• 제목/요약/키워드: swells

검색결과 60건 처리시간 0.028초

겔 작용에 의한 쿼터늄-18 헥토라이트를 사용한 Water-in-Oil 에멀젼의 안정화 기술 (Stabilizing Technology of water-in-Oil Emulsification with Quaternium-18 Hectorite by Gelling Action)

  • 김인영;조춘구;이주동
    • 대한화장품학회지
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    • 제29권1호
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    • pp.135-150
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    • 2003
  • This study is described the stabilizing technology of water-in-oil (w/o) emulsion and the mechanism of emulsification with quaternium-18 hectorite (Q-18 HTRT) by swelling action. When Q-18 HTRT is dispersed in oil, it swells and constructs card-house structure adding ethanol, and formation of water phase is caused by hydrogen bonding. The gelling activities of Q-18 HTRT were excellent such as mineral oil, squalane, cetostearyl isononanoate, isostearic acid, cetyl octanoate, octyl dodecanol and so on. Especially, when oil gel containing Q-18 HTRT passed one to three times by Roll mill. It made the W/O emulsion cream (W/O-ECRM) having 2.0 w/w% of Q-18 HTRT and also produced the control sample (control) including 3.0 w/w% of cetyl PEG/PPG- l0/l dimethicone. The stability of after 24 weeks, Hardness of W/O-ECRM dropped 7.48%, whereas hardness of control went down 57 71%. As a result of these test emulsification of W/O-ECRM is superior compared with control. In cosmetic, 0-18 HTRT can use as suspending agent, oil adsorbent, emulsifying agent, dispersing agent, viscosifier and pigment.

General picture of co-nonsolvency for linear and ring polymers

  • Park, Gyehyun;Lee, Eunsang;Jung, YounJoon
    • EDISON SW 활용 경진대회 논문집
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    • 제5회(2016년)
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    • pp.147-154
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    • 2016
  • Co-nonsolvency is a puzzling phenomenon that a polymer swells in a good solvent individually, but it collapses in a mixture of good solvents. This structural transition with changing solvent environment has been drawing attention due to practical application for stimuli-responsive polymer. The aim of this work is to describe the physical origin of the co-nonsolvency. In this work, we present Monte Carlo simulations for polymer solutions by using simple and general model. We simulate linear and ring polymers to compare their co-nonsolvency behaviors. Calculating Flory exponents and bridging fractions gives a good description for polymer structures. While the polymer structure shows non-monotonous behavior with increasing the cosolvent fraction, the chemical potential decreases monotonously. This indicates that coil-to-globule transition of polymers is purely controlled by free energy and can be regarded as a thermodynamics transition. We also present that ring polymers have higher looping probability than linear polymers, thus the bridging fraction remains higher at high cosolvent fraction. Our study provides a new perspective to understand polymer structure when the polymer "dissolves well" in any solvent.

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DVR시스템에 사용되는 인버터부의 LC필터 설계와 피드백 성능분석 (Design and Feedback Performance Analysis of the Inverter-side LC Filters Used in the DVR System)

  • 박종찬;손진근
    • 전기학회논문지P
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    • 제64권2호
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    • pp.79-84
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    • 2015
  • Voltage sags are considered the dominant disturbances affecting power quality. Dynamic voltage restorers(DVRs) are mainly used to protect sensitive loads from the electrical network voltage disturbances such as sags or swells and could be used to reduce harmonic distortion of ac voltages. The typical DVR topology essentially contains a PWM inverter with LC Filter, an injection transformer connected between the ac voltage line and the sensitive load, and a DC energy storage device. For injecting series voltage, the PWM inverter is used and the passive filter consist of inductor(L) and capacitor(C) for harmonics elimination of the inverter. However there are voltage pulsation responses by the characteristic of the LC passive filter that eliminate the harmonics of the PWM output waveform of the inverter. Therefore, this paper presented design and feedback performance of LC filter used in the DVRs. The voltage control by LC filter should be connected in the line side since this feedback method allows a relatively faster dynamic response, enabling the elimination of voltage notches or spikes in the beginning and in the end of sags and strong load voltage THD reduction. Illustrative examples are also included.

Modelling and Performance Analysis of UPQC with Digital Kalman Control Algorithm under Unbalanced Distorted Source Voltage conditions

  • Kumar, Venkateshv;Ramachandran, Rajeswari
    • Journal of Power Electronics
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    • 제18권6호
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    • pp.1830-1843
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    • 2018
  • In this paper, the generation of a reference current and voltage signal based on a Kalman filter is offered for a 3-phase 4wire UPQC (Unified Power Quality Conditioner). The performance of the UPQC is improved with source voltages that are distorted due to harmonic components. Despite harmonic and frequency variations, the Kalman filter is capable enough to determine the amplitude and the phase angle of load currents and source voltages. The calculation of the first state is sufficient to identify the fundamental components of the current, voltage and angle. Therefore, the Kalman state estimator is fast and simple. A Kalman based control strategy is proposed and implemented for a UPQC in a distribution system. The performance of the proposed control strategy is assessed for all possible source conditions with varying nonlinear and linear loads. The functioning of the proposed control algorithm with a UPQC is scrutinized and validated through simulations employing MATLAB/Simulink software. Using a FPGA SPATRAN 3A DSP board, the proposed algorithm is developed and implemented. A small-scale laboratory prototype is built to verify the simulation results. The stated control scheme for the UPQC reduces the following issues, voltage sags, voltage swells, harmonic distortions (voltage and current), unbalanced supply voltage and unbalanced power factor under dynamic and steady-state operating conditions.

