• Fashion & Textile Research Journal
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• v.8 no.3
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• pp.343-348
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• 2006

This study aims to attain gray tone dyed goods by using tannin that is contained in green tea. Tannin is given general name of polyphenol, which has a characteristic that bonds with protein and it is used for food preservative that protects against bacteria, as well as its purpose of black tone dye for silk treatment that has been processed since its early ages. In particular, as tannin reacts with all kinds of metallic mordant and changes to various colors, when tannin acid is combined with iron, it becomes tannin steel and produces gray tone color. Tannin that is contained in green tea is condensed tannins and its structure does not hydrolyze, thus having flavan type structure. In order to find the suitable condition for processing tannin, UV-Vis part absorption spectrum of green tea tannin, dye ability based on temperature and time, reflection rate based on concentration, color changes based on acid treatment and alkali treatment, changes on surface based on concentration or metal mordant condition, and lightfastness were measured. Maximum absorption wavelength (${\lambda}_{max}$) of green tea tannin was at around 273nm, while strong absorption was also observed at below 350 nm. Dye ability of green tea tannin is done more easily on silk rather than cellulose fibers such as cotton, while the optimum condition for dyeing was observed to be at $60^{\circ}C$, for 20 minutes. As a result of acid treatment, the color of dye material consisted highly of gray tones and showed overall gray tone with the combined color of yellow and red after the alkali treatment. While it was observed that as dye concentration and metal mordant concentration increased, the color changed at counter-clockwise direction on the Y-scale of Munsell's scale of colors. Additionally, lightfastness was more on a normal fading.

• Journal of the Korean Wood Science and Technology
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• v.31 no.2
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• pp.31-37
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• 2003

Among the nondestructive evaluation (NDE) methods for wood defect detection, ultrasonic wave has been considered as competitive technique in terms of economics and workability. Until now, researches on application of NDE methods for wood have focused mainly on standing tree and logs. Recently, some attempts have been conducted with NDE technique, for evaluation of wooden structural members. However, wooden structural members are different from others (standing tree or log) in various aspects. Expecially when some parts or whole member are covered with other materials, they can't be evaluated appropriately on general NDE methods. For the purpose of development of proper NDE technique for the wooden structural members, the ultrasonic wave transmission process investigated on artificial defect in wood. First, various types of transmission process were assumed, and then the transmission times were predicted respectively. Predicted times were compared with the measured time of ultrasonic wave and then a suitable type of transmission process is determined. In case of the ultrasonic wave doesn't transmit directly due to defect, it is reflected once only at the opposite surface of member, and the path is accord with the line of shortest length.

• Journal of the Korean Society of Safety
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• v.23 no.1
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• pp.66-71
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• 2008

A new route to phthalocyanine complexes were developed to synthesize these products by fusion in the absence of solvent. This new method of synthesis without using solvent has advantages over the conventional synthetic methods since there are no risk of explosion and formation of harmful vapor from organic solvent. Reaction of PcFe with axial ligands such as $PcFe(4-VP)_2$[Pc: Phthalocyanine, 4-VP: 4-Vinylpyridine] and $PcFe(VIM)_2$[VIM: 1-Vinylimidazole] afforded powderlike, pure dark greenish blue colored products. The resulted products are soluble in $CH_2Cl_2$ and found to be complexes of the type $PcFeL_2$. Spectral properties were studied with ATR-FTIR and UV/Vis. Thermal and electrical characterization was also performed. Phthalocyanine complexes exhibit useful properties such as UV/Vis blocking, antistatic characteristics and excellent thermal stability and we anticipate various applicability in numerous products.

