• Title/Summary/Keyword: synthetic temperature

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Magnetic Property of α-Fe2O3 Nanoparticles Prepared by Sonochemistry and Take-off Technique

  • Koo, Y.S.;Yun, B.K.;Jung, J.H.
    • Journal of Magnetics
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    • v.15 no.1
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    • pp.21-24
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    • 2010
  • A new synthetic method for the formation of uniform $\alpha-Fe_2O_3$ nanoparticles was reported and their magnetic properties were investigated. The sonochemical synthesis and the subsequent take-off technique resulted in spherical shaped $\alpha-Fe_2O_3$ nanoparticles with an average diameter of 60 nm. The temperature- and applied magnetic field-dependent magnetization of the $\alpha-Fe_2O_3$ nanoparticles was explained by the sum of two contributions, i.e., the Morin transition and superparamagnetism, because the critical size for superparamagnetism was within the size variation of the nanoparticles.

A Study on the Color Reproduction in Decalcomania (전사인쇄에 있어서 색재현에 관한 연구)

  • Jung, Da-Hyun;Cho, Ga-Ram;Koo, Chul-Whoi
    • Journal of the Korean Graphic Arts Communication Society
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    • v.24 no.2
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    • pp.35-48
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    • 2006
  • Textile decalcomania printing is how after the disperse dye which is melting and vaporizing absorbs on the surface of the cloth, it colors by permeating into the cloth inside. So it has applied a lot to the synthetic fiber like polyester. However, because there is no showing right temperature and time in case of printing on the polyester fiber and the microfiber, this study aims at it. The experimental methods are like this : first measuring the density for the objective judgment, and measuring colors with the colorimeter, and then study for the color reproduction through a visual evaluation.

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Development and Assessment of a Downdraft Gasifier for Biomass Gasification (하향식 바이오매스 가스화장치의 개발 및 평가)

  • Hong, Seong-Gu;Shim, Jae-Hoon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.50 no.4
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    • pp.89-97
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    • 2008
  • A downdraft gasifier was manufactured for biomass gasification. The gasifier was designed based on the principles of gasification presented in previous studies. The pipes of 25mm diameter were used for both supplying air and discharging producer gas. Wood charcoals were mostly used for fuels. The concentration of CO ranged from 25 to 35%, comparable to the values presented in other studies. The temperature outside wall of the gasifier was measured up to $400^{\circ}C$, indicating a great heat loss. When glass wool was cover over the wall, some parts of wire mesh located in the bottom of the reactor were molten down. There were several modifications that should be made in order to improve its efficiency and obtain more stable continuous gasification, including insulation, reduction in pressure loss, durable bottom meshes, the optimum length of reaction part, and safety.

Star Formation Histories of the Globular Clusters with Multiple Stellar Populations

  • Joo, Seok-Joo;Lee, Young-Wook;Yoon, Suk-Jin;Han, Sang-Il
    • Bulletin of the Korean Space Science Society
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    • 2009.10a
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    • pp.29.3-29.3
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    • 2009
  • Recent observations for the Galactic globular clusters (GCs) have shown that a number of GCs have characteristic features of multiple stellar populations, such as multiple main-sequences (MSs), splits in sub-giant branch (SGB), bimodal and/or extended horizontal branches (HBs). Based on the population synthesis models, we investigate star formation histories of the GCs with multiple populations, $\omega$ Cen, M54, NGC 1851, NGC 6388, NGC 6441, and NGC 2808, by comparing synthetic model color-magnitude diagrams (CMDs) with observations. We adopt most up-to-date Yonsei-Yale (Y2) stellar evolutionary tracks and isochrones from MS to post-HB, as well as improved color-temperature transformations from the recent stellar atmosphere libraries. Our models show that the observed features can be naturally explained by assuming the presence of helium-enhanced subpopulations.

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A Study on Stabilized CdS-CdSe Red Stain A Study on Zircon Cadmium Sulphoselenide Stain (안정화 CdS-CdSe계 채료에 관한 연구 제2보$ ZrSiO_4-Cd(S_xS_{1-x})$ 의 합성)

  • 이종근;김종옥
    • Journal of the Korean Ceramic Society
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    • v.23 no.4
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    • pp.23-26
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    • 1986
  • The synthetic conditions of $ ZrSiO_4-Cd(S_xS_{1-x})$ stains from CdS, Se, $SiO_2$ , 4ZrO_2$ and Lif were investigated and the colors were examined. Colors of the stains prepared were yellow orange red pink ruby and violet in relation to both the content of CdS-Se in $ZrSiO_4$ and firing temperature. Colors of these series stains were thermally stabilized probably by the structural stability of zirconium silicate. Furthermore by the result of X-ray diffraction analysis it is assumed that color of the zircon cadmium sulphoselenide $ ZrSiO_4-Cd(S_xS_{1-x})$ stain is developed by neither the coloring ions in $ZrSiO_4$ lattice nor the solid solution of $ZrSiO_4$ and $Cd(S_xS_{1-x})$ but by the small crystals of $Cd(S_xS_{1-x})$ being occluded by the zirconium silicate during sintering process.