Evaluation of high plasticity clay stabilization methods for resisting the environmental changes

  • Taleb, Talal;Unsever, Yesim S.
    • Geomechanics and Engineering
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    • 제30권5호
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    • pp.461-469
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    • 2022
  • One of the most important factors that should be considered for using any ground improvement technique is the stability of stabilized soil and the durability of the provided solution for getting the required engineering properties. Generally, most of the earth structures that are constructed on clayey soils are exposing movements due to the long periods of drying or wetting cycles. Over time, environmental changes may result in swells or settlements for these structures. In order to mitigate this problem, this research has been performed on mixtures of high plasticity clay with traditional additives such as lime, cement and non-traditional additives such as polypropylene fiber. The purpose of the research is to assess the most appropriate ground improvement technique by using commercially available additives for resisting the developed desiccation cracks during the drying process and resisting the volume changes that may result during wet/dry cycles as an attempt to simulate the changes of environmental conditions. The results show that the fiber-reinforced samples have the lowest volumetric deformation in comparision with cement and lime stabilized samples, and the optimum fiber content is identified as 0.38%. In addition, the desiccation cracks were not visible on the samples' surface for both unreinforced and chemically stabilized samples. Regarding cracks resistance resulting from the desiccation process, it is observed, that the resistance is connected with the fiber content and increases with the increase of the fiber inclusion, and the optimum content is between 1% and 1.5%.

Fast Detection Algorithm for Voltage Sags and Swells Based on Delta Square Operation for a Single-Phase Inverter System

  • Lee, Woo-Cheol;Sung, Kook-Nam;Lee, Taeck-Kie
    • Journal of Electrical Engineering and Technology
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    • 제11권1호
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    • pp.157-166
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    • 2016
  • In this paper, a new sag and peak voltage detector is proposed for a single-phase inverter using delta square operation. The conventional sag detector is from a single-phase digital phase-locked loop (DPLL) that is based on d-q transformations using an all-pass filter (APF). The d-q transformation is typically used in the three-phase coordinate system. The APF generates a virtual q-axis voltage component with a 90° phase delay, but this virtual phase cannot reflect a sudden change in the grid voltage at the instant the voltage sag occurs. As a result, the peak value is drastically distorted, and it settles down slowly. A modified APF generates the virtual q-axis voltage component from the difference between the current and the previous values of the d-axis voltage component in the stationary reference frame. However, the modified APF cannot detect the voltage sag and peak value when the sag occurs around the zero crossing points such as 0° and 180°, because the difference voltage is not sufficient to detect the voltage sag. The proposed algorithm detects the sag voltage through all regions including the zero crossing voltage. Moreover, the exact voltage drop can be acquired by calculating the q-axis component that is proportional to the d-axis component. To verify the feasibility of the proposed system, the conventional and proposed methods are compared using simulations and experimental results.

장기 파랑측정자료를 이용한 평상파 산정 방법론 (A Methodology of Estimating Design Waves for the Operable Harbor Condition Using Long-term Wave Data)

  • 안경모;천제호
    • 한국해안해양공학회지
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    • 제16권3호
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    • pp.178-189
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    • 2004
  • 본 논문에서는 장기간 측정된 파랑자료를 이용하여 신뢰성 있는 항만설계를 하기 위한 평상파 산정에 대한 방법론을 제시하였다. 제안된 방법론을 부산항 내 해경부두 설계에 적용하여, 부산항 입구 조도 전면해상에서 장기간 측정된 파랑자료를 이용하여 97.5% 평상파를 산정하였다. 1993년 2월부터 2002년 12월까지 측정된 파랑자료를 파향별로 유의파고와 유의파주기의 결합분포를 구한 후, 포물선형 완경사 방정식 파랑모델을 이용하여 해경부두에서의 평상파 조건을 산정하였다. 해경부두 위치에서의 항만설계를 위한 97.5% 평상파의 파고는 1.06 m 이며, 이는 부산항 항외에서 입사되는 파향 E, 유의파고 1.75 m, 유의파주기 7 sec에 의해 생성되는 것으로 분석되었다. 부산항 내 풍파에 의한 평상파에의 영향을 검토하였으나, 항내 풍파는 평상파 산정에 영향이 없으며 항외에서 항내로 진입하는 너울성 파고의 영향이 지배적임이 밝혀졌다. 따라서 항내의 풍파의 영향만을 고려하여 평상파를 추정하였을 경우 심각한 오류가 있음을 알 수 있었다.

