• Title/Summary/Keyword: synthetic solution

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Sol-gel Synthesis and Properties of Phosphate Ceramics

  • Lee, Burtrand I.;Cao, Zhicheng;Samuels, Willam D.;Exarhos, Gregory J.
    • The Korean Journal of Ceramics
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    • v.6 no.4
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    • pp.390-395
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    • 2000
  • Silicon, titanium, zirconium phosphates were synthesized by starting with appropriate chemical precursors in a solution. The synthetic procedure, chemical and physical structures were examined by FT-IR, liquid and solid state NMR, TGA, SEM, XRD, etc. The phosphates were examined for thermal and electrical properties. Advantages of the synthesis technique and the data on unique structures and thermal properties are reported.

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Synthesis of Magnesite by Hydrothermal Method (마그네사이트(MgCO$_3$)의 수열합성에 관한 연구)

  • 오기동
    • Journal of the Korean Ceramic Society
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    • v.11 no.3
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    • pp.14-18
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    • 1974
  • Magnesite single crystals up to 250 microns were synthesized from an equi-molar solution of MgCl2 and Na2CO3 in the micro-autoclave at 180-20$0^{\circ}C$. The lattice constant of synthetic magnesite was obtained a=4.6369(7), c=15.0230(10)A.U. by a least squares analysis based on the UNICS Program (Sakurai 1967) was applied to 28 reflections. Results of X-ray powder diffraction and of DTA, TGA, IRA, and EPMA studies indicate that synthesized magnesite has properties to those of natural magnesite.

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The Oxidation of Hydrazobenzene by Oxygen Catalysed by Co (3MeOsalen) in Methanol

  • Homer Roger B.;Cannon Roderick D.;Kim Stephen S.B.
    • Bulletin of the Korean Chemical Society
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    • v.6 no.2
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    • pp.115-118
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    • 1985
  • The oxidation of hydrazobenzene by oxygen in methanol solution is catalysed by Co(3MeOsalen) which is a synthetic oxygen carrier. The products are trans-azobenzene and water. The rate of the reaction has been studied spectrophotometrically and the rate law established. A mechanism involving a ternary complex of catalyst, hydrazobenzene and oxygen has been proposed.

Synthesis and in Vitro Stability Evaluations of 5-(2'-(N-(1-methyl-3'-carbamylphenyl)-n-propyl))aminoethyl)-8-hydroxy-4-methylcarbostyril Derivatives (5-(2'-(N-(1-메틸-3-(3'-카바밀페닐)-n-프로필))아미노에틸)-8-히드록시-4- 메틸카보스티릴 유도체의 합성 및 안정성 연구)

  • 윤성화;박규순
    • YAKHAK HOEJI
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    • v.39 no.5
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    • pp.506-510
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    • 1995
  • The 5-(2'-(N-(1-methyl-3'-carbamylphenyl)-n-propyl))aminoethyl)-8- hydroxy-4-methyl-carbostyril derivatives which have isoelectronic and isosteric structural similarity with dobutamine without having the Catechol-O-Methyltransferase (COMT) vulnerable m-hydroxy group were synthesized via 7 synthetic steps, and their stabilities in phosphate buffer solution(pH=7.4), human blood. 80% human plasma and 20% rat liver homogenate were determined in vitro condition.

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Stereoselective Total Synthesis of (-)-Cytoxazone

  • Kim, Ji-Duck;Hoon, Jung-Young
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.179.2-179.2
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    • 2003
  • We have developed the novel one-pot synthetic method for regioselective and stereoselective N-protected amines through the reaction of various ethers with chlorosulfonyl isocyanate (CSI). Also, we found a novel technique to compare directly the stability of carbocations in the solution phase and established the stability order of the various carbocations. And we reported the cleavage of benzyl and p-methoxybenzyl protecting groups of alcohols and phenols in the presence of other functional groups using CSI. (omitted)

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A Study on the Optimum Mixture for Reducing Combined Deterioration of Eco-Friendly Concrete Using Waste Fibe (폐섬유를 활용한 친환경 바탕 콘크리트의 복합열화 저감 최적 배합에 관한 연구)

  • Kim, Dae-Geon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.37-38
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    • 2023
  • As one of the resource recovery projects, this study aims to select natural fibers and synthetic fibers that can be used for concrete mixing among waste fibers and reuse them for the base concrete mixture. Using waste fiber, we seek a solution to the problem of reduced fluidity and hardening time of fiber-reinforced concrete and find the optimal mix of the ground concrete mixed with waste fiber.

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IN VITRO STUDY OF CARIOGENIC POTENTIAL OF INFANT FORMULAS (이유식의 우식유발능에 관한 생체외 연구)

  • Park, Deuk-Hee;Lee, Kwang-Hee;Kim, Dae-Eop
    • Journal of the korean academy of Pediatric Dentistry
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    • v.27 no.1
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    • pp.32-39
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    • 2000
  • The purpose of this study was to assess the cariogenic potential of five infant formulas in vitro. as compared with 10% sucrose solution and whole bovine milk. Buffering capacities were determined by the amount of 0.1 N lactic acid consumed to titrate the 50ml specimen solutions to pH 4.0. The pH of the specimen solution inoculated by Streptococcus mutans was measured by pH meter and the surface microhardness of primary tooth enamel immersed in the specimen solution was measured by the microhardness tester, before and after 48 hours incubation. Also, the solubility of calcium from synthetic hydroxyapatite was evaluated by atomic absorption spectrophotometer The buffering capacity of infant formulas was higher than that of sucrose solution and lower than that of milk, and there were significant differences among infant formulas(P<0.01). The average pH of infant formulas after 48 hours incubation was lower than that of sucrose solution and milk, and there was significant difference between infant formulas and milk(P<0.05). There were no signifiant differences among oops in the microhardness change of primary tooth enamel and in the amount of dissolved calcium ion from synthetic hydroxyapatite after incubation with Streptococcus mutans. In conclusion, infant formulas seemed to fulfill the basic requirments to cause dental caries in primary teeth, and there were significant differences of cariogenic potential among infant formulas. Cooperative efforts of dentistry and manufacturers to reduce the cariogenic potential of infant formulas would be necessary to prevent the early childhood caries in children.

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Recovery of Cobalt from Synthetic Leaching Solution of Manganese Nodule Matte by Solvent Extraction-electrowinning (용매추출-전해채취법에 의한 망간단괴 매트상 모의 침출용액으로부터 코발트 회수)

  • Kim, Hyun-Ho;Nam, Chul-Woo;Park, Kyung-Ho;Yoon, Ho-Sung;Kim, Min-Seuk;Kim, Chul-Joo;Park, Sang-Woon
    • Resources Recycling
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    • v.25 no.2
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    • pp.33-41
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    • 2016
  • A scale up tests (380 kg/day) using a continuous solvent extraction and electro-winning system was carried out to separate and recover cobalt from a solution containing 1.91 g/L Co and 14.65 g/L Ni. The solution was obtained during a process including solvent extraction and precipitation stages for removal of Cu and Fe from a synthetic sulfuric acid solution of manganese nodule matte. The optimal condition for solvent extraction was : solvent concentration of 0.22M Na-Cyanex 272 (45% saponified with NaOH) and O:A phase ratios of 1:1.5, 10:1 and 1.5:1 used in extraction, scrubbing and stripping stages, respectively. The extraction and stripping efficiencies were found to be 99.8% and 99.88%, respectively. The stripped solution contained 40.27 g/L Co with 4 ppm Ni. Cobalt metal of 99.963% purity was yielded with current efficiency of 67% and current density of $0.563A/dm^2$ during the electro-winning process.