• 제목/요약/키워드: surface stability

검색결과 3,613건 처리시간 0.035초

광중합법을 이용한 네마틱액정의 배향 안정성 및 프리틸트각의 발생 (Pretilt Angel Generation and Alignment Stability for Nematic Liquid Crystal Using a Photodimerization Method)

  • 황정연;서대식;김재형;한은주
    • 한국전기전자재료학회논문지
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    • 제14권4호
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    • pp.336-340
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    • 2001
  • We have investigated the generation of pretilt angle and alignment stability for a nematic liquid crystal (NLC) with obliquely polarized UV exposure on the three kinds of photo-polymer. High pretilt angle of the NLC was obtained by polarized UV exposure on a PM4Ch surface for 1 min. But, the low pretilt angle of he NLC on a PVCi surface was observed. The pretilt angle generated is attributed ot the photosensitivity by the long side chaining of photo-polymer. Also, a good thermal stability of the three kinds of photo-polymer were obtained by thermogravimetric analysis (TGA) measurement until 300$^{\circ}C$. Finally, the good LC aligning capabilities using the photodimerization method were observed by annealing-treatment until 150$^{\circ}C$.

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Stability and Interconversion of Acetylcholine Conformers

  • Lee, Jae Shin;Park, Young Choon
    • Bulletin of the Korean Chemical Society
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    • 제35권10호
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    • pp.2911-2916
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    • 2014
  • The gas phase structures, energetics, and interconversion pathways of five lowest energy conformers of acetylcholine were examined employing the B3LYP, MP2, and CCSD(T) methods in conjunction with diverse basis sets including the correlation consistent aug-cc-pVDZ and aug-cc-pVTZ basis sets. It is found that use of adequate basis set containing proper polarization and diffuse functions capable of describing the floppy potential energy surface of acetylcholine is important in correctly predicting the relative stability of these conformers. The interconversion pathways and barrier heights between these conformers were elucidated by examining the potential energy surface for torsional motion, which also manifested the presence of chiral conformations of acetylcholine corresponding to the original conformations. On the basis of high level electronic energy calculations and thermal contribution analysis, four lowest energy conformers appear to be populated in the energy range of less than 1 kcal/mol at room temperature.

Surface Modification of Ag Coated Cu Conductive Metal Powder for Conductive Silicone Sealant Gasket Paste

  • Park, Seong-Yong;Yoon, Tae-Won;Lee, Chung-Ho;Jeong, In-Bum;Hyun, Sang-Hoon
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1076-1077
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    • 2006
  • Conductive pastes consist of conductive fillers( Au, Ag, Ni, Cu etc.), organic binders, solvents and additives. Meanwhile, there are some metal powders such as copper, nickel etc that are used for pastes which have serious surface corrosion problems. This problem leads to change of the color and decrease in conductivity and affect storage stability of conductive pastes. By using silane coupling agent and dispersion agent, we can ensure both the corrosion stability and long term storage stability, and enhance the high performance electrical and mechanical properties of EMI shielding silicone sealant.

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강우침투에 따른 사면안정 해석에 관한 연구 (A Study on the Analysis of Slope Stability in Consideration of Rainfall Infiltration Effect)

  • 안종필;오희주;김진택;박용훈;심태섭
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 추계 학술발표회
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    • pp.904-909
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    • 2008
  • Most of current slope safety analysis consider only the effect of the rise of underground water level. However, because the infiltration of surface water into the ground is believed to have signification effect on slope stability, the present study performed slope safety analysis in case of the rise of underground water level, infiltration of surface water, and both resulting from rainfall, and examined their effect.

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냉간가공한 오스테나이트계 강재의 극저온 특성에 미치는 Ni 및 N의 영향 (The Effect of Nickel and Nitrogen on Cryogenic Properties of Austenitic Stainless Steel)

  • 최진일;주기남;강영환
    • 한국표면공학회지
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    • 제37권1호
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    • pp.64-70
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    • 2004
  • Cryogenic characteristics of austenitic stainless steel based on 304 steel with nickel and nitrogen were investigated at room temperature and $-196^{\circ}C$. The alloys were fabricated by vacuum arc furnace and cold working after homogenization treatment. The addition of nickel and nitrogen decreased the stability of $\delta$-ferrite and induced the stability against the formation of martensite to result significantly in enhancing ductility at $-196^{\circ}C$. Nitrogen reduced Md temperature, which was beneficial to the tensile strength and elongation at $25^{\circ}C$ and -196$^{\circ}C$.

Phase stability and Morphology of high-k gate stack of $Si/SiO_2/HfO_2$ and $Si/SiO_2/ZrO_2$

  • Lee, Seung-Hwan;Bobade, Santosh M.;Yoo, W.J.
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2007년도 추계학술대회 논문집
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    • pp.118-119
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    • 2007
  • Phase stability and morphological investigation on the $Si/SiO_2/HfO_2$ and $Si/SiO_2/ZrO_2$ stack are presented. Thermal stability of $HfO_2$ and $ZrO_2$ determines the quality of interface and subsequently the performance of device. The stacks have been fabricated and annealed at $1000^{\circ}C$ for various time. In evolution of crystalline phase and morphology (electrical and geometrical) of high-k materials, annealing time and process are observed to be crucial factors. The crystallization of some phase has been observed in the case of $Si/SiO_2/HfO_2$. The chemical environment around Zr and Hf in respective samples is observed to be different.

