• Bulletin of the Korean Chemical Society
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• v.14 no.1
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• pp.91-95
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• 1993

In this work we have studied the spin-lattice relaxation of $^{19}$F spins in benzotrifluoride in our quest for a reliable method of discriminating the contribution due to dipolar relaxation mechanism from that due to spin-rotational mechanism for nuclear spins located on methyl or substituted methyl group in organic molecules. Over the temperature range of 248-268 K the decay of normalized longitudinal magnetization was found to be well described by a two parameter equation of the form R(t) = exp(-st){$\frac{5}{6}$exp(-s$_1$)+$\frac{1}{6}$} which was derived under the assumption that interactions in the A3 spin system are modulated randomly and predominantly by internal rotational motions of -CF_3$ top, and it was shown that the separation of contribution due to dipolar interactions from that due to spin-rotation interaction could be successfully achieved by least-square fitting of observed data to this equation. The results indicate that the spin-rotational contribution is overwhelmingly larger than that of dipolar origin over the given temperature range and becomes more deminating at higher temperature.

• Wind and Structures
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• v.16 no.2
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• pp.157-178
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• 2013

Output-only modal parameter identification is based on the assumption that external forces on a linear structure are white noise. However, harmonic excitations are also often present in real structural vibrations. In particular, it has been realized that the use of forced acceleration responses without knowledge of external forces can pose a problem in the modal parameter identification, because an external force is imparted to its impulse acceleration response function. This paper provides a three-stage identification procedure as a solution to the problem of harmonic and white noise excitations in the acceleration responses of a linear dynamic system. This procedure combines the uses of the mode indicator function, the complex mode indication function, the enhanced frequency response function, an iterative rational fraction polynomial method and mode shape inspection for the correlation-related functions of the force-embedded acceleration responses. The procedure is verified via numerical simulation of a five-floor shear building and a two-dimensional frame and also applied to ambient vibration data of a large-span roof structure. Results show that the modal parameters of these dynamic systems can be satisfactorily identified under the requirement of wide separation between vibration modes and harmonic excitations.

• Nuclear Engineering and Technology
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• v.7 no.2
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• pp.127-133
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• 1975

For isotopic exchange labelling of 3,5,3'-triiodothyronine (T$_3$) and thyroxine (T$_4$) with radioiodide in the presence of molecular iodine, T$_3$:I$_2$ or T$_4$:I$_2$ molar ratios, pH, and reaction time are. considered to be important factors. A modified labelling and separation method is proposed in present paper, by which T$_3$-$^{125}$ I and T$_4$-$^{125}$ I can be obtained with the mean labelling yields of 45%, and 50%, respectively. The whole reaction products can be separated by adoption of thin-layer chromatography technique using silica gel plate and the solvent system composd of chloroform, methanol and ammonia.

• Archives of Pharmacal Research
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• v.26 no.9
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• pp.763-767
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• 2003

The differences in pharmacokinetic behavior and tissue distribution of verapamil and its enantiomers were investigated in rats. In high-performance liquid chromatographic method, an achiral ODS column (150 mm $\times$ 4.6 mm i.d.) with the mobile phase consisting of methanol-water (73:30, v/v) was used for the determination of the concentration for racemic verapamil, and a Chiralcel OJ column (250 mm$\times$4.6 mm i.d.) with the mixture of n-haxane-ethanol-triethylamine (85:15:0.2, v/v/v) as mobile phase was used to determine the concentrations of verapamil enantiomers. A fluorescence detector in the analytical system was set at excitation and emission wavelengths of 275 nm and 315 nm. The differences between enantiomers were apparent in the pharmacokinetics in rats. The area under the concentration-time curve (AUC) of S-(-) verapamil was higher than that of R-(+) verapamil. The half-distribution time ($T_{1/2(\alpha)}$) of S-(-) verapamil which distributing to tissue from blood was shorter than that of R-(+) verapamil, but the elimination half-time ($T_{1/2(\beta)}$) was longer in rat following oral administration of racemic verapamil. At 1.3 h after oral administration of racemic verapamil, however, there were no significant differences between enantiomers for the distributions in major tissues such as heart, cerebrum, cerebellum, liver, spleen and kidney.

• Mass Spectrometry Letters
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• v.10 no.1
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• pp.1-10
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• 2019

Amphetamine-type stimulants (ATS) are a group of ${\beta}$-phenethylamine derivatives that produce central nervous system stimulants effects. The representative ATS are methamphetamine and 3, 4-methylenedioxymethamphetamine (MDMA), and abuse of ATS has become a global problem. Methamphetamine is abused in North America and Asia, while amphetamine and 3, 4-methyle nedioxym ethamphetamine (Ecstasy) are abused in Europe and Australia. Methamphetamine is also the most abused drug in Korea. In addition to the conventional ATS, new psychoactive substances (NPS) including phenethylamines and synthetic cathinones, which have similar effects and chemical structure to ATS, continue to spread to the global market since 2009, and more than 739 NPS have been identified. For the analysis of ATS, two tests that have different theoretical principles have to be conducted, and screening tests by immunoassay and confirmatory tests using GC/MS or LC/MS are the global standard methods. As most ATS have a chiral center, enantiomer separation is an important point in forensic analysis, and it can be conducted using chiral derivatization reagents or chiral columns. In order to respond to the growing drug crime, it is necessary to develop a fast and efficient analytical method.

