• Title/Summary/Keyword: tack strength

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Effect of Isocyanate Index on the Properties of Rigid Polyurethane Foams Blown by HFC 365mfc

  • Kim, Sung-Hee;Kim, Byung-Kyu;Lim, Ho
    • Macromolecular Research
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    • v.16 no.5
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    • pp.467-472
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    • 2008
  • Rigid polyurethane foams (RPUFs) were fabricated from crude MDI (CMDI) and polypropylene glycols (PPGs) of various isocyanate indices with a physical blowing agent (HFC 365mfc). There was a tendency for the gel time to decrease and the tack-free time to increase with increasing index value. With increasing index value the foam density and compression strength decreased and the glass transition temperature, dimension stability and thermal insulation increased, while the cell size and closed cell content were virtually unchanged. Allophanate crosslinks and condensation reactions between the isocyanate groups, which are favored with a high index value, exerted significant effects on the properties of RPUFs.

Preparation and Properties of the Fast-Curing γ-Ray-Shielding Materials Based on Polyurethane

  • Ni, Minxuan;Tang, Xiaobin;Chai, Hao;Zhang, Yun;Chen, Tuo;Chen, Da
    • Nuclear Engineering and Technology
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    • v.48 no.6
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    • pp.1396-1403
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    • 2016
  • In this study, fast-curing shielding materials were prepared with a two-component polyurethane matrix and a filler material of PbO through a one-step, laboratory-scale method. With an increase in the filler content, viscosity increased. However, the two components showed a small difference. Curing time decreased as the filler content increased. The minimum tack-free time of 27 s was obtained at a filler content of 70 wt%. Tensile strength and compressive strength initially increased and then decreased as the filler content increased. Even when the filler content reached 60 wt%, mechanical properties were still greater than those of the matrix. Cohesional strength decreased as the filler content increased. However, cohesional strength was still greater than 100 kPa at a filler content of 60 wt%. The ${\gamma}$-ray-shielding properties increased with the increase in the filler content, and composite thickness could be increased to improve the shielding performance when the energy of ${\gamma}$-rays was high. When the filler content was 60 wt%, the composite showed excellent comprehensive properties.

Autohesion Behavior of Brominated-Isobutylene-Isoprene Gum Nanocomposites with Layered Clay (층상점토 충전 브롬화 이소부틸-이소프렌 검 나노복합체의 점착거동)

  • Mensah, Bismark;Kim, Sungjin;Lee, Dae Hak;Kim, Han Gil;Oh, Jong Gab;Nah, Changwoon
    • Elastomers and Composites
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    • v.49 no.1
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    • pp.43-52
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    • 2014
  • The effect of nanoclay (Cloisite 20A) on the self-adhesion behavior of uncured brominated-isobutylene-isoprene rubber (BIIR) has been studied. The dispersion state of nanoclay into the rubber matrix was examined by SEM, TEM and XRD analysis. The thermal degradation behavior of the filled and unfilled samples was examined by TGA and improvement in the thermal stability of the nanocomposites occurred based on the weight loss (%) measurements. Also, addition of nanoclay enhanced the cohesive strength of the material by reinforcement action thereby reducing the degree of molecular diffusion across the interface of butyl rubber. However, the average depth of penetration of the inter-diffused chains was still adequate to form entanglement on either side of the interface, and thus offered greater resistance to peeling, resulting in high tack strength measurements. The improvement in tack strength was only achieved at critical nanoclay loading above 8 phr. Contact angle measurement was also made to examine the surface characteristics. There was no significant interfacial property change by employing the nanoclay.