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무전해 Ni-Zn-P 도금의 속도 및 안정성에 미치는 첨가제의 영향 (Effect of Additives on Deposition Rate and Stability of Electroless Black Ni-Zn-P Plating)

  • 오영주;황경진;정원용;이만승
    • 한국표면공학회지
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    • 제36권4호
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    • pp.317-323
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    • 2003
  • The effect of additives such as complexing agents, stabilzers and boric acid on the bath stability and the deposition rate of electroless black Ni-Zn plating has been examined. The deposits obtained became black and showed an amorphous structure. The significant increasing in the deposition rate was not found when only glycine and citric acid were used as complexing agents. The deposition rate increased up to 3 and 4 times by adding malic acid and glycolic acid as an additional complexing agent, respectively. The stabilizers and the boric acid, however, had little influence on the deposition rate.

키토산 섬유를 담체로 이용한 라이소자임 효소의 고정화 (Immobilization of Lysozyme from Hen Egg by Crosslinking Method onto Chitosan Non-woven)

  • 이소희
    • 한국염색가공학회지
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    • 제30권4호
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    • pp.264-274
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    • 2018
  • Immobilization of lysozyme on chitosan non-woven using glutaraldehyde(GA) was investigated. For this, 100 % chitosan non-woven was prepared as novel support for the enzyme immobilization. In addition, free lysozyme activity was examined depending on various pH and temperature by measuring time. Moreover, the optimum immobilization conditions depending on various pH, temperature, immobilization time and lysozyme concentration was evaluated. In addition, thermal stability and storage stability of immobilized lysozyme were measured. The characteristics of immobilized lysozyme was examined by FT-IR, surface morphology, and MTT assay. The results are follows: the optimal immobilization of lysozyme were pH 7.0, $25^{\circ}C$, lysozyme concentration 1.5 mg/ml, immobilization time 240 min. The immobilized lysozyme showed higher thermal stability than the free trypsin. The immobilized lysozyme activity was retained 80 % of its initial activity at $4^{\circ}C$ over 30 days of storage. The lysozyme was immobilized effectively on chitosan non-woven by observation of surface morphology.

MECHANISM OF KEYHOLE FORMATION AND STABILITY IN STATIONARY LASER WELDING

  • Lee, Jae Y.;Sung H. Ko;Choong D. Yoo
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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    • pp.644-651
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    • 2002
  • The formation and stability of stationary laser weld keyholes are investigated using a numerical simulation. The effect of multiple reflections in the keyhole is estimated using the ray tracing method, and the free surface profile, flow velocity and temperature distribution are calculated numerically. In the simulation, the keyhole is formed by the displacement of the melt induced by evaporation recoil pressure, while surface tension and hydrostatic pressure oppose cavity formation. At laser powers of 500W and greater, the protrusion occurs on the keyhole wall, which results in keyhole collapse and void formation at the bottom. Initiation of the protrusion is caused mainly by collision of upward and downward flows due to the pressure components.

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미니돼지에서 발치 후 즉시 임플란트 매식시 치경부 표면처리가 골재생에 미치는 효과 (THE EFFECT OF SURFACE TREATMENT OF THE CERVICAL AREA OF IMPLANT ON BONE REGENERATION IN MINI-PIG)

  • 조진용;김영준;유민기;국민석;오희균;박홍주
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제34권3호
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    • pp.285-292
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    • 2008
  • Purpose: The present study was performed to evaluate the effect of surface treatment of the cervical area of implant on bone regeneration in fresh extraction socket following implant installation. Materials and methods: The four minipigs, 18 months old and 30 kg weighted, were used. Four premolars of the left side of both the mandible and maxilla were extracted. ${\phi}$3.3 mm and 11.5 mm long US II plus implants (Osstem Implant co., Korea) with resorbable blasting media (RBM) treated surface and US II implants (Osstem Implant co., Korea) with machined surface at the top and RBM surface at lower portion were installed in the socket. Stability of the implant was measured with $Osstell^{TM}$ (Model 6 Resonance Frequency Analyser: Integration Diagnostics Ltd., Sweden). After 2 months of healing, the procedures and measurement of implant stability were repeated in the right side by same method of left side. At four months after first experiment, the animals were sacrificed after measurement of stability of all implants, and biopsies were obtained. Results: Well healed soft tissue and no mobility of the implants were observed in both groups. Histologically satisfactory osseointegration of implants was observed with RBM surface, and no foreign body reaction as well as inflammatory infiltration around implant were found. Furthermore, substantial bone formation and high degree of osseointegration were exhibited at the marginal defects around the cervical area of US II plus implants. However, healing of US II implants was characterized by the incomplete bone substitution and the presence of the connective tissue zone between the implant and newly formed bone. The distance between the implant platform (P) and the most coronal level of bone-to-implant contact (B) after 2 months of healing was $2.66{\pm}0.11$ mm at US II implants group and $1.80{\pm}0.13$mm at US II plus implant group. The P-B distance after 4 months of healing was $2.29{\pm}0.13$mm at US II implants group and $1.25{\pm}0.10$mm at US II plus implants group. The difference between both groups regarding the length of P-B distance was statistically significant(p<0.05). Concerning the resonance frequency analysis (RFA) value, the stability of US II plus implants group showed relatively higher RFA value than US II implants group. Conclusion: The current results suggest that implants with rough surface at the cervical area have an advantage in process of bone regeneration on defect around implant placed in a fresh extraction socket.