• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.621-622
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• 2006

In this paper, we show some experimental results of binder-free WC sintered by Pulsed Electric Current Sintering (PECS) also known as Field Assisted Sintering Technology (FAST). These binder-free WC have extremely hardness and stiffness. However, these mechanical properties are dependent on the sintering condition, e.g., maximum temperature, applied pressure, etc. We show some relationship between mechanical properties and sintering condition to improve to sinter the binder-free WC.

• International Journal of Concrete Structures and Materials
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• 제8권4호
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• pp.289-299
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• 2014

Alkali-activated slag concretes are being extensively researched because of its potential sustainability-related benefits. For such concretes to be implemented in large scale concrete applications such as infrastructural and building elements, it is essential to understand its early and long-term performance characteristics vis-a'-vis conventional ordinary portland cement (OPC) based concretes. This paper presents a comprehensive study of the property and performance features including early-age isothermal calorimetric response, compressive strength development with time, microstructural features such as the pore volume and representative pore size, and accelerated chloride transport resistance of OPC and alkali-activated binder systems. Slag mixtures activated using sodium silicate solution ($SiO_2$-to-$Na_2O$ ratio or $M_s$ of 1-2) to provide a total alkalinity of 0.05 ($Na_2O$-to-binder ratio) are compared with OPC mixtures with and without partial cement replacement with Class F fly ash (20 % by mass) or silica fume (6 % by mass). Major similarities are noted between these binder systems for: (1) calorimetric response with respect to the presence of features even though the locations and peaks vary based on $M_s$, (2) compressive strength and its development, (3) total porosity and pore size, and (4) rapid chloride permeability and non-steady state migration coefficients. Moreover, electrical impedance based circuit models are used to bring out the microstructural features (resistance of the connected pores, and capacitances of the solid phase and pore-solid interface) that are similar in conventional OPC and alkali-activated slag concretes. This study thus demonstrates that performance-equivalent alkali-activated slag systems that are more sustainable from energy and environmental standpoints can be proportioned.

• Structural Engineering and Mechanics
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• 제82권2호
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• pp.133-149
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• 2022

This study investigates the resistance of sustainable ultra-high performance concrete (UHPC) on steel reinforcement corrosion. For enhancing the sustainability of UHPC, concrete mixes were prepared with ordinary Portland cement main binder, and mixes with moderate to high percentages of blast furnace cement (CEM III), fly ash (FA), and slag cement as partial replacements of the full quantity of the used cement. Linear polarization resistance technique was employed to estimate the electrochemical behavior of the concrete specimens. Results showed that the compressive strength and the resistance of steel to corrosion in marine environments can be enhanced by improving the sustainability of UHPC through incorporation of CEM III, FA, and slag cement. FA replacement of up to 50% with the addition of 15% SF content produced better compressive strength and steel corrosion resistance than slag cement whether with the use of ordinary Portland cement or blast furnace cement as the main binder.

• Geomechanics and Engineering
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• 제38권4호
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• pp.335-352
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• 2024

Low carbon energy demand in South Korea is increasing, hence leading to an increasing usage of wood pellets and the amount of its combustion by-product called wood pellet fly ash (WA). In an effort to develop recycling technology, this research investigates the use of WA as a new sustainable binder for backfill soil materials. The influence of WA on weathered granite soils (WS) is investigated by mixing 5%, 15%, and 25% of WA dosage, compacted at optimum moisture content, then cured for 3, 7, 14, and 28 days. After curing, the compacted specimens were investigated through unconfined compressive tests, pH tests, total suction tests, and microstructural analysis. The findings suggest that the higher the dosage rate, the higher strength and modulus. Additionally, the alkali ions of WA aid in the cementation of WS particles, and newly cementitious minerals are confirmed after 28 curing days. The refinement of pore microstructures led to a denser WS matrix and stiffness improvements. The results validate the binding potential of wood pellet fly ash on weathered granite soils in terms of strength, modulus, and microstructures.

• Structural Engineering and Mechanics
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• 제86권4호
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• pp.431-441
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• 2023

The aim of this paper is to present a new sustainable ternary and quaternary binder by partially replacing ordinary Portland cement (OPC) with different percentages of supplementary cementitious materials. The motivation is to reduce our dependency on OPC to reduce CO₂ emission and carbon foot print. As the main substitute for the OPC, siliceous fly ash was used. Moreover, silica fume and nanosilica were also used. During examinations the main mechanical parameters of concrete composites, i.e., compressive strength (f_cm) and splitting tensile strength (f_ctm) were assed. The microstructure of these materials was also analysed. It was found that the concrete incorporating pozzolanic materials is characterized by a well-developed structure and has high values of mechanical parameters. The quaternary concrete containing: 80% OPC, 5% FA, 10% SF, and 5% nS have shown the best results in terms of good strength parameters as well as the most favourable microstructure, whereas the worst mechanical parameters with microstructure containing microcracks at phase interfaces were characterized by concrete with more content of FA additive in the concrete mix, i.e., 15%. Nevertheless, all concretes made on quaternary binders had better parameters than the reference one. It can be stated that sustainable concrete incorporating pozzolanic materials could be good substitute of ordinary concretes.

