• Title/Summary/Keyword: surface-coated

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Electrostatic Properties of N-Acetyl-Cysteine-Coated Gold Surfaces Interacting with TiO2 Surfaces

  • Park, Jin-Won
    • Bulletin of the Korean Chemical Society
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    • v.30 no.4
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    • pp.902-906
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    • 2009
  • It is found that that the coating N-acetyl cysteine (NAC) on gold surfaces may be used to design the distribution of either gold particle adsorbed to the $TiO_2$ surface or vice versa by adjusting the electrostatic interactions. In this study, we investigated electrostatic properties of the NAC-coated-gold surface and the $TiO_2$ surface. The surface forces between the surfaces were measured as a function of the salt concentration and pH value using the AFM. By applying the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory to the surface forces, the surface potential and charge density of the surfaces were quantitatively acquired for each salt concentration and each pH value. The surface potential and charge density dependence on the salt concentration was explained with the law of mass action, and the pH dependence was with the ionizable groups on the surface.

A Study on the Mirror Surface Finishing System Using Micro Abrasive Film (마이크로 연마 필름을 이용한 경면 가공 시스템에 관한 연구)

  • Kim, Hong-Bea;Kim, Ki-Soo;Namgung, Suk
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.10
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    • pp.68-74
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    • 1997
  • The surface finishing system using the micro abrasive film was designed and manufactured to make the mirror surface of the cylindrical workpices. An experimental study of srface finishing was carried out to investigate the performance of mirror surface finishing system. The surface roughness value of stainless steel was about 0.2 .approx. 0.25 .mu. m Rmax, 0.02 .approx. 0.04 .mu. m Ra, using abrasive grain size of 12, 9 .mu. m. The surface roughness value of chrome coated workpiece was about 0.07 .approx. 0.11 .mu. m Ra using abrasive grain size 3 .mu. m. In the same condition, the chrome coated workpiece has obtained better surface roughness charateristics than the one of stainless steel.

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Enhanced Field Electron Emission from Dielectric Coated Highly Emissive Carbon Fibers

  • Almarsi, Ayman M.;Hagmann, Mark J.;Mousa, Marwan S.
    • Applied Microscopy
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    • v.47 no.1
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    • pp.55-62
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    • 2017
  • This paper describes experiments aimed at characterizing the behavior of field electron emitters fabricated by coating carbon fibers with epoxylite resin. Polyacrylonitrile carbon fibers of type VPR-19, thermally treated at $2,800^{\circ}C$, were used. Each was initially prepared in a "uncoated" state, by standard electro polishing and cleaning techniques, and was then examined in a scanning electron microscope. The fiber was then baked overnight in a field electron microscope (FEM) vacuum chamber. Current-voltage characteristics and FEM images were recorded on the following day or later. The fiber was then removed from the FEM, coated with resin, "cured" by baking, and replaced in the FEM. After another overnight bake, the FEM characterization measurements were repeated. The coated fibers had significantly better performance than uncoated fibers. This confirms the results of earlier experiments, and is thought to be due in part to the formation of a conducting channel in the resin over layer. For the coated fiber, lower voltages were needed to obtain the same emission current. The coated fibers have current-voltage characteristics that show smoother trends, with greater stability and repeatability. No switch-on phenomena were observed. In addition, the emission images on the phosphor-coated FEM screen were more concentrated, and hence brighter.

Studies on the Application of High-Gloss Plastic Pigment for Paper Coating(II) -Effect of Mixing Ratio of Pigment on the Packing Structure and Optical Properties of Coated Paper- (종이 도공용 고광택 유기안료의 적용에 관한 연구(제2보) -안료의 혼합비율이 도공층의 적층구조와 광학적 특성에 미치는 영향-)

  • 이용규;정경모
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.4
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    • pp.41-48
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    • 2000
  • The main objective of this study was to investigate the packing state and optical properties of coated paper prepared with different coating colors by varying the blending ratio of such pigment as clay, $CaCO_3$, and plastic pigment. To evaluate the effect of packing state of pigment on the properties of coated paper, the coating thickness, which was theoretically calculated by specific gravity, and packing volume of pigment were used. It was found that there exists close relationship between the coating thickness and surface property of coated paper. For instance, the macro roughness(smoothness) of coated paper is closely related to bulkiness. Plastic pigments used in this research has a high finishing efficiency on the light weight coatings. Especially, hollow sphere pigment was very effective for improving the property of coated paper produced in this test. And when HSP was blended with $CaCO_3$the surface property such as smoothness and gloss improved significantly.