The morphology and mechanical properties of the blends of syndiotactic polystyrene and polystyrene-block-poly(ethylene-co-butylene)-block-polystyrene copolymers

  • O, Hyun-Tack;Kim, Hwang-Ryong;Kim, Jin-Kon;Park, Joon-Young
    • Korea-Australia Rheology Journal
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    • v.13 no.2
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    • pp.83-87
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    • 2001
  • The morphology and mechanical properties of the blends of a syndiotactic polystyrene (SPS) and poly-styrene-block-poly(ethylene-co-butylene)-block-polystyrene copolymers (SEBS) with various polystyrene block contents are studied. Mechanical properties, especially elongation at break and impact strength (IS), of the blend depend upon the morphology and interfacial adhesion, which in rum are affected by the viscosity ratio of constituent components and the styrene block content in SEBS. The IS of a blend was affected by the combined effect of rubber content and the interfacial adhesion. A maximum IS was found for a blend with the weight fraction of the PS block in an SEBS of 0.18. The IS of blends with smaller weight fractions of the PS block exhibited lower due to poor interfacial adhesion between SPS/SEBS in spite of a larger amount of rubber block. On the other hand, the IS of blends with larger weight fraction of the PS block becomes smaller due to lower amounts of rubber block in spite of better interfacial adhesion.

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THE EFFECTS OF HEAT TREATMENT ON THE MECHANICAL PROPERTIES OF THE ELGILOY WIRE (열처리가 Elgiloy 선재의 기계적 성질에 미치는 영향)

  • Hur, Tack;Rhee, Byung-Tae;Choi, Seok Kyu;Kim, Hyung-Il
    • The korean journal of orthodontics
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    • v.22 no.3 s.38
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    • pp.557-578
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    • 1992
  • Heat treatment which removes internal stress enhances the mechanical properties of the orthodontic arch wire. The main purpose of this experiment was to investigate the effects of the heat treatment on the mechanical properties of the Elgiloy wire. The Elfiloy wire, 0.016' X 0.022' and 0.018' X 0.025', were heat treated in an electric oven for 5, 10 and 15 minutes at selected temperatures between 300 and $900^{\circ}C$. Tensile strength and load deflection rate were measured to reveal the changes of mechanical property at various conditions, and each specimen was observed under metallurgic microscope. Also to trace the precipitation material due to overheat treatment, a qualitative analysis was carried out with EDS system. It was found that heat treatment at a low temperature caused an increase in the tensile strength and bending resistance, and a maintenance in the fibrous in the tensile strength and bending resistance, and a maintenance in the fibrous structure of both sizes of wire. The changes observed in properties and appearance were probably due to the relief of internal stresses incurred in the metal during cold working. In both sizes of wire the tensile strength and the bending resistance continued to decrease at high temperature, and the fibrous structure continued to disappear then was not observed at $900^{\circ}C$. The carbide precipitation founded in grain boundary at $750^{\circ}C$ probably was other elements carbide (Ni, Co) except Cr. The grain growth was observed at $1100^{\circ}C$. Optimum heat treatment for the 0.016' X 0.022' Elgiloy wire was 10 minutes at $500^{\circ}C$, and for the 0.018' X 0.025' Elgiloy wire it was 5 to 15 minutes at $500^{\circ}C$.

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Effects of Intra-particle Composition on the Adhesive Properties and Water Dispersity of Water Dispersible Acrylic Emulsion Pressure Sensitive Adhesive (입자 내 조성 변화가 수분산성 아크릴 에멀젼 점착제의 점착 물성과 수분산성에 미치는 영향)

  • Seo, In Seon;Lee, Myung Cheon
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.444-448
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    • 2007
  • The effects of intra-particle composition on the adhesive properties and water dispersity of acrylic emulsion type pressure sensitive adhesives (PSAs) were investigated. In the case of PSA having uniform intra-particle composition, the higher holding strength made the water dispersity lower. By changing the intra-particle composition in hard core/soft shell type, however, it was possible to get PSAs showing both high holding strength and water dispersity. When the weight ratio of MAA/AA is 4/1, high holding strength, but low initial tack and very low water dispersity were observed in both cases of higher contents of (AA+MAA) in core and shell area. When the weight ratio of MAA/AA is 1/4, however, higher water dispersity and lower holding strength were indicated in the case of higher contents of (AA+MAA) in shell area.

