• 제목/요약/키워드: surface-coated

Search Result 3,102, Processing Time 0.042 seconds

Corrosion Inhibition of Steel Rebar in Concrete with the Coated MCI 2022

  • Bezad Bavarian;Lisa Reiner;Kim, Chong Y.
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2002.10a
    • /
    • pp.63-67
    • /
    • 2002
  • The induced chemical and salt solution in water or admixture are originated to the corrosion process of the steeo rebar. These liquids penetrate into concrete as the accompanied by the chemical reaction and cause to attack the steel rebar in concrete. Concrete surfaces which it exposed to deicing, water and sea water is allowed to enter the chlorides in the structures. To prevent from the source of corrosion and deterioration Is subjected to put an end to corrode or reduce to contaminate on the steel rebar. As this reason the MCI 2022 products are applied to the surface of concrete and steel rebar. The concrete samples were made of to the kind of four, i.e. RF, MR, MS, and MM. Corrosion inhibitor is applied to coat on the surface of concrete after it had been cured for 28days. Specimen were immersed in a 3.5% sodium chloride solution. Concrete specimen were tested to determine the changes of the resistance polarization, Rp, over a 22 weeks period. MCI 2022 is significantly shown the corrosion inhibition of steel rebar in 3.5% NaCl solution. In the each different concrete sample, MS and MM is seemed to be better than others. The results are proofed that MCI 2022 is promised to maintain the inhibition of corrosion with high resistance polarization of the steel rebar in concrete.

  • PDF

Nano Particle Coatings on α-alumina Powders by a Carbonate Precipitation (Carbonate 침전법을 이용한 α-알루미나의 나노파티클 코팅)

  • Lim, Jong-Min;Kim, Sang-Woo
    • Journal of Powder Materials
    • /
    • v.14 no.2 s.61
    • /
    • pp.145-149
    • /
    • 2007
  • Nanocrystalline transient aluminas (${\gamma}$-alumina) were coated on core particles (${\gamma}$-alumina) by a carbonate precipitation and thermal-assisted combustion, which is environmentally friend. The ammonium aluminum carbonate hydroxide (AACH) as a precursor for coating of transient aluminas was produced from precipitation reaction of ammonium aluminum sulfate and ammonium hydrogen carbonate. The crystalline size and morphology of the synthetic, AACH, were greatly dependent on pH and temperature. AACH with a size of 5 nm was coated on the core alumina particle at pH 9. whereas rod shape and large agglomerates were coated at pH 8 and 11, respectively. The AACH was tightly bonded coated on the core particle due to formation of surface complexes by the adsorption of carbonates, hydroxyl and ammonia groups on the surface of the core alumina powder. The synthetic precursor successfully converted to amorphous- and ${\gamma}$-alumina phase at low temperature through decomposition of surface complexes and thermal-assisted phase transformation.

Grain Boundary Chemistry and Electrical Characteristics of Semiconducting $SrTiO_3$ Ceramics Synthesized from Surface-Coated Powders (표면 코팅된 분말을 이용하여 제조된 반도성 $SrTiO_3$ 소결체의 입계화학과 전기적 특성)

  • Park, Myung-Beom;Kim, Chong-Don;Heo, Hyun;Cho, Nam-Hee
    • Journal of the Korean Ceramic Society
    • /
    • v.36 no.11
    • /
    • pp.1252-1260
    • /
    • 1999
  • The defect chemistry and electrical characteristics of the grain boundaries of semiconducting SrTiO3 ceramics synthesized with wet-chemically surface-coated powders were investigated. The starting powders were separated into groups of 1-10${\mu}{\textrm}{m}$ 10-20${\mu}{\textrm}{m}$ etc by sedimentation and sieving methods. Na+ ions were absorbed on the powder surfaces by wet chemical-treatment method. The width of the grain boundary ranged up to several nm and the intergranular materials was amorphous. The additives coated on the surface of the powders were observed to be present at the grain boundaries of the ceramics. The diffusion depth of the additives into grains was about 30nm for the SrTiO3 ceramics synthesized with 5w/o coated materials, The threshold voltage grain boundary resistance and boundary potential barrier of the ceramics increased from 0.67V/cm 2.27k$\Omega$ and 0.05eV to 80.9V/cm 13.0k$\Omega$ 1.44eV with increasing the amount of the additives from 0 to 5 w/o respectively .

