• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.63-63
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• 2010

Using both experimental and theoretical approaches, we have investigated the adsorption properties of an organic molecule (HATCN), which is used in OLEDs as an efficient hole injection layer, on metal and inert surfaces. We have also studied the structural and electronic properties of such interfaces and the dependences on deposition thickness. We have observed different trends in work function changes with different surfaces. Our photoelectron spectroscopic measurements have revealed an abnormal phenomenon in HATCN on a metal (Cu) surface: the work function decreases at lower coverage (~monolayer) of HATCN on a metal (Cu) surface, but it increases back and becomes higher than that of a bare Cu surface at higher coverage. It has, on the contrary, been observed that the work function of graphene surface just increases as the HATCN coverage increases. Our first-principles density functional calculations has not only verified our experimental observations, but also disclosed the underlying mechanism of such abnormal and different work function behaviors. We have found that the change in work function results from mutual polarization induced by the geometrical deformation and the bond dipole formed at the interface due to the charge redistribution. At low coverage of HAT-CN on Cu substrate, the former reduces the work function significantly by pulling down the vacuum level, while the latter tends to push up the vacuum level resulting in the work function increase.

• Polymer(Korea)
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• v.24 no.5
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• pp.721-727
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• 2000

The electrolytic plating of a metallic nickel on carbon fiber surfaces was carried out to improve mechanical interfacial properties of carbon fiber/epoxy resin composites. The surface characteristics of carbon fibers and the mechanical interfacial properties of final composites were characterized by X-ray photoelectron spectroscopy (XPS) and interlaminar shear strength (ILSS), respectively. It was found that the electrolytic Ni-plating conditions significantly affected the degree of adhesion at interfaces between carbon fibers and epoxy resin matrix in a composite system. Especially, the increase of O,$_{1s}$/$C_{1s}$ ratio, production of NiO groups, and formation of metallic nickel on the nickel-plated carbon fiber surfaces led to an increase of the ILSS of the composites. Also, the ILSS of the composites was greatly correlated with the $O_{1s}$/$C_{1s}$ ratio of the carbon fibers treated in this work.is work.

• Structural Engineering and Mechanics
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• v.15 no.6
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• pp.609-628
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• 2003

Mechanical anchorage devices are generally tested in the laboratory and may be analyzed using the finite element method. These devices are composed of many components interacting through diverse contact interfaces. Generally, a Coulomb friction law is sufficient to take into account friction between smooth surfaces. However, in the case of mechanical anchorages, a gripping system, named herein the wedge-tendon system, is used to anchor the prestressing tendon. The wedge inner surface is made of a series of triangular notches designed to grip the tendon. In this particular case, the Coulomb law is not adapted to simulate the contact interface. The present paper deals with a new constitutive contact/gripping law to simulate the gripping effect. A parameter identification procedure, based on experimental results as well as on a finite element/neural network approach, is presented. It is demonstrated that all parameters have been selected in a satisfactory way and that the proposed constitutive law is well adapted to simulate the wedge gripping effect taking place in a mechanical anchorage device.

• IE interfaces
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• v.8 no.3
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• pp.133-139
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• 1995

Free from curves and surfaces are frequently used in designing engineering products such as car, ship, airplane, and hosing of electronic households. In many aspect, it is very nice to use the cutter radius compensation function of CNC controller when contour machining a 2-dimensional curve. However, if the 2D curve is a parametric spline, it is not easy to apply the cutter radius compensation function of CNC controller to the NC data obtained from many commercial CAM system. This is mainly due to the error magnification effect when offsetting line segments with inevitable round-off error at their vertices. Proposed in this paper is an approach to contour machining a 2D parametric spline while using cutter radius compensation. Some implementation results are included.

• IE interfaces
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• v.12 no.3
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• pp.458-467
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• 1999

In this paper, we analyze the calendaring operation in the process of paper manufacturing. Controllable parameters involved in the calendaring operation are the calendar material, temperature and pressure. Main objective of this paper is to find the robust design of these parameters which would provide consistent quality of paper in terms of the thickness, brightness, and roughness. We first use a split-plot design in the context of a central composit design for a preliminary analysis to find the proper calendar material. Next, response surfaces for the mean and variance of each quality attribute are fitted as functions of calender temperature and pressure. Bootstrap resampling approach is used to find the robust parameter design.

• The Korean Journal of Ceramics
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• v.1 no.3
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• pp.160-164
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• 1995

Mechanical and chemical tests were performed on $Zro_2 \cdot SiO_2$ glass fibers manufactured by the sol-gel method and E-glass fibers-reinforced cement composites in order to investigate the interactions between glass fibers and cement matrices. Chemical attack leads to corrosion of the glass fiber surfaces. In the corrosion reactions, the surface of $30ZrO_2 \cdot 70 SiO_2$ glass fibers developed a densified concentric layer, which consists of glass corrosion products with much higher Zr and lower Si than the fresh glass fiber. The layer of reaction product is regarded to stiffen the cement matrices and provide a useful improvement to the mechanical properties. The addition of $ZrO_2$ content increases the corrosion resistance of glass fibers in cement by forming a passivating layer on the surface of glass fibers.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.55 no.12
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• pp.581-585
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• 2006

Macro interfaces between two different bulk materials which affect the stability of insulation system exist inevitably in the complex insulation system using in extra high voltage (EHV) electric devices. In this paper, Interface between epoxy and ethylene propylene diene terpolymer (EPDM) was selected as an interface in electrical insulation system and the AC dielectric strength of the interface was investigated. Air compress system was used to give pressure to the interface. Specimens were prepared in various ways to generate different surface conditions for each type of interface. Increasing interfacial pressure, decreasing surface roughness and spreading oil over surfaces improve the AC interfacial dielectric strength. Especially, the dielectric strength was saturated at certain interfacial pressure.