• Geomechanics and Engineering
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• v.27 no.5
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• pp.481-495
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• 2021

This article assesses and estimates the progressive failure mechanism of complex pit-rest secondary toppling of slopes that are located within the vicinity of the Gas Flare Site of Refinery No. 4 in South Pars Special Zone (SPSZ), southwest Iran. The finite element numerical procedure based on the Shear Strength Reduction (SSR) technique has been employed for the stability analysis. In this regard, several step modelling stages that were conducted to evaluate the slope stability status revealed that the main instability was situated on the left-hand side (western) slope in the Flare Site. The toppling was related to the rock column-overburden system in relation to the overburden pressure on the rock columns which led to the progressive instability of the slope. This load transfer from the overburden has most probably led to the separation of the rock column and to its rotation downstream of the slope in the form of a complex pit-rest secondary toppling. According to the numerical modelling, it was determined that the Strength Reduction Factor (SRF) decreased substantially from 5.68 to less than 0.320 upon progressive failure. The estimated shear and normal stresses in the block columns ranged from 1.74 MPa to 8.46 MPa, and from 1.47 MPa to 16.8 MPa, respectively. In addition, the normal and shear displacements in the block columns ranged from 0.00609 m to 0.173 m and from 0.0109 m to 0.793 m, respectively.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.7 no.1
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• pp.25-31
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• 2009

An analytical method of $^{99}Tc$ concentration in soil was set up and discussed considering the $^{99}Tc$ concentration in Korean soil measured with its analytical method. A selective TEVA resin was used to separate and purify the $^{99}Tc$ in the soil sample. $^{99m}Tc$ from a commercial $^{99}Mo/^{99m}Tc$ generator was used as a yield tracer for the chemical separation of $^{99}Tc$ and its problem when using $^{99m}Tc$ as a tracer was discussed. The chemical recovery yield of $^{99}Tc$ was above 70%. The optimum conditions of inductively coupled plasma mass spectrometry system(ICP-MS) were set up to determine the $^{99}Tc$ after the separation process. The minimum detectable activity(MDA) was 15 mBq/kg-dry in this analytical procedure. The $^{99}Tc$ concentration in soils of Jeju and Kori were measured in the rage of 33.73-89.16 mBq/kg-dry. Those values were less than those reported in other countries and seemed to be originated from atmospheric fallout.

• Korean Chemical Engineering Research
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• v.51 no.2
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• pp.240-244
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• 2013

Although forward osmosis desalination technology has drawn substantial attention as a next-generation desalination method, the energy efficiency of its draw solution treatment process should be improved for its commercialization. When ammonium bicarbonate is used as the draw solute, the system consists of forward-osmosis membrane modules, draw solution separation and recovery processes. Mixed gases of ammonia and carbon dioxide generated during the draws solution separation, need to be recovered to re-concentrate ammonium bicarbonate solution, for continuous operation as well as for the economic feasibility. The diluted ammonium bicarbonate solution has been proposed as the absorbent for the draw solution regeneration. In this study, experiments are conducted to investigate performance and features of the absorption corresponding to absorbent concentration. It is concluded that ammonium bicarbonate solution can be used to recover the generated ammonia and carbon dioxide. The results will be applied to design and operation of pilot-scale forward-osmosis desalination system.

• The KIPS Transactions:PartD
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• v.9D no.6
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• pp.1145-1156
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• 2002

We propose a web document transcoding technique that translates existing web pages designed for desktop computers into an appropriate form for hand-held devices connected to the wireless internet. By defining a content block based on a visual separation and using it as a minimum unit for analyzing and converting processes, we can get web pages converted more exactly. We also apply the reallocation of the content block and the generation of new index in order to provide convenient interface without left-right scrolling in small screen devices. These methods, compared with existing ways such as text level summary or partial extraction method, can provide efficient navigation and a full recognition of web documents. To gain those transcoding benefits, we propose the Layout-Forming Tag Analysis Algorithm that analyzes structural tags, which motivate visual separation and the Component Grouping Algorithm that extracts the content block. We also classify and rearrange the content block and generate the new index to produce an appropriate form of web pages for small display devices. We have designed and implemented our transcoding system in a proxy server and evaluated the methods and the algorithms through an analysis of transcoded results. Our transcoding system showed a good result on most of popular web pages that have complicated structures.

• Geotechnical Engineering
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• v.13 no.1
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• pp.111-122
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• 1997

The calculation of phase velocities in Spectral-Analysis -of-Surface -Waves (SASW) meas urements requires unwrapping phase angles. In case of layered systems with strong stiffness contrast like a pavement system, conventional phase unwrapping algorithm to add in teger multiples of 2n to the principal value of a phase angle may lead to wrong phase volocities. This is because there is difficulty in counting the number of jumps in the phase spectrum especially at the receiver spacing where the measurements are in the transition Bone of defferent modes. A new phase interpretation scheme, called "Impulse Response Fil traction ( IRF) Technique," is proposed, which is based on the separation of wave groups by the filtration of the impulse response determinded between two receivers. The separation of a wave group is based on the impulse response filtered by using information from Gabor spectrogram, which visualizes the propagation of wave groups at the frequency -time space. The filtered impulse response leads to clear interpretation of phase spectrum, which eliminates difficulty in counting number of jumps in the phase spectrum. Verification of the IRF technique was performed by theoretical simulation of the SASW measurement on a pavement system which complicates wave propagation.opagation.