  • PDF

Excellent Seam Weldable Nano-Composite Coated Zn-Ni Plating Steels for Automotive Fuel Tank

  • Jo, Du-Hwan;Yun, Sang-Man;Park, Kee-Cheol;Kim, Myung-Soo;Kim, Jong-Sang
    • Corrosion Science and Technology
    • /
    • v.18 no.1
    • /
    • pp.16-23
    • /
    • 2019
  • Steels for automotive fuel tank require unique properties such as corrosion resistance for fuel, welding for joining, forming for press, and painting for exterior. Recently, automakers have been requiring excellent seam weldable steels to enhance manufacturing productivity of fuel tank. Thus, POSCO developed a new type of functional steels coated with nano-composite thin layer on Zn-Ni plating steels. The nano-composite coating solution was prepared by mechanical fine dispersion of solutions consisting of polymeric resin and nano-composite materials in aqueous media. The composite solution was coated on the plating steel surface by using roll coater and cured through induction furnace. These new developed plating steels were evaluated for quality performances such as seam and spot weldability, press formability, and corrosion resistance. These new functional steels coated with nano-composite layer exhibited excellent seam weldability and press formability. Detailed discussion of coating solution and experimental results suggest that nano-sized composite dispersion as coating layer plays a key role in enhancing the quality performance.

The Electrochemical Characteristics of Surface-modified Carbonaceous Materials by tin Oxides and Copper for Lithium Secondary Batteries

  • Lee, Joong-Kee;Ryu, D.H.;Shul, Y.G.;Cho, B.W.;Park, D.
    • Carbon letters
    • /
    • v.1 no.3_4
    • /
    • pp.170-177
    • /
    • 2001
  • Lithium intercalated carbon (LIC) are basically employed as an anode for currently commercialized lithium secondary batteries. However, there are still strong interests in modifying carbon surface of active materials of the anode because the amount of irreversible capacity, charge-discharge capacity and high rate capability are largely determined by the surface conditions of the carbon. In this study, the carbonaceous materials were coated with tin oxide and copper by fluidized-bed chemical vapor deposition (CVD) method and their coating effects on electrochemical characteristics were investigated. The electrode which coated with tin oxides gave the higher capacity than that of raw material. Their capacity decreased with the progress of cycling possibly due to severe volume changes. However, the cyclability was improved by coating with copper on the surface of the tin oxides coated carbonaceous materials, which plays an important role as an inactive matrix buffering volume changes. An impedance on passivation film was decreased as tin oxides contents and it resulted in the higher capacity.

  • PDF

Dynamic Sliding Behavior of Water Droplets on the Coated Hydrophobic Surfaces (발수코팅된 표면에서의 수적의 동적 전락거동)

  • Song, Jeong-Hwan;Nakajima, Akira
    • Korean Journal of Materials Research
    • /
    • v.17 no.11
    • /
    • pp.569-573
    • /
    • 2007
  • The static and dynamic hydrophobicities of the water droplets placed on a hydrophobic surface coated using a fluoroalkylsilanes monolayer with different molecular chain lengths were investigated through direct observation of the actual droplet motion during the sliding process. The surface roughness of both was found to be less than 1 nm. The static contact angles of the coated FAS-3 and FAS-17 were respectively $80^{\circ}$ and $108^{\circ}$ at $150^{\circ}C$, 1 h. The slope of sliding acceleration against the water droplet mass exhibited an inflection point, thus suggesting the switching of the dominant sliding mode from slipping to rolling. While their sliding angles were similar in value, notable differences were exhibited in terms of their sliding behavior. This can be understood as being due to the contribution of the shear stress difference at the interface between the solid surface and water during the sliding process. These results show that the sliding acceleration of the water droplets depends strongly on the balance between gravitational and retentive forces on the hydrophobic surface.

Recycling Water Treatment of Aquaculture by Using DynaSand Filter II. Effect of Coating on Removal of Bacteria and Virus in Sand Columns (상향류식 연속 역세 여과를 이용한 양어장 순환수 재리용 II. 여과사의 표면처리에 의한 세균 및 바이러스 처리율 검토)

  • 박종호;조규석;황규덕;김이오
    • Journal of Aquaculture
    • /
    • v.16 no.2
    • /
    • pp.76-83
    • /
    • 2003
  • To improve the efficiency of removal of bacteria and virus with DynaSand Filters used for treatment of recycling wastewater from aquaculture, effect of biofilm formation on bacterial transport through coated sand was estimated. At the neutral pH (pH 7.0), the coated sand was positive of zeta potential (surface charge). Column experiments were also carried out to test the effect of uncoated sand as well as coated sand with Al and Fe. The coated sand influenced more significantly the surface properties, adsorption and transport than the uncoated sand. The leaching batch system investigated for synthetic water showed concentrations of 7.47, 4.80, 20.89 and 7.23 mg/L for the uncoated sand, coated sand with Al, Fe and Al+Fe, respectively. Hence there are significant differences among the tested coatings with reference to bacterial transport and surface properties.

