• Title/Summary/Keyword: surface-coated

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Electrostatic Properties of N-Acetyl-Cysteine-Coated Gold Surfaces Interacting with ZrO2 Surfaces

  • Park, Jin-Won
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2855-2860
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    • 2012
  • The coating N-acetyl cysteine (NAC) on gold surfaces may be used to design the distribution of either gold particle adsorbed to the $ZrO_2$ surface or vice versa by adjusting the electrostatic interactions. In this study, it was performed to find out electrostatic properties of the NAC-coated-gold surface and the $ZrO_2$ surface. The surface forces between the surfaces were measured as a function of the salt concentration and pH value using the AFM. By applying the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory to the surface forces, the surface potential and charge density of the surfaces were quantitatively acquired for each salt concentration and each pH value. The dependence of the potential and charge density on the concentration was explained with the law of mass action, and the pH dependence was with the ionizable groups on the surface.

The Effect of Surface Environment on the Mechanism in Oblique Cutting (3차원 절삭에서 표면환경이 절삭기구에 미치는 영향)

  • Seo, Nam-Seob
    • Journal of the Korean Society for Precision Engineering
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    • v.1 no.2
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    • pp.24-32
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    • 1984
  • The object of the study is to discuss the effect of magic ink as a surface active substance on the mechanism of chip formation in oblique cutting. The Rehbinder effect has been known as a phenomenon that the mechanical strength reduces when the metal is coated with some surface active substances. In order to interpret these surface effects defined by Rehbinder, the influence on the shear strength of shear plane by coating surface active substances, cutting force by the depth of cut, surface roughness and hardness ratio were observed. The results are as follows: 1. By coating the magic ink on free surface of the forming chip, the effective shear angle increases, and the cuttinbg force and the deformed chip thickness decreases. 2. With the large inclination angle the effective shear angle increases, and the specific cutting force and the friction angle decrease. 3. Cutting of the coated surface improves the surface roughness and the hardness ratio drops, which means another Rehbinder effect.

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A Stlidy on the Mirror Surface F~n~shinSgy stem using Micro Abraslve Film (마이크로 필름을 이용한 경면가공 시스템에 관한 연구)

  • 김기수;남궁석
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1994.10a
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    • pp.273-278
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    • 1994
  • The surface finishing systems using the micro abrasive film were designed and manufactured to make the mirror surface of the cylindrical workpiece. An experimental study of surface finishing was carried out to investigate the performance of mirror surface finishing system. The surface roughness of stainless steel was about Rmax 0.2~0.25 .mu.m, Ra 0.02~0.04 .mu.m in abrasive grain size 12, 9 .mu.m. the surface roughness of chrome coated workpiece was about Rmax 0.07~ 0.11 .mu. m, Ra 0.01 in abrasive grain size 3 .mu. m. Also, to measure the mirror finishing time by mirror surface finishing system, the experiment was carried out on the chrome coated and ground roller of diameter 76mm and length 650mm. The finishing time and surface roughness were 40min and Rmax 0.1~0.13 .mu.m, Ra 0.01 .mu.m.

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Effect of Skinpassing Conditions on the Surface Characteristics of Hot-dip Galvanized Steel Sheets (용융아연도금강판의 표면특성에 미치는 조질압연 조업조건의 영향)

  • 전선호
    • Journal of Surface Science and Engineering
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    • v.34 no.4
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    • pp.327-336
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    • 2001
  • The skinpassing conditions such as roll type, roll force and roll roughness of the work roll were evaluated to give the surface properties of the galvanized steel sheets that were required for automotive and to get rid of the surface defects that caused with the bad control of galvanized coating process parameters. The surface defects of the galvanized steel sheets such as the ripple mark and the scratch were completely removed as the roll force of SPM work roll was increased and the amount of the transfer of roll surface texture to the strip was also gained a lot. The image clarity of electro discharge textured (EDT) coated steel sheets before and after painting was higher than that of the bright (BRT) and shot blasted (SBT) coated steel sheets because of higher PPI value, lower waviness and uniform surface pattern. Since micro-craters transferred on the surface of the galvanized steel sheets played a role of nucleation sites of chromate reaction, Increase of micro-craters was bring to better corrosion resistance with the increase of the roll force and the use of EDT roll at the skin pass mill.

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Performance Evaluation of Ti-Al-N coated Endmill by Arc ton Plating (아크이온플레이팅에 의한 Ti-Al-N코팅 엔드밀의 성능평가)

  • 이상용;강명창;김정석;김광호
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2002.04a
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    • pp.251-254
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    • 2002
  • The technique of high speed machining is widely studied in machining field. In this study, TiAIN single-layered and TiAIN/TiN double-layered coatings were applied to end-mill by an arc ion plating technique. Their performances were comparatively studied about cutting force, tool wear, tool life and surface roughness of workpiece under high speed cutting conditions. The TiAIN single-layer coated tool showed higher wear-resistance due to its higher hardness, while the TiAIN/TiN double-layer coated tool showed better performance for high metal removal, i.e., high fled per tooth condition due to its higher toughness. The surface roughness of the workpiece was not influenced by the wear amount of coated tools.

