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Structural Changes in Isothermal Crystallization Processes of Synthetic Polymers Studied by Time-Resolved Measurements of Synchrotron-Sourced X-Ray Scatterings and Vibrational Spectra

  • Tashiro, Kohji;Hama, Hisakatsu
    • Macromolecular Research
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    • v.12 no.1
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    • pp.1-10
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    • 2004
  • The structural changes occurring in the isothermal crystallization processes of polyethylene (PE), poly-oxymethylene (POM), and vinylidene fluoridetrifluoroethylene (VDFTrFE) copolymer have been reviewed on the basis of our recent experimental data collected by the time-resolved measurements of synchrotron-sourced wide-angle (WAXS) and small-angle X-ray scatterings (SAXS) and infrared spectra. The temperature jump from the melt to a crystallization temperature could be measured at a cooling rate of 600-1,000 $^{\circ}C$/min, during which we collected the WAXS, SAXS, and infrared spectral data successfully at time intervals of ca. 10 sec. In the case of PE, the infrared spectral data clarified the generation of chain segments of partially disordered trans conformations immediately after the jump. These segments then became transformed into more-regular all-trans-zigzag forms, followed by the formation of an orthorhombic crystal lattice. At this stage, the generation of a stacked lamella structure having an 800-${\AA}$-long period was detected in the SAXS data. This structure was found to transfer successively to a more densely packed lamella structure having a 400-${\AA}$-long period as a result of the secondary crystallization of the amorphous region in-between the original lamellae. As for POM, the formation process of a stacked lamella structure was essentially the same as that mentioned above for PE, as evidenced from the analysis of SAXS and WAXS data. The observation of morphology-sensitive infrared bands revealed the evolution of fully extended helical chains after the generation of lamella having folded chain structures. We speculate that these extended chains exist as taut tie chains passing continuously through the neighboring lamellae. In the isothermal crystallization of VDFTrFE copolymer from the melt, a paraelectric high-temperature phase was detected at first and then it transferred into the ferroelectric low-temperature phase at a later stage. By analyzing the reflection profile of the WAXS data, the structural ordering in the high-temperature phase and the ferroelectric phase transition to the low-temperature phase of the multi-domain structure were traced successfully.

Estimation of Dynamic Motions and Mooring Forces for Floating Type Offshore Platform Based on Hydrodynamic Analysis (동수력학 해석 기반 부유식 해양 플랫폼의 동적 운동 및 계류력 산정)

  • Cha, Ju-Hwan;Moon, Chang-Il;Song, Chang-Yong
    • Journal of Ocean Engineering and Technology
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    • v.26 no.2
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    • pp.48-57
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    • 2012
  • This paper deals with numerical analyses in the context of estimations of hydrodynamic motions and dynamic loads for a floating type offshore platform using some exclusive simulation code such as code for the simulation of a floating type of offshore crane based on multi-body dynamics, along with the commercial code AQWA. Verifications of numerical models are carried out by comparing the RAO results from the simulation code. In the verification analyses, hydrodynamic motions are examined in the frequency domain for the floating type offshore platform according to the mooring lines. Both the hydrodynamic motions and dynamic loads are estimated for floating type offshore platforms equipped with the catenary type and taut mooring lines. A review and comparison are carried out for the numerically estimated results. The structural safety of the connection parts in an offshore structure such as a floating type offshore platform is one of the most important design criteria in view of fatigue life. The dynamic loads in the connecting area between a floating type offshore platform and its mooring lines are estimated in detail according to variations in the mechanical properties of the mooring lines. The dynamic tension load on the mooring lines is also estimated.

Is Extracorporeal Shock Wave Therapy Effective in the Treatment of Myofascial Pain Syndrome?

  • Kim, Jong-Ick;Lee, Hyo-Jin;Park, Hyung-Youl;Lee, Won-Hee;Kim, Yang-Soo
    • Clinics in Shoulder and Elbow
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    • v.19 no.1
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    • pp.20-24
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    • 2016
  • Background: Extracorporeal shock wave therapy (ESWT) is one of the treatment options used for patients with myofascial pain syndrome (MPS), although its effectiveness is controversial. The purpose of this study was to evaluate the effectiveness of ESWT in the treatment of MPS in terms of pain relief and functional improvements. Methods: We assessed 93 patients with MPS who underwent ESWT from March 2009 to July 2014. After exclusion of 25 patients with shoulder diseases, 68 patients were enrolled in the study. The mean follow-up period was 7.5 months (${\pm}4.2weeks$), and the average duration of symptoms was 5 months (range, 2-16 months). ESWT was applied to intramuscular taut bands and referred pain areas once a week for 3 weeks. Visual analog scale (VAS) pain scores and American Shoulder and Elbow Surgeons (ASES) scores were obtained at an initial assessment and at the 6-week, 3-month, and 6-month follow-up assessments. Results: VAS pain scores and ASES scores improved significantly after 3 sessions of ESWT (p<0.05). Both scores were improved, although not significantly, after 6 weeks (p>0.05). Conclusions: ESWT is an effective treatment option for patients with MPS.

