• Title/Summary/Keyword: surface stability

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Highly stabilized microstructure and excellent electrochemical performances of Ni-rich LiNi0.9Co0.05Mn0.05O2 cathode via La modification (La 개질을 통한 Ni-rich LiNi0.9Co0.05Mn0.05O2 양극재의 고도로 안정화된 미세구조 및 우수한 전기화학적 성능)

  • Seung-Hwan, Lee
    • Journal of Industrial Technology
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    • v.42 no.1
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    • pp.1-5
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    • 2022
  • Although the mileage of electric vehicles can be increased based on the excellent energy density of the LiNi0.9Co0.05Mn0.05O2, it is known that the reason for limiting its use is the low lifespan and poor surface stability due to the structural deformation of the LiNi0.9Co0.05Mn0.05O2. To improve the structural stability of LiNi0.9Co0.05Mn0.05O2, electrochemical performance is improved by La coating on the surface. La-modified LiNi0.9Co0.05Mn0.05O2 shows an initial capacity of 210.6 mAh/g, a capacity retention rate of 89.9 % after 50 cycles, and a retention rate of 52.5% at 6.0 C. These are superior performances than the pristine sample, because the structural stability of the LiNi0.9Co0.05Mn0.05O2 cathode is improved by the La coating.

Effect of Single or Fractionated X-Irradiation on the Pulmonary Surfactant in Rabbits (단회(單回) 및 분획(分劃) X선(線) 흉부(胸部) 조사(照射)가 가토(家兎) 폐포(肺胞) 표면활성(表面活性) 물질(物質)에 미치는 영향(影響))

  • Kim, Jun;Choo, Young-Eun
    • The Korean Journal of Physiology
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    • v.4 no.2
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    • pp.53-60
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    • 1970
  • In an attempt to clarity the effect of X-irradiation on the activity of surfactant in rabbits, and also to observe the possible difference when the irradiation was made in single or fractionated dose, X-ray in dose of 900 r was irradiated to rabbits either in single or fractionated dose of 300 r each day for three day, Tension-area diagram of lung extract was recorded automatically by a modified Langmuir-Wilhelmy balance with a synchronized recording system designed in this department. The surface tension of lung extract was measured at 1,3,5,24, and 48 hours post-irradiation, and the results were compared with the non-irradiated normal group. The result obtained are summerized as follows: 1) The maximal surface tension, minimal surface tension, width of the tension-area diagram at the surface area of 40% in lung extract, and stability index of the normal rabbit lung extracts were 40.73 dynes/cm, 8.96 dynes/cm. 20.71 dynes/cm, and 1.28 respectively. 2) Activity of surfactant was significantly depressed by X-irradiation, and the pattern of depression was more prominent in the single irradiation group than in the fractionated group. 3) It was found that the changes of the width of the tension-area diagram at the surface area of 40% in lung extract and stability indices corresponded well with that of the maximal or minimal surface tension.

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Surface Properties and Betergency of the Binary Surfactant Mixture (계면활성제 혼합용액의 계면특성 및 세척성에 관한 연구)

  • 심소희;박정희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.3
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    • pp.632-640
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    • 1997
  • Changes in surface properties and detergency of sunactant mixtures were investigated in order to study the optimum mixing ratio of anionic and nonionic surfactants by measuring surface tension, interfacial tension, suspendability, and emulsification as a Amction of mixing ratio. Also, surface tension and detergency of the surfactant mixtures were determined with the increase of water-hardness or temperature. The results were as follows: the addition of NPE to anionic surfactant solutions (LAS or SDS) by 0.1 mole fraction remarkably decreased surface tension. NPE (n=15)/anionic surfactant mixtures showed a synergistic effect in lowering interfacial tension and emulsification, but NPE (n=7.5)/anionic surfactant mixtures did not. In suspension stability, however, synergism appeared when LAS or 505 was mixed with both of NPE's. With respect to the hydrophile of NPE, NPE (n=15) was more effective than NPE (n=i.5) in improving suspension stability. Detergency of LAS/NPE mixture changed almost linearly with mixing ratio, but that of SDS/NPE mixture increased remarkably by the addition of 0.1 or 0.2 mole fraction of NPE at all temperatures. As the temperature increased, surface tension of surfactant mixtures decreased and detergency was improved, but their synergistic effect decreased. In hard water, the mixtures showed better detergency than single surfactuant solutions.

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Effects of ta-C Coatings on Surface Characteristics of Dental Ni-Ti Files (치과용 Ni-Ti파일의 표면특성에 미치는 ta-C코팅효과)

  • Sun-Kyun Park;Han-Cheol Choe
    • Corrosion Science and Technology
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    • v.22 no.5
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    • pp.368-376
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    • 2023
  • Dental Ni-Ti files must ensure stability and resistance to fatigue fracture. DLC and ta-C were coated to remove defects on the surface and ensure stability, and the surface characteristics were investigated. When coated with DLC, it was black, and in case of ta-C coating, it was blue-black. Scratches, which are defects caused by mechanical processing, were formed on the surface of the un-coated Ni-Ti file from the end of the file along the direction of processing, with the Pro-file appearing in the vertical direction and the K-file appearing in the file direction. Scratches were reduced on the coated surface, and the surface roughness was greatly reduced after coating compared to before coating. The un-coated Ni-Ti file had the lowest hardness, the DLC-coated file had the highest hardness, and ta-C showed relatively high hardness. The elastic modulus of the DLC coating film was high, and the ta-C elastic modulus was low. The adhesion of the DLC coating film tended to be higher than that of ta-C, and the wear loss amount of DLC coating of taC was lower. The corrosion potential of the ta-C coating increased significantly, and the corrosion current density decreased.