• Nuclear Engineering and Technology
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• v.51 no.4
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• pp.996-1007
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• 2019

We investigated the influence of the aspect ratio (H/R) of the oxide layer on the reactor vessel heating in three-layer configuration. Based on the analogy between heat and mass transfers, we performed mass transfer experiments to achieve high Rayleigh numbers ranging from $6.70{\times}10^{10}$ to $7.84{\times}10^{12}$. Two-dimensional (2-D) semi-circular apparatuses having the internal heat source were used whose surfaces of top, bottom and side simulate the interfaces of the oxide layer with the light metal layer, the heavy metal layer, and the reactor vessel, respectively. Multi-cell flow pattern was identified when the H/R was reduced to 0.47 or less, which promoted the downward heat transfer from the oxide layer and possibly mitigated the focusing effect at the upper metallic layer. The top boundary condition greatly affected the natural convection of the oxide layer due to the presence of secondary flows underneath the cold light metal layer.

• Restorative Dentistry and Endodontics
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• v.25 no.4
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• pp.575-586
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• 2000

In this study, adaptation of compomer to saliva contaminated dentin was evaluated with scanning electron microscope(SEM) and confocal laser scanning microscope(CLSM). For the SEM study, the occulusal surfaces of thirty two molar teeth were grounded to exposure dentin surfaces. The specimen were randomly assigned to control and three experimental groups with four samples in each group. In control group, Dyract and F-2000 compomer were bonded on the specimens according to the manufactures direction. Experimental groups were subdivided into three groups. They were contaminated with saliva on dentin surfaces ; Experimental group 1 : Saliva was dried with compressed air. Experimental group 2 : Saliva was rinsed with air-water spray and dried. Experimental group 3 : After polymerization of an adhesive, they were contaminated with saliva, and then saliva was rinsed with air-water spray and dried. Dyract and F-2000 compomer were bonded on saliva-treated dentin surfaces. The interfaces between dentin and compomer were observed with SEM. For the CLSM study, Class V cavities were prepared in buccal and ligual surfacess of thirty two molars. The specimens were divided into control and experimental groups. Class V cavities in experimental group were contaminated with saliva and those surfaces in each experimental groups received the same treatments as for the SEM study. Cavities were applied Prime & Bond 2.1 and F-2000 compomer primer/adhesive that were mixed with fluorescein, and then were filled with Dyract and F-2000 compomer. Specimens were embedded in transparent acrylic resin and sectioned buccolingual1y with diamond wheel saw, and then mounted on cover slide for CLSM study. The interface between cavity and compomer was observed by fluoresence imaging with a CLSM. The results were as follows : 1. In SEM exammination of Dyract group, control group, experimental group 2, 3 showed close adaptation to dentin and hybrid layer of $3{\sim}4{\mu}m$ diameter. Interfacial gap between compomer and dentin in experimental group 1 was wider than in control group. 2. In SEM examination of F-2000 group, adaptation to dentin of control group was closer than Dytact control group, but hybrid-like layer was not observed. Interfacial gap between compomer and dentin in experimental group 1 was wider than in Dyract experimental group 1. 3. In dissolution specimens of Dyract and F-2000 group, resin tags penetrated through dentinal tubules in control group and experimental group 1 and 3, but the penetration of resin tag was irregular and partial in experimental group 1. 4. In CLSM exammination of Dyract and F-2000 group, adhesive patterns of control and experimental groups showed same as in SEM. This result suggests the treatment methods, rinsing & drying, repeating all adhesive procedures, will produce good effect on adaptation of compomer to dentin if the dentin surface or polymerized adhesive is contaminated by saliva.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 1997.10a
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• pp.140-145
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• 1997

In case of spot-welded joints, the fatigue cracks generally originate from the weld interfaces of the neighborhood nugget tips, and propagate toward the outer surfaces of the sheets. Generally, because fatigue crack was observed in nugget around, strain gage was attached at nugget zone. Accordingly, it was very difficult to detect the generation time of fatigue crack in spot-welded joints and to measure the propagation speed of fatigue crack. We developed the non-destructive method, according to which th fatigue crack propagation rate can be quantitatively estimated by utilizing information obtained from strain gages bonded on the electrode indentations of spot welds. The results measured by real crack were compared with the data which was measured by strain gauge method in fatigue testing. And so fatigue strength was evaluated by stress intensity factor. In this study behavior of fatigue crack propagation under repeated load were considered.