delta$의 증가를 확인하였고 이로 인해 얻어진 발포체는 낮은 구조적인 안정성과 높은 개방기포 함량을 나타내었다. 기포개방제의 농도 증가에 따라 matrix의 파괴와 matrix내 수소결합된 우레아의 고른 분산을 발포체의 형태학적 성질의 관찰로 확인할 수 있었다. 결론적으로 고탄성 폴리우레탄 발포체의 제조시 기포개방제의 높은 친수성에 기인하여 matrix의 탄성특성 저하가 일어나고 이로 인해 높은 개랑기포 함량을 가진 발포체가 형성됨을 알 수 있었다. 발포체의 경도, 인장강도, 인열강도, 신율 등은 기포개방제의 농도 증가에 따라 저하하였다.

• 한국응용과학기술학회지
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• 제16권2호
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• pp.179-185
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• 1999

본 연구에서는 연질 폴리우레탄 발포제 제조에서 여러 발포제와 내부온도, 기계적 물성과의 관계에 대해서 연구, 조사하였다. 발포제로는 물을 주발포제로 하여 보조발포제는 CFC-11(trichlorofluoromethane), HCFC-114b(dichlorofluoroethane), dichloromethane, n-pentane, iso-pentane, cyclopentane을 사용하였다. 기계적 물성을 측정하기 위하여 연질 폴리우레탄 발포제의 밀도가 $0.015{\pm}0.002g/cm^3$와 $0.024{\pm}0.002g/cm^3$인 두 종류의 발포제를 제조하였다. 연질 폴리우레탄의 발포제의 제조시 발포제별로 내부온도를 측정하였으며, 48시간 경과 후 밀도, 인장강도, 신장율, 인열강도, 압축강도, 압축영구변형률을 측정하였다. 연구 결과 dichloromethane과 cyclopentane이 보조발포제로 가장 적합하였다.

• 펄프종이기술
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• 제31권4호
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• pp.76-83
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• 1999

This study was carried to investigate optimum conditions of charcoal added paper in making cigarette filter for the removal of smoke contents of cigarettes. We investigated the physical properties of charcoal added paper according to the ratio of pulps, the amounts of characoal , the weight of sheets and crimping conditions in dry method, and then analyzed the smoke contents of cigarettes. The results obtained were as follows. 1. Sw-BKP was higher than Hw-BKP in methylene blue absorption by UV test. 2. Charcoal had an effect on stiffness for decreasing factor greatly , while the addition amounts of Sw-BKP and high weigth of sheets increased it, and the interaction of weight of sheets and charcoal was higher than other factors. 3. Tear index decreased by charcoal addition greatly, on the other hand high weight of sheets and Sw-BKP/Hw-BKP ratio increased ter, and the interaction of pulps and chacoal acted on major factors. 4. We estimated crimp index with sensory evaluation , and charcoal hand an effect on decreasing factor in crimping greatly, while the interaction of weight of sheets and pulp ratio was higher than others. 5. In the case of charcoal added paper filter, tar removal efficiency of smoke contents was higher but about 6% than cigarette filter. Especially vapour phase(aldehyde) in smoke contents was removed greatly.

• 한국공간구조학회논문집
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• 제10권2호
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• pp.127-134
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• 2010

막 구조는 자유로운 형태, 경량성, 내구성, 햇빛 투광성 및 균질성 때문에 전 세계적으로 현대 건축물에 다양하게 사용되어 왔다. 새로운 막 재료의 개발로 새로운 건축 구조설계에 대한 가능성을 열어가고 있다. 최근 주로 사용되는 막 구조의 지붕 재료에는 PVC, PVF, PVDF, PTFE 코팅 막재 및 ETFE 막재가 수로 사용되고 있다. 건축용 막은 내화성, 강도 부족, 인열강도, 내구성 및 탄성 등에 대한 몇가지 문제점들을 가지고 있다. 이러한 문제점들을 평가하기 위해서 본 연구에서는 PVDF 코팅 폴리에스터 막재에 대한 인장강도, 인열 강도 및 반복하중거동 시험을 실시하여 건축용 막재의 기초적인 역학적 특성을 분석하고자 한다. 막재의 탄성계수는 337.30~1257.63N/$mm^2$, 신율은 17.90~26.91%로 주어졌다.