Studies on Rheological Properties of High Solids Coating Colors (I) - Effect of Rheology Modifiers on Viscoelastic Properties -

  • Yoo, Sung-Jong;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.5
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    • pp.39-45
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    • 2012
  • For a fundamental study for high concentration pigment coating, the effects of alkali swellable emulsion (ASE) type rheology modifier and surface adsorption emulsion (SAE) type rheology modifier on both the stability and the viscoelastic behavior of a coating color were elucidated. The coating color prepared with SAE type rheology modifier showed superior thermal and mechanical stability than that with ASE type. In the high concentration and high speed coating process, the mechanical stability of a coating color was a key parameter since both impact force and shear force were increased with the increase of coating color concentration and coating speed, respectively.

Control of Processing Conditions for Improvement of vibration Characteristics of Injection Molded Disk (사출성형 디스크의 진동특성 향상을 위한 공정조건 제어)

  • Sin Hyo-Chol;Nam Ji-Geun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.30 no.6 s.249
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    • pp.615-621
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    • 2006
  • Increased application of optical disks requires more improved dynamic stability of rotating disks. In this study, a new concept of controlling the processing conditions of injection molded disks was developed to improve vibration characteristics. The critical speed, which shows stiffness and dynamic stability of disk, is affected by the residual stress distribution; this varies as functions of distance from the gate and processing condition. The critical speed of disk was calculated with the initial stress taken into consideration, which was determined from injection molding simulation. Choosing melt temperature, mold temperature, filling speed and packing pressure as design parameters, critical speed is maximized with the method of response surface. It is shown that the stability of injection molded disk has been improved for the new condition obtained as a result of the study proposed.

Thermal Stability of 2.5Y-TZP under Low-Temperature Aging (2.5Y-TZP의 안정성에 관한 연구)

  • 장성도;오경영
    • Journal of the Korean Ceramic Society
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    • v.27 no.2
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    • pp.226-232
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    • 1990
  • The degradation phenomena and thermal stability of 2.5Y-TZP at low-temperature were studied by means of XRD, Raman spectra and microstructural analysis. The degradation of heat-treated 2.5Y-TZP at 20$0^{\circ}C$-20hr in air was observed on the TZP surface, be caused by the cracks generated from tlongrightarrowm transformation, and the cracks was propagated inside the polycrystalline body. The ZrO2 grain boundaries and grains near the crack were revealed as if these were diffused and dissolved. And it was also observed mlongrightarrowt transformation as the degraded TZP was refired at 140$0^{\circ}C$, and it was thought to be the fact that the moisture in atmosphere during the aging process contributed to the degradation. The thermal stability of 2.5Y-TZP was improved dramatically with an addition of 3w/o CeO2 or a provision of high Y2O3 concentration on the TZP surface.

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Comparison of Coverage-Dependent Adsorption Structures of Alanine and Leucine on Ge(100): Bonding Configuration and Adsorption Stability

  • Park, Yeong-Chan;Yang, Se-Na;Kim, Jeong-Won;Lee, Han-Gil
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.215-215
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    • 2011
  • The bonding configuration and adsorption stability of alanine and leucine adsorbed on Ge(100)-2${\times}$1 surface were investigated and compared using core-level photoemission spectroscopy (CLPES) and density functional theory (DFT) calculations. The bonding configuration, stability, and adsorption energies were evaluated for two different coverage levels. In both cases, the C 1s, N 1s, and O 1s core-level spectra at a low coverage (0.30 ML) indicated that the carboxyl and amine groups participated in bonding with the Ge(100) surface in an "O-H dissociated-N dative bonded structure". At high coverage levels (0.60 ML), both this structure and an "O-H dissociation bonded structure" were present. As a result, we found that alanine adsorbs more easily (lower adsorption energy) than leucine on Ge(100) surfaces due to less steric hindrance of side chain.

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Computational Analysis of Aqueous Solution Stability for Electroformed Fe-Cr-Ni Thin Layer (전산모사를 활용한 Fe-Cr-Ni 전주용 수용액의 안정성 분석)

  • Jeon, Seung-Hwan;Han, Sang-Seon;Kim, Ma-Ro;Choe, Yong;Lee, Sang-Beom
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.214-214
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    • 2014
  • Computational analysis of aqueous solution stability of Fe-Cr-Ni system to find an electroplating condition of Fe-Cr-Ni layer. Aqueous sulfate solution with iron, chromium and nickel ions was selected by using a numerical S/W with which aqueous solution stability was analyzed. Several possible conditions to perform electro-forming of Fe-Cr-Ni were selected with thermo-dynamical data. The Fe-Cr-Ni system was electro-formed which composition and microstructure of the electroplated Fe-Cr-Ni significantly depended on the solution temperature and electro-potential. The final composition of Fe-3%Cr-48%Ni with less than $30{\mu}m$ thick was well electroplated.

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Pretilt Angel Generation and Alignment Stability for Nematic Liquid Crystal Using a Photodimerization Method (광중합법을 이용한 네마틱액정의 배향 안정성 및 프리틸트각의 발생)

  • 황정연;서대식;김재형;한은주
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.4
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    • pp.336-340
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    • 2001
  • We have investigated the generation of pretilt angle and alignment stability for a nematic liquid crystal (NLC) with obliquely polarized UV exposure on the three kinds of photo-polymer. High pretilt angle of the NLC was obtained by polarized UV exposure on a PM4Ch surface for 1 min. But, the low pretilt angle of he NLC on a PVCi surface was observed. The pretilt angle generated is attributed ot the photosensitivity by the long side chaining of photo-polymer. Also, a good thermal stability of the three kinds of photo-polymer were obtained by thermogravimetric analysis (TGA) measurement until 300$^{\circ}C$. Finally, the good LC aligning capabilities using the photodimerization method were observed by annealing-treatment until 150$^{\circ}C$.

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