A Nonlinear Material Model for Concrete Compression Strength Considering Confining Effect (30-40Mpa의 압축강도를 갖는 콘크리트의 구속효과를 고려한 비선형 재료모델의 적용성 검토)

  • Lee, Heon-Min;Park, Jae-Guen;Hwang, Jae-Min;Yun, Hee-Tack;Shin, Hyun-Mock
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2009.04a
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    • pp.379-382
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    • 2009
  • 횡방향으로 구속된 콘크리트의 응력-변형률 거동은 구속되지 않은 콘크리트와는 다른 거동을 한다. 보통강도 콘크리트에서 구속효과를 고려한 콘크리트 재료모델로는 Mander 모델이 대표적이며 고강도 콘크리트의 구속효과의 경우 여러 연구자들에 의하여 제안된 모델 중 공시체 수준의 실험결과와 잘 일치하는 Sakino-Sun 모델을 사용하였다. 보통강도에서는 Mander모델을 고강도 콘크리트에서는 Sakino-Sun 모델을 사용하였으나 중간 강도인 30-40MPa의 강도에서 Mander 모델과 Sakino-Sun 모델의 적용시 실험결과와 해석결과가 다소 차이를 보이며 또한 두 모델은 적용할 수 있는 최대 또는 최소 콘크리트 압축강도의 한계범위가 명확하지 않다. 따라서 이 연구에서는 30-40MPa의 강도의 횡방향으로 구속된 콘크리트의 비선형 재료모델을 제안하고 실제 30-40MPa의 압축강도를 갖는 콘크리트 공시체의 일축압축시험 결과와의 비교를 통해 그 적용성을 검토하였다.

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Non-Destructive Evaluation of Semiconductor Package by Electronic Speckle Pattern Interferometry

  • Kim, Koung-Suk;Kang, Ki-Soo;Jung, Seung-Tack
    • Journal of Mechanical Science and Technology
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    • v.19 no.3
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    • pp.820-825
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    • 2005
  • This paper proposes non-destructive ESPI technique to evaluate inside defects of semiconductor package quantitatively. Inspection system consists of ESPI system, thermal loading system and adiabatic chamber. The technique has high feasibility in non-destructive testing of semiconductor and gives solutions to the drawbacks in previous technique, time-consuming and the difficulty of quantitative evaluation. In result, most of defects are classified in delamination, from which it is inferred to the insufficiency of adhesive strength between layers and nonhomogeneous heat spread. The $90\%$ of tested samples have a delamination defect started at the around of the chip which may be related to heat spread design.

Electro-optical and Viscoelastic Properties of Liquid Crystal-Polymer Composite Films (액정-고분자 복합막의 전기광학 특성과 동적 점탄성)

  • 남수용
    • Journal of the Korean Graphic Arts Communication Society
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    • v.14 no.2
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    • pp.101-113
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    • 1996
  • In general, printing inks are mainly composed of pigments and vehicles. Its characteristics are affected, to a greater or lesser extent, by the size and distribution of the pigment particles in the dispersion. Color strength, transparency and gloss generally increases with an decrease in particle size of pigments. On the contrary, opacity, lightfastness tend to increases with an increase in particle size of pigments In this work, we have investigated an effect of surface area of pigments on the physical properties of printing of printing ink which made up vehicles for sheet fed and organic pigment Lake Red C(C.I.Pigment Red 53:1) that different surface area and particle size. It was found that gloss, tack and yield value increases with an increase in surface are of pigments, but grindness is reduced.

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Physiological Review of Weakness in Patients with Hemiparesis (편부전마비 환자에서의 근육약화에 대한 생리학적 고찰)

  • Kim, Jong-Man;Kim, Tack-Hoon
    • Physical Therapy Korea
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    • v.3 no.2
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    • pp.84-94
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    • 1996
  • This paper reviews physiological changes in the nervous system of patients with hemiparesis that may contribute to muscle weakness. The discussion includes the important role that alterations in the physiology of motor units, notably changes in firing rates and muscle fiber atrophy, play in the manifestation of muscle weakeness. This role is compared with the lesser role that spasticity of the antagonist muscle group appears to play in determining the weakness of agonist muscles. The contribution of other factors that result in mechanical restraint of the agonist by the antagonist is discussed relative to muscle weakness in patients with hemiparesis. More studies on patients with hemiparesis are required to assess what role muscle strength training should play in rehabiliting patients after a stroke.

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