• 펄프종이기술
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• 제33권4호
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• pp.15-20
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• 2001

The function of the moisture-proof paper is to prevent moisture from adsorbing into the packed goods. Water-vapor transmission rate of the moisture-proof paper should be less than 100g/$m^2$.24hr and the optimum rate would be less than 50g/$m^2$.24hr. In general the moisture-proof paper has been made by laminating polyethylene or polypropylene on top of the base paper. However this kind of moisture-proof paper has a problem in recycling so that it brings about environmental pollution. In general the moisture-proof paper has been made by laminating polyethylene or polypropylene on top of the base paper. However this kind of moisture-proof paper has a problem in recycling so that it brings about environmental pollution. The purpose of this paper was to make moisture-proof paper using the mixture of SB latex and wax emulsion which was recyclable and environmentally friendly. Water vapor transmission rate showed less than 50g/$m^2$.24hr in mixture ratio of 85:15, 87:13, 90:10. Especially the mixture ratio of 87:13 showed the most favorable water-vapor transmission rate. However, the moisture-proof layer was destroyed slightly by folding in packing. It has been observed that there was no close relationship between water-vapor transmission rate of the moisture-proof paper and grammage of the base paper, but the density of base paper had influenced on water vapor transmission rate. It was also observed that the moisture-proof paper could be recycled. The moisture-proof paper was similar to base paper in degree of the pulping, and there was no significant difference in dispersion between moisture-proof paper and base paper. Most of wax particles which caused the spots during drying process could be removed by flotation process. Tensile strength and tear strength of both moisture-proof paper and base paper after pulping were measured to examine the fiber bonding, and no significant difference in physical properties was observed.

• 한국의류산업학회지
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• 제15권3호
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• pp.452-460
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• 2013

This study conducted a performance evaluation of protective clothing materials used for welding in a hazardous shipbuilding industry work environment. The welding process was selected as the one that most requires industrial protective clothing according to work environment characteristics. Flame proofing and convection heat protection performance (HTI) in the heat transfer characteristics of protective clothing material were indicated in the order of SW1(Oxidant carbon)>SW2(silica coated Oxidant carbon)>SW4(Oxidant carbon/p-aramid)>SW3(flame proofing cotton). However, radiant heat protection performance (RHTI) and the heat transfer factor (TF) were indicated in the order of SW1>SW4>SW2>SW3 and showed different patterns from the convection heat protection performance. SW1 showed superior air permeability and water vapor permeability. The tensile strength and tear strength of welding protective clothing material were indicated in the order of SW4>SW2>SW3>SW1 and showed that a blend fabric of p-aramid was the most superior for the mechanical properties of SW4. SW1 had excellent heat transfer properties in yet met the minimum performance requirements of tensile strength proved to be inappropriate as being a material for welding protective clothing. The abrasion resistance of woven fabric proved superior compared to nonwoven fabric; however, seam strength and dimensional change both met the minimum performance requirements and indicated that all samples appeared non-hazardous. Finally, oxidant carbon/p-aramid blend fabric appeared appropriate as a protective clothing materials for welding.

• Elastomers and Composites
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• 제37권2호
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• pp.86-98
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• 2002

본 연구에서는 실리카/카본블랙 혼합사용과 카본블랙 단독 사용의 경우 상온 또는 고온에서의 인장강도(modulus) 및 인열저항성, 내cutting성, 내crack성을 비교 평가하였다. 실리카와 카본블랙의 함량비 및 단계배합 방법을 통해 NR 가황물을 제조하였으며, 충전제의 함량은 60phr로 고정하였고, semi-EV 가황시스템을 적용하여 실험을 실시하였다. 실리카의 분산은 25phr이하일 때 양호하였으며, 실리카/카본블랙의 함량비가 25/35인 경우 인열에너지, 내crack특성, 내cutting특성이 가장 우수하였다. 충전제로써 카본블랙 단독사용과 실리카/카본블랙(25/35) 혼합사용의 경우를 비교해 보면, 열화에 따른 modulus 및 인장강도, 인열에너지는 실리카/카본블랙(25/35)을 사용한 시편이 더 낮은 감소율을 나타내었다. Cutting특성에서는 카본블랙 단독 사용보다는 실리카/카본블랙(25/35) 혼합사용의 경우가 더 높은 cutting 저항성을 나타내었다. 내crack 특성 또한 실리카/카본블랙(25/35)을 혼합사용한 경우가 온도에 따른 더 높은 변형에너지 완화율(Gp)에도 불구하고 더 낮은 크랙성장속도를 나타내었다.