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The effect of Cr coated on the Ni and Inconel 601 substrate by PECVD on the oxidation behavior at high temperature (PECVD법으로 증착한 Cr코팅층이 Inconel 601과 Ni의 내산화성에 미치는 영향)

  • 강옥경;정명모;김길무
    • Journal of the Korean institute of surface engineering
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    • v.28 no.3
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    • pp.142-151
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    • 1995
  • In this research, a thin layer of Cr was coated on the pure Ni and Inconel 601 by PECVD (Plasma Enhanced Chemical Vapor Deposition) in order to study the effect of Cr on the oxidation behavior at high temperature. Cr coated Inconel 601, which was oxidized at $1100^{\circ}C$ for 24 hours, formed a protective $Cr_2O_3$ oxide layer and the resistance to isothermai oxidation was improved. On the other hand, oxidation resistance of Cr coated Inconel 601 at 100$0^{\circ}C$ was not significantly improved, probably due to the formation or insufficient $Cr_2O_3$ layer. But, when oxidized at $1000^{\circ}C$ and $1100^{\circ}C$ for 100 hours, Cr coated Inconel 601 improved isothermal oxidation resistance by the formation of continuous $Cr_2O_3$ external scale and by the development of $Al_2O_3$ subscales. Cr coated Ni formed inner layer of $Cr_2O_3$ within almost pure NiO, which provided additional cation vacancies, thus increasing the mobility of Ni ions in this region. It is believed that this doping effect resulted in an increase in the observed oxidation rate compared with pure Ni and did not improve the oxidation resistance.

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Characteristics on Spray Cooling Performance on the Micro-Porous Coated Surfaces (마이크로다공성 발열체 표면에서의 액체분무 냉각성능 특성)

  • Kim Yoon-Ho;Choi Chi-Hwan;Lee Kyu-Jung
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.18 no.4
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    • pp.304-311
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    • 2006
  • Experiments on evaporative spray cooling on the square plate heaters with plain or micro-porous coated surfaces were performed in this study. Micro-porous coated surfaces were made by using DOM [Diamond particle, Omegabond 101, Methyl-Ethyl-Keton] method. In case of purely air-jet cooling, the micro-porous coating doesn't affect the cooling capacity. In spray cooling three different flow patterns (complete wetting, evaporative wetting, dryout) are observed on both plain and micro-porous coated surfaces. The effects of various operating conditions, such as water flow rate, particle size, and coating thickness were investigated on the micro-porous coated surfaces. It is found that the level of surface wetting is an important factor to determine the performance of spray cooling. It depends on the balance between absorbed liquid amount by capillary force over porosity and the evaporative amount. The micro-porous coated surface has largest cooling capacity, especially in the evaporative wetting zone. It is found that the effects of liquid flow rate and coating thickness are significant in evaporative wetting zone, but are not in complete wetting and dryout zones.

Surface Characteristic of Graphene Coated Stainless Steel for PEMFC Bipolar Plate (그래핀이 코팅된 스테인리스강의 고분자전해질 연료전지 분리판 적용을 위한 표면 특성)

  • Lee, Su-Hyung;Kim, Jung-Soo;Kang, Nam-Hyun;Jo, Hyung-Ho;Nam, Dae-Guen
    • Journal of the Korean institute of surface engineering
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    • v.44 no.5
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    • pp.226-231
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    • 2011
  • Graphene was coated on STS 316L by electro spray coating method to improve its properties of corrosion resistance and contact resistance. Exfoliated graphite (graphene) was made of the graphite by chemical treatment. Graphene is distributed using dispersing agent, and STS 316L was coated with diffuse graphene solution by electro spray coating method. The structure of the exfoliated graphite was analyzed using XRD and the coating layer of surface was analyzed by using SEM. Analysis showed that multi-layered graphite structure was destroyed and it was transformed into fine layers graphene structure. And the result of SEM analysis on the surface and the cross section, graphene layer was uniformly formed with 3~5 ${\mu}m$ thickness on the surface of substrate. Corrosion resistance test was applied in the corrosive solution which is similar to the PEM fuel cell stack inside. And interfacial contact resistance test was measured to simulate the internal operating conditions of PEM fuel cell stack. The results of measurements show that stainless steel coated with graphene was improved in corrosion resistance and surface contact resistance than stainless steel without graphene coating layer.