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The Effect of Butt Gap in Insulation Properties for a HTS Cable (고온초전도 케이블의 절연강도에 미치는 butt gap 의 영향)

  • 곽동순;김영석;뤼엔반둥;김해종;김상현
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.213-217
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    • 2003
  • In this paper, we studied electric Insulation characteristics of synthetic Laminated Polypropylene Paper (LPP) in liquid nitrogen (L$N_2$) for the application to high temperature super-conducting (HTS) cable. And, we selected the insulation paper/L$N_2$composite insulation type for the electric insulation design of a HTS cable. Furthermore, we compared the breakdown characteristics of the butt gap and bended mini-model cable that comes into being in this kind of cryogenic insulation type. It is necessary to understand the winding parameter of insulation paper/L$N_2$composite insulation.

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Design and Synthesis of New 3-Allylthio-6-alkylthiopyridazine Analogs via Nucleophillic Substitution Reaction (친핵 치환반응을 이용한 새로운 3-Allylthio-6-alkylthiopyridazine 유도체의 합성과 설계)

  • Park, Hae-Sun;Park, Myung-Sook
    • YAKHAK HOEJI
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    • v.58 no.1
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    • pp.28-32
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    • 2014
  • A new series of 3-allylthio-6-alkylthiopyridazines (3)~(12) was synthesized from dichloropyridazine (1) for development of candidates to retain anticancer activity of human breast cancer. The process involves allythiolation and alkylthiolation from 3,6-dichloropyridazine. 6-Substituted allylthiopyridazines (3)~(12) were prepared from 3-allylthiopyridazinyl chloride (2) via nucleophilic substitution with alkylthiol anion as nucleophile. 3-Allylthiopyridazinyl chloride (2) could be converted to pyridazines (3)~(11) using 1 equivalent of alkyl mercaptan at reflux temperature in methanol. 3,6-Diallylthiopyridazine (12) was synthesized from 3,6-dichloropyridazine (1) using allyl mercaptan (4 equivalent) and sodium hydroxide in methanol. Synthetic compounds were fully identified using NMR, IR, GC-MS data.

Phase behaviors, lamellar structures, and physical properties of synthetic vitamin E ceramide (Tocomide) mixed with cholesterol and linoleic acid

  • Lee, Young-Jin;Kim, Do-Hoon;Park, Ho-Sik;Kang, Hyung-Seok;Kim, Joong-Soo;Kim, Han-Kon
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.357-368
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    • 2003
  • II-A isotherms and phase behaviors of 'tocomide', a newly synthesized 1,3-bis(N-(2-hydroxyethyl)-tocopherol succinylamino)-2-hydroxypropane, mixed with cholesterol and linoleic acid, was studied for its monolayer miscibility and a stable delivery formulation for antioxidant applications. The monolayer of tocomide and cholesterol was formed in a homogeneously mixed state at air-water interface. The ternary mixtures with linoleic acid showed various bulk structures, including a stable and transparent solution of thermodynamically stable lamellar phase. The lamellar structure was confirmed by the X-ray diffraction (XRD) patterns and polarized microscopy such that pure tocomide formed a liquid crystal at room temperature with a lamellar periodicity of 36.7 $\AA$(2$\theta$=2.41$^{\circ}$).

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Synthesis and Characterization of High Luminance ${Zn_2}{SiO_4}$:Mn Phosphors (고발광 ${Zn_2}{SiO_4}$:Mn 형광체의 제조 및 특성)

  • 성부용;정하균;박희동;김대수
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.774-780
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    • 2000
  • In order to improve luminescence prperty of phosphors, we have synthesized Zn2SiO4:Mn phosphors by a new chemical synthetic route, i.e., the homogeneous precipitation method. This method has featured that the formation of phosphoris completed at relatively low temperature of 105$0^{\circ}C$ and the particle morphology exhibits spherical shape to be well-dispersed and uniform size. At all the Mn concentration explored, phosphors prepared by this method have exhibited the improved emission intensities. In particular, the emission intensities of phosphors with Mn doping contents between 1 at% and 3.5 at% were higher about 40% than that of commercial phosphor. On the other hand, the decay time has been decreased from 23 ms to 11 ms with increasing Mn concentration. In addition, the phosphor composition containing 3 at% Mn has displayed the most saturated color.

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Low-Temperatrue Synthesis of Mullite Powders by the Emulsion Technique (MgO-Al2O3-SiO2계 요업원료의 제조 및 소결특성 -에멀젼법에 의한 Mullite분체의 저온합성-)

  • 현상훈;이희수;송승룡
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.361-370
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    • 1989
  • Mullite powders were synthesized from the common solution of aluminum sulfate and sodium silicate solutions by the emulsion-hot kerosene technique. The reaction temperature and mechanism for mullitization and the characteristics of synthesized mullite powders were investigated. The effect of Na components introduced from sodium silicate solution on the physical property and microstructure of sintered mullite was also examined. It was proved that mullites were formed at 75$0^{\circ}C$ through the reaction mechanism of Na2O.2.2SiO2+3.3Al2(SO4)3longrightarrow1.1(3Al2O3.2SiO2)+Na2SO4+8.9SO3. Synthetic mullite powders consisted of the compositiion of 3Al2O3.2SiO2 and showed highly agglomeration of hollow spherical particles of 1${\mu}{\textrm}{m}$ diameter. The density and fracture toughness of sintered mullites were somewhat reduced because of the effect of a very small amount of residual Na components.

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