• Title/Summary/Keyword: syntheses

Search Result 527, Processing Time 0.022 seconds

Metal Complexes of Sulfur-containing Ligands Ⅰ. Syntheses and Properties of Nickel(Ⅱ) Complexes of Dithiocarbamates (황함유리간드의 금속착물 Ⅰ. 디티오카바메이트류의 니켈(Ⅱ)착물의 합성과 그 성질)

  • In-Sik Kim;Kim Chan-Woo;Chang-Su Kim
    • Journal of the Korean Chemical Society
    • /
    • v.37 no.2
    • /
    • pp.206-212
    • /
    • 1993
  • Syntheses and properties of zwitterionic dithiocarbamates and their nickel(Ⅱ) complexes are described. The complexes have been characterized by mass infrared and electronic absorption spectroscopy, and conductivity measurement. Ni(Ⅱ)-dithiocarbamato complexes are soluble in polar solvents such as water, methanol, and acetone etc. The possible structures were proposed on the basis of elemental analyses and physical properties.

  • PDF

Syntheses, Spectral, Surface Morphological and Gamma Ray Irradiation Studies of Some Oxomolybdenum(V) and Dioxomolybdenum(VI) Complexes of an Azo Dye Derived from 4-aminoantipyrine

  • Nair, M.L. Harikumaran;Appukuttan, Anju.S.
    • Journal of the Korean Chemical Society
    • /
    • v.56 no.2
    • /
    • pp.217-227
    • /
    • 2012
  • Syntheses of some novel oxomolybdenum(V) and dioxomolybdenum(VI) complexes with an azo dye methoxyphenolazoantipyrine (HL) derived from 4-aminoantipyrine and 2-methoxyphenol are reported. The complexes have been characterized by elemental analyses, molar conductance, magnetic susceptibility data, IR, UV-Vis, $^1H$ NMR, EPR and FAB mass spectral studies. The physicochemical studies and spectral data indicate that HL acts as a bidentate chelating ligand. The complexes have the general formulae [$MoO(HL)XCl_2$] and [$MoO_2(HL)XCl$],where X=Cl, NCS or $NO_3$. All the complexes are found to have distorted octahedral geometry. Structural and morphological characterization of the complexes [$MoO(HL)Cl_3$](1) and [$MoO_2(HL)Cl_2$](4) before and after gamma ray irradiation,was performed by X-ray diffraction and scanning electron microscopy( SEM).The ligand and the complexes were screened for their possible antimicrobial activities.

Syntheses of Thermotropic Liquid-Crystalline Copoly(ester amide)s Containing a Flexible Spacer in the Main Chain and Their Structure Interpretation (Thermotropic copoly(ester amide)의 합성과 구조해석)

  • ;;Tosiyuki Uryu
    • Textile Coloration and Finishing
    • /
    • v.2 no.4
    • /
    • pp.237-244
    • /
    • 1990
  • Syntheses and liquid-Crystallinites of thermotropic copoly (ester amide)s were investigated. The three components melt polycondensation of 4,4'-dicarboxy-$\alpha$, $\omega$-diphenoxyalkane as an A component, 4-4'diacetoxybiphenyl as a B, and p-N-acetoxy-aminobenzoic acid as a C gave the thrmotropic copoly(ester amide)s containing a flexible splacer in the polymer backbone. Diacetylated hydroquinone, methyl hydroquinone, chlorohydroquinone, and phenyl hydroquinone were used as anther B components. A polymer(6BPAB) having 10 mol% of C component and hexamethylene space. showed a typical nematic texture between $245^{\circ}C(T_m)\; and\; more\; than\; 360^{\circ]C(T_i)$. The melting points of the members of this series of polymers increased with decreasing methylene spacer. The polymer structure and mesomorphic nature were examined by solid and solution ^{13}C-NMR4 spectroscopy, cross polarizing microscopy with a hot stage, and X-ray diffactometry.

  • PDF

DESIGN AND SYNTHESES OF 2-OXIRANECARBOXYLATE DERIVATIVES AND THEIR HYPOGLYCEMIC ACTIVITIES

  • Jew, Sang-sup;Kim, Eun-kyung;Je, Sun-mi;Zhao, Long-Xuan;Kim, Hyung-ook;Park, Hyeung-geun;Ko, Kwang-ho;Kim, Won-ki;Kim, Hwa-Jung
    • Proceedings of the Korean Society of Applied Pharmacology
    • /
    • 1998.05a
    • /
    • pp.31-35
    • /
    • 1998
  • A series of 2-oxiranecarboxylate derivatives was prepared as carnitine palmitoyl transferase I (CPT- -I) inhibitors for the development of new antidiabetic agents. The syntheses and biological activities were reported. The most promising derivative, 15b showed 2.5 times more hypoglycemic activity and 2 times lower acute toxicity compared to Etomoxir.

  • PDF