히드록시프로필셀룰로오스와 카르보폴을 이용한 부유성 히드로겔 매트릭스의 제조 및 in Vitro 평가 (Preparation and in vitro Evaluation of a Buoyant Hydrogel Matrix with Hydroxypropylcellulose and Carbopol)

  • 김상헌;이민성;최영욱
    • Journal of Pharmaceutical Investigation
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    • 제26권2호
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    • pp.137-144
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    • 1996
  • The study was carried out for the preparation and evaluation of a buoyant hydrogel matrix (BHM), which is buoyant in a neutral or in pH 2.0 buffer solution, by the aspects of buoyancy, swelling, and drug release. Physical mixtures of HPC and CP in various molar ratio were employed as a mucoadhesive polymer which swells and controls the rate of drug release. Anhydrous citric acid and sodium bicarbonate in the molar ratio of 1:3 were employed as effervescing agents which provide a buoyancy for the mucoadhesive polymeric matrix. The buoyancy in vitro was expressed as both floating time$(T_{fl})$ and surfing time$(T_{sf})$, which are the time required for floating from the bottom to the surface of the medium and the time to keep the floated state at the surface of medium during release studies, respectively. A close relationship was observed between the buoyancy and the amount of effervescing agent added. $T_{fl}$ of the buoyant hydrogel matrices were decreased to about 10 seconds linearly with increasing the amount of effervescing agent in the range of 5 to 15%. $T_{sf}$ of the buoyant hydrogel matrices were varied from 1 to 3 hr depending on the amount of effervescing agent. The swelling was observed by changes in diameter of the buoyant hydrogel matrices in distilled water or acidic buffer solution, resulted in dependences on pH and the amount of effervescing agents. The release of hydrochlorothiazide from the buoyant hydrogel matrices were followed by apparent zero-order kinetics, while the buoyant hydrogel matrices were floated at the surface and maintaining their swollen shapes.

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해수의 영향에 따른 이수식 TBM의 슬러리 관리를 위한 기초적 연구 (A fundamental study of slurry management for slurry shield TBM by sea water influence)

  • 김대영;이재원;정재훈;강한별;지성현
    • 한국터널지하공간학회 논문집
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    • 제19권3호
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    • pp.463-473
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    • 2017
  • 벤토나이트는 물과 접촉하면 팽창하고 점성을 발휘하는 성질이 있어 일반적으로 차수가 필요한 토목공사에 많이 활용되고 있다. 이수식 TBM에서는 이와 같은 성질을 활용하여 가압된 슬러리로 불투수성 막을 형성하고 굴착벽면의 붕괴를 방지하는 동시에 굴착된 버력을 운송하며 굴착을 수행한다. 하지만 벤토나이트는 해수와 접촉할 경우 팽창성이 저하되어 그 성질을 발휘하지 못하는 문제가 있다. 이는 해수 조건에서 이수식 TBM으로 터널을 굴착할 시 지하수 유입 증가로 인한 굴착 안정성 및 버력 배출에 문제를 초래할 수 있다. 본 연구에서는 이수식 TBM으로 터널을 굴착 시 해수의 유입으로 인한 슬러리의 상태변화를 살펴보고 이에 대응하기 위한 슬러리 관리방안을 제시 하였다. 이를 위해 현장에서 적용된 슬러리 품질관리 기준을 바탕으로 실내 시험을 수행하였으며, 해수의 영향이 있는 현장에 적용 할 수 있는 방안을 제시하였다.

BATHYMETRIC MODULATION ON WAVE SPECTRA

  • Liu, Cho-Teng;Doong, Dong-Jiing
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2008년도 International Symposium on Remote Sensing
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    • pp.344-347
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    • 2008
  • Ocean surface waves may be modified by ocean current and their observation may be severely distorted if the observer is on a moving platform with changing speed. Tidal current near a sill varies inversely with the water depth, and results spatially inhomogeneous modulation on the surface waves near the sill. For waves propagating upstream, they will encounter stronger current before reaching the sill, and therefore, they will shorten their wavelength with frequency unchanged, increase its amplitude, and it may break if the wave height is larger than 1/7 of the wavelength. These small scale (${\sim}$ 1 km changes is not suitable for satellite radar observation. Spatial distribution of wave-height spectra S(x, y) can not be acquired from wave gauges that are designed for collecting 2-D wave spectra at fixed locations, nor from satellite radar image which is more suitable for observing long swells. Optical images collected from cameras on-board a ship, over high-ground, or onboard an unmanned auto-piloting vehicle (UAV) may have pixel size that is small enough to resolve decimeter-scale short gravity waves. If diffuse sky light is the only source of lighting and it is uniform in camera-viewing directions, then the image intensity is proportional to the surface reflectance R(x, y) of diffuse light, and R is directly related to the surface slope. The slope spectrum and wave-height spectra S(x, y) may then be derived from R(x, y). The results are compared with the in situ measurement of wave spectra over Keelung Sill from a research vessel. The application of this method is for analysis and interpretation of satellite images on studies of current and wave interaction that often require fine scale information of wave-height spectra S(x, y) that changes dynamically with time and space.

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