A Study on the Dynamic Analysis of Mooring System During Hook-up Installation

  • Lee, Min Jun;Jo, Hyo Jae;Lee, Sung Wook;Hwang, Jea Hyuk;Kim, Jea Heui;Kim, Young Kyu;Baek, Dong Il
    • Journal of Ocean Engineering and Technology
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    • v.34 no.5
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    • pp.285-293
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    • 2020
  • This study evaluated the Hook-up installation of an offshore site construction process, which is the final step in an offshore site installation process. During Hook-up installation, the offshore structure can have a detrimental effect on the work stability due to low-frequency motion. Moreover, economic costs can be incurred by the increase in available days of a tugboat. Therefore, this study developed a numerical analysis program to assess the dynamic behavior of mooring systems during hook-up installation to analyze the generally performed installation process and determine when the tugboat should be released. In this program, the behavior of an offshore structure was calculated using Cummin's time-domain motion equation, and the mooring system was calculated by Lumped mass method (LMM). In addition, a tugboat algorithm for hook-up installation was developed to apply the Hook-up procedure. The model used in the calculations was the barge type assuming FPSO (Floating production storage and off-loading) and has a taut mooring system connected to 16 mooring lines. The results of the simulation were verified by comparing with both MOSES, which is a commercial program, and a calculation method for restoring coefficient matrix, which was introduced by Patel and Lynch (1982). Finally, the offset of the structure according to the number of tugboats was calculated using the hook-up simulation, and the significant value was used to represent the calculation result.

Vibration control of a stay cable with a rotary electromagnetic inertial mass damper

  • Wang, Zhi Hao;Xu, Yan Wei;Gao, Hui;Chen, Zheng Qing;Xu, Kai;Zhao, Shun Bo
    • Smart Structures and Systems
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    • v.23 no.6
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    • pp.627-639
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    • 2019
  • Passive control may not provide enough damping for a stay cable since the control devices are often restricted to a low location level. In order to enhance control performance of conventional passive dampers, a new type of damper integrated with a rotary electromagnetic damper providing variable damping force and a flywheel serving as an inertial mass, called the rotary electromagnetic inertial mass damper (REIMD), is presented for suppressing the cable vibrations in this paper. The mechanical model of the REIMD is theoretically derived according to generation mechanisms of the damping force and the inertial force, and further validated by performance tests. General dynamic characteristics of an idealized taut cable with a REIMD installed close to the cable end are theoretically investigated, and parametric analysis are then conducted to investigate the effects of inertial mass and damping coefficient on vibration control performance. Finally, vibration control tests on a scaled cable model with a REIMD are performed to further verify mitigation performance through the first two modal additional damping ratios of the cable. Both the theoretical and experimental results show that control performance of the cable with the REIMD are much better than those of conventional passive viscous dampers, which mainly attributes to the increment of the damper displacement due to the inertial mass induced negative stiffness effects of the REIMD. Moreover, it is concluded that both inertial mass and damping coefficient of an optimum REIMD will decrease with the increase of the mode order of the cable, and oversize inertial mass may lead to negative effect on the control performance.

Movable Anchorage System for Mitigation of Cable Vibration in Cable-Stayed Bridges with Sag (Sag가 고려된 사장교 케이블의 진동저감을 위한 Movable Anchorage 시스템)

  • Hwang, Inho;Park, Jun Hyung;Lee, Jong Seh
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.5A
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    • pp.657-664
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    • 2008
  • Rain-wind induced cable vibration can cause the damages in the cable-stayed bridge due to very little inherent damping characteristics and low fundamental frequency. External Dampers attached to stay cables near anchorages have been shown to be effective means at short stay-cables. However, installation locations of external dampers are limited to a particular range due to aesthetic and practical reasons for very long stay-cables. A recent study by the authors showed that the stay-cable vibration system can perform better than the optimal passive viscous damper, thereby demonstrating its applicability in large cable-stayed bridges. This paper extends the previous study on the taut string representation of the cable by adding cable sag and inclination. The response of the proposed system compared to those of the cable with and without an external damper, and the movable anchorage system provides very effective mitigation of cable vibration. Cable damping ratio is seen to be remarkably reduced by movable anchorage system for a wide range of cable sag. This result shows that the sag effects of the proposed system should be considered.