Durability of Various Anti-Corrosive Organic Coatings in Marine Environment for Twelve Years

  • Yamamoto, Mashiro;Kajiki, Toshitaka;Kamon, Toshikuni;Yoshida, Kotaro
    • Corrosion Science and Technology
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    • v.3 no.1
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    • pp.20-25
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    • 2004
  • In order to clarify the durability of protective coatings for maritime steel structures, various anti-corrosive organic coated steel samples were exposed for twelve years in semitropical marine environment at Miyakojima Island, Okinawa, JAPAN. Samples were various organic coated steel pipes, 4.0 m in length and 150 mm in diameter. While the bare steel pipe entirely corroded in 4.5 mm thickness in four and half years, these organic coated steel pipes exhibited protective appearances after twelve-year-exposure except for the defect in the coatings. Polyethylene (PE) lining pipe exhibited a good protective performance. Urethane painted pipe was also good but some barnacles stuck to its surface. A combination of petrolatum tape and FRP cover showed sufficient corrosion resistance for steel surface. The correlation in results between exposure and laboratory acceleration test was examined. It was found that salt spray test (SST) results corresponded to rusted area of scratched portion and that adhesion change of coating layer corresponded to the rotating immersion test result. Among the on-site measured data, volume resistivity is utilized for the index of corrosion protection performance of organic coating.

A Study on the Electromagnetic shielding Effectiveness Using Conductive Polymers (전도성 고분자를 이용한 전자파 차폐효과의 연구)

  • 하남규;이보현;김태영;김종은;서광석
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.3
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    • pp.207-214
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    • 2001
  • The conductive polymers, polyaniline (PANI) emeralidin base and 3,4-polyethylene dioxythiophene(PEDOT) were synthesized and coated on the PET film dealt with acryl type primer to study the electromagnetic shielding effectiveness. When both PANI and PEDOT were coated on the PET film dealt with acryl type priemer, their surface properties such as he adhesive increased. For PANI, when blended with the binder such as PMMA, it adhesive and surface hardness increased, too. The visible light transmittance decreased, while the electromagnetic shielding effectiveness increased, when coated thickness of PANI and PEDOT increased. For PANI, the electromagnetic shielding effectiveness increased as its surface resistance decreased. For PANI, when the surface resistance was 140 Ω/$\square$, the shielding effectiveness was found to be 11 dB in the far field, and 13 dB in the near field at 1 GHz. For PEDOT, when the surface resistance was 200 Ω/$\square$, the shielding effectiveness was found to be 3 dB in the far field, and 7dB in the near field.

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Multi response optimization of surface roughness in hard turning with coated carbide tool based on cutting parameters and tool vibration

  • Keblouti, Ouahid;Boulanouar, Lakhdar;Azizi, Mohamed Walid.;Bouziane, Abderrahim
    • Structural Engineering and Mechanics
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    • v.70 no.4
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    • pp.395-405
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    • 2019
  • In the present work, the effects of cutting parameters on surface roughness parameters (Ra), tool wear parameters (VBmax), tool vibration (Vy) and material removal rate (MRR) during hard turning of AISI 4140 steel using coated carbide tool have been evaluated. The relationships between machining parameters and output variables were modeled using response surface methodology (RSM). Analysis of variance (ANOVA) was performed to quantify the effect of cutting parameters on the studied machining parameters and to check the adequacy of the mathematical model. Additionally, Multi-objective optimization based desirability function was performed to find optimal cutting parameters to minimize surface roughness, and maximize productivity. The experiments were planned as Box Behnken Design (BBD). The results show that feed rate influenced the surface roughness; the cutting speed influenced the tool wear; the feed rate influenced the tool vibration predominantly. According to the microscopic imagery, it was observed that adhesion and abrasion as the major wear mechanism.