• Computers and Concrete
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• 제17권4호
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• pp.523-539
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• 2016

Alkali-activated binder (AAB) is increasingly being considered as an eco-friendly and sustainable alternative to portland cement (PC). The present study evaluates 30 different AAB mixtures containing fly ash and/or slag activated by sodium hydroxide and sodium silicate by correlating their properties from micro to specimen level using regression. A model is developed to predict compressive strength of AAB as a function of volume fractions of microstructural phases (physicochemical properties) and ultrasonic pulse velocity (elastic properties and density). The predicted models are ranked and then compared with the experimental data. The correlations were found to be quite reasonable (R2 = 0.89) for all the mixtures tested and can be used to estimate the compressive strengths for similar AAB mixtures.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2018년도 추계 학술논문 발표대회
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• pp.112-113
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• 2018

The present feasible tests are to develop the lightweight concrete using bottom ash aggregates and performed air foam for applying to sustainable high-insulation panel. The main variables investigated are water-to-binder, foam volume ratio, and curing conditions. Test results showed that the lightweight concrete possessed the compressive strength of 5~9 MPa at the air dry density of 951~1,139 kg/m3.

• Computers and Concrete
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• 제17권3호
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• pp.337-351
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• 2016

This paper presents the properties of pervious concrete containing high-calcium fly ash. The water to binder ratios of 0.19, 0.22, and 0.25, designed void ratios of 15, 20, and 25%, and fly ash replacements of 10, 20, and 30% were used. The results showed that the use of fly ash as partial replacement of Portland cement enhanced the mixing of paste resulting in a uniform mix and reduced amount of superplasticizer used in the mixture. The compressive strength and flexural strength of pervious concrete were slightly reduced with an increase in fly ash replacement level, while the abrasion resistance increased due mainly to the pozzolanic and filler effects. The compressive strength and flexural strengths at 28 days were still higher than 85% of the control concrete. The aggregate size also had a significant effect on the strength of pervious concrete. The compressive strength and flexural strength of pervious concrete with large aggregate were higher than that with small aggregate.

• Computers and Concrete
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• 제9권6호
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• pp.427-437
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• 2012

This article presents the effect of replacement fly ash (FA) with diatomite (DE) on the properties of geopolymer mortars. DE was used to partially replace FA at the levels of 0, 60, 80 and 100% by weight of binder. Sodium silicate ($Na_2SiO_3$) and sodium hydroxide (NaOH) solutions were used as the liquid portion in the mixture in order to activate the geopolymerization. The NaOH concentrations of 15M, $Na_2SiO_3$/NaOH ratios of 1.5 by weight, and the alkaline liquid/binder (LB) ratios by weight of 0.40, 0.50, 0.60 and 0.70 were used. The curing at temperature of $75^{\circ}C$ for 24 h was used to accelerate the geopolymerization. The flows of all fresh geopolymer mortars were tested. The compressive strengths and the stress-strain characteristics of the mortar at the age of 7 days, and the unit weights were also tested. The results revealed that the use of DE to replace part of FA as source material in making geopolymer mortars resulted in the increased in the workability, and strain capacity of mortar specimens and in the reductions in the unit weights and compressive strengths. The strain capacity of the mortar increased from 0.0028 to 0.0150 with the increase in the DE replacement levels from 0 to 100%. The mixes with 15M NaOH, $Na_2SiO_3$/NaOH of 1.5, LB ratio of 0.50, and using $75^{\circ}C$ curing temperature showed 7 days compressive strengths 22.0-81.0 MPa which are in the range of normal to high strength mortars.

• 산업기술연구
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• 제41권1호
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• pp.1-6
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• 2021

Fly ash and silica fume belong to industry by-products that can be used to produce concrete. This study shows the model of a neural network to evaluate the strength development of blended concrete containing fly ash and silica fume. The neural network model has four input parameters, such as fly ash replacement content, silica fume replacement content, water/binder ratio, and ages. Strength is the output variable of neural network. Based on the backpropagation algorithm, the values of elements in the hidden layer of neural network are determined. The number of neurons in the hidden layer is confirmed based on trial calculations. We find (1) neural network can give a reasonable evaluation of the strength development of composite concrete. Neural network can reflect the improvement of strength due to silica fume additions and can consider the reductions of strength as water/binder increases. (2) When the number of neurons in the hidden layer is five, the prediction results show more accuracy than four neurons in the hidden layer. Moreover, five neurons in the hidden layer can reproduce the strength crossover between fly ash concrete and plain concrete. Summarily, the neural network-based model is valuable for design sustainable composite concrete containing silica fume and fly ash.