• Title/Summary/Keyword: syntheses

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( Syntheses of Improved Polymer/Organic Materials for Electroluminescence(EL) Device and Electro-Optical Characteristics I. Properties of Dye Doped Organic EL Device (고기능 EL소자용 고분자/유기 재료의 합성 및 전기 광학적 특성 I. 색소 도핑에 의한 EL소자의 특성)

  • 김성훈
    • Journal of the Korean Graphic Arts Communication Society
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    • v.13 no.2
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    • pp.33-45
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    • 1995
  • 1, 4-Diketo-3, 6-diphenyl-pyrrolo-[3, 4c]-pyrrole(abbriviated DPP) is a new heterocyclic pigment of red color whose chlorinated derivative is now on the market. DDP was synthesized from benzonitrile and diethylsuccinate. Pariser-parr-pople(PPP) molecular orbital calculations have been carried out on the DPP in other to study spectroscopically the DPP chromophore on deprotonation.

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Synthesis and Photoluminescence of Silole Derivatives

  • Sharma, Arun Kumar;Lee, Sung-Gi;Um, Sungyong;Cho, Bomin;Sohn, Honglae
    • Journal of Integrative Natural Science
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    • v.6 no.3
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    • pp.176-180
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    • 2013
  • The syntheses of 9,9'-spiro-9-silabifluorene as well as 1,1-dichloro-1-silafluorene and 1,1-dimethyl-1-silafluorene through the formation of 2,2'-dibromobiphenyl have been emphasized with good yields. Their fluorescence spectra are obtained using photoluminescence spectrometer and assumed to be the precursors of the development of polymers.

Approaches to the Syntheses of Partially Reduced Imidazo[1,2-a]pyridines

  • Shin, Jun-Hwa;Nho, Young-Chang;Howard, Arthur S.
    • Bulletin of the Korean Chemical Society
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    • v.29 no.10
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    • pp.1998-2004
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    • 2008
  • Two synthetic pathways to substituted hexahydroimidazo[1,2-a]pyridines, which may serve as precursors of aza-alkaloids, were investigated. The first involves the condensation of a bisnucleophilic enediaminoester and a biselectrophile. The second involves attachment to nitrogen of the carbon chain skeleton required to form the six-memberd ring, before formation of the enediaminoester. Several substituted hexahydroimidazo[1,2- a]pyridines were synthesized via these two approaches.

Syntheses and Central Nervous Depressant Activities of Piperine Derivatives (V) (피페린 유도체의 합성 및 중추 억제작용에 관한 연구(V) -Methylenedioxyphenylalkenoic Acid Amide 유도체-)

  • 도경삼;임중기;우경식;이은방
    • YAKHAK HOEJI
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    • v.30 no.4
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    • pp.163-168
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    • 1986
  • Thirteen compounds were synthesized by condensing the N-heterocyclic amines (piperidine, pyrrolidine, morpholine) and secondary aliphatic amines (dimethylamine, diethylamine) with 3,4-methylenedioxyphenylalkenoic acid chlorides for developing CNS depressants. Among them, N, N-diethyl-3,4-methylenedioxycinnamamide (IX) and N, N-dimethyl-5-(3,4-methylenedioxyphenyl)-2, 4-pentadienoic acid amicle (XII) exhibited strong activity in antagonism against pentylenetetrazole-induced convulsion, strychnine-induced convulsion and maximal electroshock seizure. N, N-Dimethyl-3, 4-methylenedioxycinnamide (VIII) showed more potent activity in antagonism against strychnine-induced convulsion and maximal electroshock seizure and in the prolongation of hexobarbital sleeping time.

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Syntheses and Characterization of Columnar Discotic Liquid Crystals Based on TTF Core for Organic Electronic Materials

  • Wang, Lei;Jeong, Kwang-Un;Lee, Soo-Hyoung;Lee, Myong-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1477-1479
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    • 2008
  • We report the first TTF compounds having columnar LC phase at room temperature. Based on the thermal, structural, and morphological observations, it was concluded that TTF derivative with long alkyl chains has highly ordered oblique columnar LC at room temperature. The new TTF derivatives have excellent oxidative stability which is desirable for a p-type (hole transport) materials.

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Syntheses of Infrared Absorbing Nickel Complex Dyes (적외흡수 니켈 착체색소의 합성)

  • Kim, Sung-Hoon;Lim, Yong-Jin
    • Textile Coloration and Finishing
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    • v.3 no.3
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    • pp.29-33
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    • 1991
  • Some ir absorbing nickel complex dyes were synthesized by the reaction of phenylene diamines, 2-aminobenzenethiols and 2-aminobenzene selenols, tetrathiols with nickel (II) chloride. These dyes absorbed ir light, but those from phenylene diamines absorbed at 780-800 nm which is the most favorable wavelength region for semiconductor laser optical recording dye medium.

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