• Title/Summary/Keyword: surface properties

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Characterization of Surface Properties of $BaTiO_3$ Powder by XPS

  • Chun, Myoung-Pyo;Cho, Jung-Ho;Kim, Byung-Ik
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.678-679
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    • 2006
  • The effects of particle size on the surface properties of hydro-thermally synthesized barium titanate powders were investigated by means of particle size analysis, specific surface area, SEM, zeta potential and XPS. Particle sizes were measured by laser light scattering and are in the range of 150 to 1100nm. Zeta potential increased with increasing particle size and it was large minus value in the range of particle size from 500 to 900nm, which seems to be related with the dissolution of $Ba^{2+}$ ion in these particle sizes from the analysis of surface properties by XPS.

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The Improvement of Fatigue Properties by 2-step Shot Peening (2단쇼트피닝에 의한 피로특성의 향상)

  • 이승호;심동석
    • Journal of the Korean institute of surface engineering
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    • v.36 no.6
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    • pp.475-479
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    • 2003
  • In this study, to investigate the effects of 2-step shot peening at the surface of spring steel, tests are conducted on spring steel and shot peened specimens. Various tests are accomplished to evaluate mechanical properties influenced by shot peening process, and fatigue tests are also performed to evaluate the improvement of fatigue strength. And then the residual stresses are examined. The mechanical properties of material did not change so much by shot peening. However, the fatigue strength of notched specimen remarkably increased. In the case of 1-step shot peening, fatigue strength increased by about 20% than unpeened specimen. Especially, in the case of 2-step shot peening, fatigue strength increased by about 40%, because the residual compressive stress at surface was higher than that of 1-step shot peened specimen. The fatigue strength and life are closely related to the value and position of maximum compressive residual stress by shot peening.

Electrical Imaging of Thin Film Surface by Scanning Maxwell-stress Microscopy (주사형 맥스웰응력 현미경에 의한 표면의 전기적 이미지)

  • Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1508-1510
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    • 1998
  • Recent development of scanning probe microscope techniques has made it possible to investigate, not only microscopic surface topography, but also physical and chemical properties on the nanometer-scale. The scanning Maxwell-stress microscopy (SMM) is surface characterization tool capable of mapping both the surface topography and electrical properties, such as surface potential, surface charge dielectric constant of thin films with a nanometer-scale resolution by means of the AC voltage driven oscillation of metal coated cantilever. In this study, we observed the surface potential distribution and molecular ordering in thin films. We have demonstrated that the SMM can be used for imaging surface potential distribution over the film surface and also be used for detecting surface changes in thin films. This is first step towards the understanding of electrical phenomena in organic and inorganic materials, biological system with SMM.

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Electrostatic Properties of N-Acetyl-Cysteine-Coated Gold Surfaces Interacting with TiO2 Surfaces

  • Park, Jin-Won
    • Bulletin of the Korean Chemical Society
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    • v.30 no.4
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    • pp.902-906
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    • 2009
  • It is found that that the coating N-acetyl cysteine (NAC) on gold surfaces may be used to design the distribution of either gold particle adsorbed to the $TiO_2$ surface or vice versa by adjusting the electrostatic interactions. In this study, we investigated electrostatic properties of the NAC-coated-gold surface and the $TiO_2$ surface. The surface forces between the surfaces were measured as a function of the salt concentration and pH value using the AFM. By applying the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory to the surface forces, the surface potential and charge density of the surfaces were quantitatively acquired for each salt concentration and each pH value. The surface potential and charge density dependence on the salt concentration was explained with the law of mass action, and the pH dependence was with the ionizable groups on the surface.

Formation of CH3NH3PbBr3 Perovskite Nanocubes without Surfactant and Their Optical Properties

  • Kirakosyan, Artavazd;Yun, Seokjin;Kim, Deul;Choi, Jihoon
    • Journal of the Korean institute of surface engineering
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    • v.51 no.1
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    • pp.79-85
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    • 2018
  • We systematically investigated the optical properties of sub-micron sized methylammonium lead tribromide ($CH_3NH_3PbBr_3$) cubes in the range of 100 to 700 nm, which were prepared by a surfactant-free precipitation method. We found that despite the strong absorbance, their photoluminescence quantum yield (PLQY) is very low as 0.009~0.011 % for whole range of sizes. Surfactant-free synthesis approach results in nanocubes that has no surface passivating reagents (e.g. surfactants) on their surface. As-prepared particles contain a large number of surface defects that may cause the low PLQY. The role of the surface defects were investigated in their photoluminescence decay process, which can be correlated with the particle size. Larger particles are characterized by a slower decay rate compared to smaller particles due to a large number of surface defects in the smaller particles that trap more excitons in the fluorescence decay process. These experimental results provide new insights into the fundamental relationship between surface state and optical properties.