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Wear Characterisitics of TiN-coated Boron Cast Iron by Arc Evaporation Process (CAE 증착기술에 의해 TiN이 증착된 보론주철의 마모거동)

  • Song, Kun;Yoon, Eui-Sung;Ahn, Hyo-Sok
    • Tribology and Lubricants
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    • v.8 no.1
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    • pp.63-69
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    • 1992
  • In order to gain better understanding of wear behaviors of TiN-coated boron cast iron, tests and analyses were conducted with block-on disc type tribometer. TiN layer of thickness $2 \mu m$ and $4 \mu m$, coated by cathodic arc evaporation process, were experimentally investigated with the variation of applied load and sliding speed under dry sliding condition. Wear characteristics were expressed in terms of the three-dimentional wear map as well as the wear rate vs sliding speed and load. Comparisons of wear and friction characteristics between coated cast irons and uncoated cast irns were also made. Wear mechanism of TiN layer was explained in view of surface interaction between the mating surfaces. The thicker coating exhibited higher hardness and adhesion strength. the significance of stresses at the surface and in the subsurface was briefly discussed in relation to the wear behavior.

Preparation of $ZrO_2$ Coated Graphite Powders in Aqueous and Nonaqueous Solution (수계-비수계 용매를 이용한 흑연분말의 $ZrO_2$ 수열코팅)

  • 김정환;이태근;이기강;이석근
    • Korean Journal of Crystallography
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    • v.14 no.2
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    • pp.67-72
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    • 2003
  • Graphite powders were coated with ZrO₂ by the controlled hydrolysis of a DI water, ethanol and DI water+ethanol solutions. The hydrolysis process was carried out with temperature control because of the low wettability of Zr ions to the surface of the graphite. PVA was added to the solution for the enhancement of metal ion adsorption. The surface of the graphite powders coated with ZrO₂ was observed by SEM and TEM. There are two types of ZrO₂ particles with the condition of ZrOCl₂°§8H₂O aqueous solutions were used; (a) primary particles a few nm in size and (b) secondary particles with ∼0.1 ㎛ size were obtained. The graphite powders coated in 50% ethanol-50% DI water solution of Zr(SO₄)₂ㆍ4H₂O have the relatively uniform coating layer and the starting temperature of oxidation was 100℃ higher than the raw graphite.

A study on the effect of the external electric type corrosion resistance for the bolt connection in weathering steel box girders. (무도장 내후성 강교량의 Box Girder 내부볼트 연결부에 대한 외부전원식 정기방식효과에 관한 연구)

  • Park Yong-Gul;Kim Hun-Tae;Baek Chan Ho;Choi Jung Youl
    • Proceedings of the KSR Conference
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    • 2004.10a
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    • pp.988-993
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    • 2004
  • This paper considers corrosion problems in the bolt connection of weathering steel box girder bridge using the external electric type corrosion resistance method which resisted to local corrosion in coated steel surface with contacted air. The weathering steel was created a rust itself in the passive state. but a coated box girder type was easily dew form could be made galvanic cell that accelerated corrosion. so that it was ruled by protection coat with some paint. Therefore, it needed that can be applied the external electric type corrosion resistance method in coated surface. As a result of the test of polarization amount had measured that the weathering steel was higher currents than the general steel by about $5\~10\%$. Therefore. an external electric type corrosion resistance method can be used to protect local corrosion in the coated bolt connection of weathering steel box girders effectively.

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Duplex Surface Modification with Micro-arc Discharge Oxidation and Magnetron Sputtering for Aluminum Alloys

  • Tong, Honghui;Jin, Fanya;He, Heng
    • Journal of the Korean Vacuum Society
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    • v.12 no.S1
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    • pp.21-27
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    • 2003
  • Micro-arc discharge oxidation (MDO) is a cost-effective plasma electrolytic process which can be used to improve the wear and corrosion resistance of Al-alloy parts by forming a alumina coating on the component surface. However, the MDO coated Al-alloy components often exhibit relatively high friction coefficients and low wear resistance fitted with many counterface materials, additionally, the pitting corrosion for the MDO coated AI-alloy components, especially for a thinner alumina coating, often occurs in atmosphere circumstance due to the porous alumina coats. Therefore, a duplex treatment, combining a MDO coated ahumina thin layer with a TiN coating, prepared by magnetron sputtering (MS), has been investigated. The Vicker's microhardness, pin-on-disc, electrochemical measurement, salt spray, XRD and SEM tests were used to characterize and analyze the treated samples. The work demonstrates that the MDO/MS coated samples have a combination of a very low friction coefficient and good wear resistance as well as corrosion since the micro-holes on alumina coating are partly or fully covered by TiN material.