• 한국염색가공학회지
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• 제32권3호
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• pp.176-183
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• 2020

In order to study wearable air cushion materials capable of responding to massive impact in high-altitude fall situation, high tenacity woven fabrics were bonded by heat only depending on various type of thermoplastic films and then mechanical properties were measured. Tensile strength, elongation, and 100% modulus measurement results for 4 types of films show that TPU-2 has higher impact resistance and easier expansion than PET-1. After thermal bonding, the combination with the highest tensile strength was a material with a TPU-2 film for nylon and a PET-2 film for PET, so there was a difference by type of fabric. The tear strength of the bonded materials were increased compared to the fabric alone, which shows that durability against damage such as tearing can be obtained through film adhesion. All of the peel strengths exceeded the values required by automobile airbags by about 5 times, and the TPU-2 bonded fabric showed the highest value. The air permeability was 0 L/dm2 /min. For both the film and the bonded material, which means tightness between the fabric and the film through thermal bonding. It is expected to be applied as a wearable air cushion material by achieving a level of mechanical properties similar to or superior to that of automobile airbags through the method of bonding film and fabric by thermal bonding.

• 펄프종이기술
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• 제29권3호
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• pp.34-42
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• 1997

This study was carried out to investigate the proper cooking conditions of soda-anthraquinone and alkaline sulfite-anthraquinone pulping of rice-straw, and get basic data f9r the use of rice-straw chemical pulp through the test of characteristics and physical properties of pulps made in the various cooking conditions From the experimental results , we can conclude as follows. In the soda-anthraquinone pulping of rice-straw, the optimum cooking conditions were 60 min. at $150^{\circ}C$ in the amount of caustic soda of 20% with the addition of anthraquinone(0.05%). And total yield, Kappa No. and brightness of pulp made in the condition above mentioned were 41.9%, 7.7 and 51.1 respectively. In the alkaline sulfite-anthraquinone pulping of rice-straw, the proper mixing ratio of cooking chemical(caustic soda : sodium sulfite) was 50:50. And the optimum cooking conditions were 60 min. at $150^{\circ}C$ in the amount of cooking chemical of 20% with the addition of anthraquinone(0.05%). At that time, the total yield, Kappa No, and brightness of pulp were 50.1%, 9.1 and 40.2 respectively. As a result, the alkaline sulfite-anthraquinone pulping was superior to the soda-anthraquinone pulping in the aspect of yield, but inferior in the viewpoints of Kappa No. and brightness. For the comparison of qualities of pulps made in the various cooking methods and conditions, the physical properties of four sorts of pulps were tested. As a result, soda-anthraquinone pulps were superior to alkaline sulfite-anthraquinone pulps in the various strengths excluding tear strength and brightness. On the other hand, pulps made in the condition of addition of cooking chemical of 20% were superior to pulps in the dosage of 15% in the aspects of all the strengths and brightness.

• 펄프종이기술
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• 제44권4호
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• pp.51-61
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• 2012

The new alkali pulping process combined with electron beam treatment was applied to utilize hemp bast tissues as a new valuable fibrous resource. Hemp bast tissues have some chemical properties with high lignin contents and holocellulose not to be defiberized by alkali pulping only, compared with the bast tissue of paper mulberry. To make up for the weakness of traditional alkali pulping process, electron beams were directly irradiated into the swelled bast tissue of hemp in NaOH solution and distilled water, and then facilitated the defiberization of hemp bast tissues. The papermaking from hemp bast fibers manufactured by the combination pulping process showed good apparent density, formation structure and air permeability, and had some mechanical properties with lower tensile, tear, burst strength and folding endurance. It is finally concluded that the combination pulping process with electron beam treatment could be suggested a new alternative for non-woody fibers.