Passive Control System for Mitigation of Cable Vibration in Cable-Stayed Bridges (사장교의 케이블 진동저감을 위한 수동 제어시스템)

  • Hwang, Inho;Lee, Jong Seh
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.5A
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    • pp.881-885
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    • 2006
  • Rain-wind induced cable vibration can cause serious problems in cable-stayed bridges. Externally attached dampers have been used to provide an effective means to suppress the vibration of relatively short stay-cables. For very long stay-cables, however, such damper systems are rendered ineffective, as the dampers need to be attached near the end of cables for aesthetic reasons. This paper investigates a new control system to mitigate the cable vibration. The proposed control system which consists of a laminated rubber bearing and an internal damper may be installed inside of the cable anchorage. A simple analytical model of the cable-damper system is developed first based on the taut string representation of the cable. The response of a cable with the proposed control system is obtained and then compared to those of the cable with and without an external passive damper. The proposed stay-cable vibration control system is shown to perform better than the optimal passive viscous damper, thereby demonstrating its applicability in large cable-stayed bridges for mitigation of rain-wind induced vibration of stay-cables.

Mooring chain fatigue analysis of a deep draft semi-submersible platform in central Gulf of Mexico

  • Jun Zou
    • Ocean Systems Engineering
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    • v.14 no.2
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    • pp.171-210
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    • 2024
  • This paper focuses on the rigorous and holistic fatigue analysis of mooring chains for a deep draft semi-submersible platform in the challenging environment of the central Gulf of Mexico (GoM). Known for severe hurricanes and strong loop/eddy currents, this region significantly impacts offshore structures and their mooring systems, necessitating robust designs capable of withstanding extreme wind, wave and current conditions. Wave scatter and current bin diagrams are utilized to assess the probabilistic distribution of waves and currents, crucial for calculating mooring chain fatigue. The study evaluates the effects of Vortex Induced Motion (VIM), Out-of-Plane-Bending (OPB), and In-Plane-Bending (IPB) on mooring fatigue, alongside extreme single events such as 100-year hurricanes and loop/eddy currents including ramp-up and ramp-down phases, to ensure resilient mooring design. A detailed case study of a deep draft semi-submersible platform with 16 semi-taut moorings in 2,500 meters of water depth in the central GoM provides insights into the relative contributions of wave scatter diagram, VIMs from current bin diagram, the combined stresses of OPB/IPB/TT and extreme single events. By comparing these factors, the study aims to enhance understanding and optimize mooring system design for safety, reliability, and cost-effectiveness in offshore operations within the central GoM. The paper addresses a research gap by proposing a holistic approach that integrates findings from various contributions to advance current practices in mooring design. It presents a comprehensive framework for fatigue analysis and design optimization of mooring systems in the central GoM, emphasizing the critical importance of considering environmental conditions, OPB/IPB moments, and extreme single events to ensure the safety and reliability of mooring systems for offshore platforms.

Nonlinear Dynamic Analysis on Low-Tension Towed Cable by Finite Difference Method (유한차분법을 이용한 저장력 예인케이블의 비선형 동적해석)

  • Han-Il Park;Dong-Ho Jung
    • Journal of the Society of Naval Architects of Korea
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    • v.39 no.1
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    • pp.28-37
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    • 2002
  • In this study nonlinear dynamic behaviors of towed tow-tension cables are numerically analysed. In the case of a taut cable analysis, a bending stiffness term is usually neglected due to its minor effect but it plays an important role in a low-tension cable analysis. A low-tension cable may experience large displacements due to relatively small restoring forces and thus the effects of fluid and geometric non-linearities become predominant. The bending stiffness and non-linearity effects are considered in this work. In order to obtain dynamic behaviors of a towed low-tension cable, three-dimensional nonlinear dynamic equation is described and discretized by employing a finite difference method. An implicit method and Newton-Raphson iteration are adopted for the time integration and nonlinear solutions. For the calculation of huge size of matrices. block tri-diagonal matrix method is applied, which is much faster than the well-known Gauss-Jordan method in two point boundary value problems. Some case studies are carried out and the results of numerical simulations are compared with those of a in-house program of WHOI Cable with good agreements.

A clinical report of a patient with Tourett's disorder (뚜렛 장애(Tourett's disorder) 환자(患者) 1례(例)에 대한 증례보고(症例報告))

  • Sung, Woo-Yong;Lee, Seung-Hyun;Son, Ji-Hyung;Han, Seung-Hea;Jung, Hyo-Chang
    • Journal of Oriental Neuropsychiatry
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    • v.14 no.2
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    • pp.213-218
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    • 2003
  • This is a case report of a patient with Tourett's disorder treated by Ukgan-san. We evaluated the patient Tourett's disorder by behavior and sound. His tic behaviors like eye blinking, shoulder shrugging, head jerking, facial frimace have been shown frequently, and His phonic tic symptoms like coughing, throat clearing, sniffing have been presented frequently, too. We diagnosed his condition as Wind-syndrome Caused by Hyperactivity of Liver-yang by patient's redish face, taut pulse, Left umbilical throb. So we treated the patient with Ukgan-san. and the score of Yale Global Tic Severity Scale(YGTSS) was 30 at the start of treatment. and the score of YGTSS was 3 at the end. We found that Ukgan-san was effective for the patient with Tourett's disorder.

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