Preparation and Characterization of Carbon Nanofiber Composite Coated Fabric-Heating Elements (탄소나노섬유복합체를 이용한 의류용 직물발열체의 제조 및 특성)

  • Kang, Hyunsuk;Lee, Sunhee
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.39 no.2
    • /
    • pp.247-256
    • /
    • 2015
  • This study prepared fabric-heating elements of carbon nanofiber composite to characterize morphologies and electrical properties. Carbon nanofiber composite was prepared with 15wt% PVDF-HFP/acetone solution, and 0, 1, 2, 4, 8, and 16wt% carbon nanofiber. Dispersion of solution was conducted with stirring for a week, sonification for 24 hours, and storage for a month, until coating. Carbon nanofiber composite coated fabrics were prepared by knife-edge coating on nylon fabrics with a thickness of 0.1mm. The morphologies of carbon nanofiber composite coated fabrics were measured by FE-SEM. Surface resistance was determined by KS K0555 and worksurface tester. A heating-pad clamping device connected to a variable AC/DC power supply was used for the electric heating characteristics of the samples and multi-layer fabrics. An infrared camera applied voltages to samples while maintaining a certain distance from fabric surfaces. The results of morphologies indicated that the CNF content increased specifically to the visibility and presence of carbon nanofiber. The surface resistance test results revealed that an increased CNF content improved the performance of coated fabrics. The results of electric heating properties, surface temperatures and current of 16wt% carbon nanofiber composite coated fabrics were $80^{\circ}C$ and 0.35A in the application of a 20V current. Carbon nanofiber composite coated fabrics have excellent electrical characteristics as fabric-heating elements.

Machining Characteristics of SiC reinforced Composite by multiple diamond-coated drills (다이아몬드 피복공구에 의한 SiC 강화 복합재료의 절삭특성)

  • M. Chen;Lee, Y. M.;S. H. Yang;S. I. Jang
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 2003.06a
    • /
    • pp.533-537
    • /
    • 2003
  • Compared to sintered polycrystalline diamond (PCD), the deposited thin film diamond has a great advantage on the fabrication of cutting tools with complex geometries such as drills. Because of high performance in high speed machining non-ferrous difficult-to-cut materials in the field of automobiles industry, aeronautics and astronautics industry, diamond-coated drills find large potentialities in commercial applications. However, the poor adhesion of the diamond film on the substrate and high surface roughness of the drill flute adversely affect the tool lift and machining quality and they become the main technical barriers for the successful development and commercialization of diamond-coated drills. In this paper, diamond thin films were deposited on the commercial WC-Co based drills by the electron aided hot filament chemical vapor deposition (EACVD). A new multiple coating technology based on changing gas pressure in different process stages was developed. The large triangular faceted diamond grains may have great contribution to the adhesive strength between the film and the substrate, and the overlapping ball like blocks consisted of nanometer sized diamond crystals may contribute much to the very low roughness of diamond film. Adhesive strength and quality of diamond film were evaluated by scanning electron microscope (SEM), atomic force microscope (AFM), Raman spectrum and drilling experiments. The ring-block tribological experiments were also conducted and the results revealed that the friction coefficient increased with the surface roughness of the diamond film. From a practical viewpoint, the cutting performances of diamond-coated drills were studied by drilling the SiC particles reinforced aluminum-matrix composite. The good adhesive strength and low surface roughness of flute were proved to be beneficial to the good chip evacuation and the decrease of thrust and consequently led to a prolonged tool lift and an improved machining quality. The wear mechanism of diamond-coated drills is the abrasive mechanical attrition.

  • PDF

A Study on Improving the Surface Roughness of Stereolithography Parts -Using Paraffin Coating and Grinding Postprocess- (광조형물의 표면 조도 향상에 관한 연구 -파라핀 코팅과 연삭 후처리 공정 이용-)

  • 안대건;김호찬;이석희
    • Proceedings of the Korean Society of Precision Engineering Conference
    • /
    • 2001.04a
    • /
    • pp.45-48
    • /
    • 2001
  • SL(Stereolithogrphy) part is made by piling up thin layers which causes the stair stepping effect at the surface of SL parts. This effect causes excessive surface roughness and requires additional postprocess finishing such as abrasive basting which is detrimental to part geometry and time consuming. Hence paraffin coating and grinding postprocess is proposed to raise the surface quality of SL part. The paraffin which has suitable properties for the proposed postprocess is coated all over the part surface. By grinding the thin layer of coated on the SL part only, the surface roughness can be improved without any damage on the part. From the experimental result, It is verified as very practical for die casting with silicon rubber mold.

  • PDF