Selective Removal of Cr (VI) and Cr (III) in Aqueous Solution by Surface Modified Activated Carbon

  • Lee, Jeong-Min;Kim, Min-Il;Lee, Young-Seak
    • Carbon letters
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    • v.9 no.1
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    • pp.23-27
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    • 2008
  • The adsorption and reduction of Cr (VI) to Cr (III) by surface modified activated carbon (AC) in an aqueous solution was studied. The effects of surface modifications on the properties of the carbons were investigated by the analysis of specific surface area, carbon surface pH, acid/base surface values and functional groups. In order to understand the Cr(VI) adsorption and reduction ratio from Cr(VI) to Cr(III), the Cr adsorption capacity of AC was also measured and discussed by using inductively coupled plasma and UV spectrophotometer. The modifications bring about substantial variation in the chemical properties whereas the physical properties such as specific surface area, pore volume and pore size distribution nearly were not changed. Total Cr adsorption efficiency of as-received activated carbon (R-AC) and nitric acid treated activated carbon (N1-AC and N2-AC) were recorded on 98.2, 99.7 and 100%. Cr(III) reduction efficiency of R-AC increased largely from 0.4% to 28.3% compared to N1-AC and N2-AC.

Investigation on Adhesion Properties of Sandwich Composite Structures Considering on Surface Treatments

  • Park, Gwanglim;Oh, Kyungwon;Kong, Changduk;Park, Hyunbum
    • International Journal of Aerospace System Engineering
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    • v.1 no.1
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    • pp.16-20
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    • 2014
  • Recently, various kinds of study on light weight structure are performing in the world. The Al honeycomb sandwich structural type adopt for improvement of lightness and structural stability to major part structure of aircraft or spacecraft. Adhesion badness properties of adhesive and adhesion properties of fillet mainly studied about al honeycomb structure. But study for adhesive properties of sandwich construction with surface treatment of Aluminum alloy barely performed. In this study, adhesive film was used between Al and honeycomb core of honeycomb panel[1]. The study for adhesive properties of sandwich construction with surface treatment of AA 5052 skin was performed.

Properties of the Frost Layer Formed on a Cold Flat Surface (냉각평판에 형성된 서리층의 물성치)

  • Kim, Sung-Gone;Yang, Dong-Keun;Lee, Kwan-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.3
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    • pp.374-380
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    • 2003
  • This paper proposes dimensionless correlations predicting properties of the frost layer formed on a cold flat surface. Experiments are carried out to obtain the correlations with various environmental parameters such as air temperature, air velocity, absolute humidity, and cooling plate temperature. As a result, the frost properties (frost layer thickness, density, surface temperature, thermal conductivity) are correlated as a function of Reynolds number, Fourier number, absolute humidity and non-dimensional temperature by using a dimensional analysis. The correlations agree well with the previous and our experimental data within a maximum error of 10%, and are used to predict the frost properties in the following ranges: Reynolds number of 20216 to 53763, Fourier number of 0.1962 to 2.5128, absolute humidity of 3.22 to 8.47, and non-dimensional temperature of 0.125 to 0.5.

A Study on Effect of Nitrogen Ion Implantation on Improvement of Surface Properties of Tool Steel (금형공구강의 표면성질 향상에 미치는 질소이온주입의 효과에 관한 연구)

  • Kim, Hwa-Jeong;Kim, Yohng-Jo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.7 no.4
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    • pp.3-9
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    • 2008
  • The ion implantation technology is generally used in order to improve surface mechanical properties, especially tribological properties, of engineering metals. In this study, experimental works were carried out to investigate the surface properties, such as hardness, wear quantity, wear rate and friction force, of a nitrogen ion implanted tool steel STD11 under dry condition. Specimens for the wear test were made to investigate the influences of the initial ion implantation temperature and the total ion radiation. Wear properties, such as the wear quantity and the wear rate, of the nitrogen ion implanted tool steel were considerably improved, especially under the low sliding speed and the low applied load.

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Optimization on Organoleptic Properties of Mushroom (Agaricus bisporus) Pickles using Response Surface Methodology (반응표면법을 이용한 양송이버섯 피클의 관능적 특성 최적화)

  • 김옥선;주나미
    • Korean journal of food and cookery science
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    • v.20 no.2
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    • pp.158-163
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    • 2004
  • The purpose of this study was to determine the organoleptic properties of mushroom pickles made at various compounding ratios according to central composite design for optimum organoleptic properties. In this study, various kinds of mushroom pickle were made at different compounding ratios of vinegar, sugar and salt-critical ingredients of the pickle recipe and the products were presented to an expert panel, who graded the subjects in 7 degrees for 5 items: color, flavor, hardness, taste and overall quality. As a result of sensory quality, mushroom pickles with 300g of vinegar, 150g of sugar and 60g of salt achieved the highest grade. Meanwhile, the results of Response Surface Methodology were different from the sensory quality results, showing that the optimum mixing conditions for overall organoleptic properties of mushroom pickle were 279.58g of vinegar, 179.34g of sugar and 59.09g of salt. (Ed- based on this conflict in results, I suggest that you make a final recommendation, of either the first, the second, or perhaps an intermediate, ratio)