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.401-408
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• 2005

Recently shield TBM tunnellings are being applied to subway construction in Korean cities. Generally these kinds of tunnellings have the problems in the stability of ground such as subsidence because urban subway is constructed in the shallow depth. A sinkhole occurred on the road just above the tunnel during tunneling in Kwangju, so a survey for upper layer of the tunnel was needed. But conventional Ground Probing Radar can't be applicable due to the presence of steel-mesh screen in the shield segment, so no existent geophysical method is applicable in this site. Because the outer surface of each shield segment is electrically insulated, dipole-dipole resistivity method which is popular in engineering site investigation, was tried to this survey for the first time. Specially manufactured flexible ring-type electrodes were installed into the grouting holes at an interval of 2.4 m on the ceiling. The K-Ohm II system which has been developed by KIGAM and tested successfully in many sites, was used in this site. The system consists of 1000Volt-1Ampere constant-current transmitter, optically isolated 24 bit sigma-delta A/D conversion receiver - maximum 12 channel simultaneous measurements, and graphical automatic acquisition software for easy data quality check in real time. Borehole camera logging with circular white LED lighting was also done to investigate the state of the layer. Measured resistivity data lack of some stations due to failing opening lids of holes, shows general high-low trend well. The dipole-dipole resistivity inversion results discriminate (1) one approximately 4 meter diameter cavity (grouted but incompletely hardened, so low resistivity - less than $30{\Omega}m$), (2) weak zone (100-200${\Omega}m$), and (3) hard zone (high resistivity - more than 1000${\Omega}m$) very well for the distance of 320 meters. The 2-D inversion neglects slight absolute 3-D effect, but we can get satisfactory and useful information. Acquired resistivity section and video tapes by borehole camera logging will be reserved and reused if some problem occurs in this site in the future.

• Geomechanics and Engineering
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• v.12 no.2
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• pp.295-312
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• 2017

Cast in situ and grouted concrete helical piles with 150-200 mm diameter half cylindrical ribs have become an economical and effective choice in Shanghai, China for uplift piles in deep soft soils. Though this type of pile has been successful used in practice, the reinforcing mechanism and the contribution of the ribs to the total resistance is not clear, and there is no clear guideline for the design of such piles. To study the inclusion of ribs to the contribution of shear resistance, the shear behaviour between silty sand and concrete slabs with parallel ribs at different spacing and angles were tested in a large direct shear box ($600mm{\times}400mm{\times}200mm$). The front panels of the shear box are detachable to observe the soil deformation after the test. The tests were modelled with three-dimensional finite element method in ABAQUS. It was found that, passive zones can be developed ahead of the ribs to form undulated failure surfaces. The shear resistance and failure mode are affected by the ratio of rib spacing to rib diameter. Based on the shape and continuity of the failure zones at the interface, the failure modes at the interface can be classified as "punching", "local" or "general" shear failure respectively. With the inclusion of the ribs, the pull out resistance can increase up to 17%. The optimum rib spacing to rib diameter ratio was found to be around 7 based on the observed experimental results and the numerical modelling.

• Journal of the Korean Society of Radiology
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• v.13 no.1
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• pp.73-80
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• 2019

Neutrons are generated by the nuclear reaction, which is absorbed into the concrete wall and causes the activation during cyclotron operation. The purpose of this study is to investigate the effect of neutron activation and radiative concrete on concrete type. This experiment used Monte Carlo simulation and RESRAD model. The results of the experiment showed that the higher the content of Fe in concrete, the greater the shielding rate. The effect of $^{56}Fe(n,\;2np)^{54}Mn$ reaction on workers is also increased. However, radioactive nuclides have low activity and have very low impact on workers. Radioactive concrete should be treated as general wastes with less than its self-disposal tolerance level, and it should be recycled to the surface such as road repair rather than landfill to minimize the effect of $^{14}C$.

• Proceedings of the KIEE Conference
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• 2001.05a
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• pp.190-193
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• 2001

In order to verify the efficiency or availability and stability of photovoltaic(PV) generation systems, huge system apparatuses are needed, in general, in which an actual size of solar panel, a type of converter system and some amount of load facilities should be installed in a particular location. It is also hardly possible to compare a Maximum Power Point Tracking (MPPT) control scheme with others under the same weather and load conditions in an actual PV generation system. The only and a possible way to bring above-mentioned problem to be solved is to realize a transient simulation scheme for PV generation systems using real weather conditions such as insolation and surface temperature of solar cell. The authors, in this paper, introduces a novel simulation method, which is based on a real-time digital simulator (RTDS), for PV generation systems under the real weather conditions. Firstly, VI characteristic equation of a solar cell is developed as an empirical formula and reconstructed in the RTDS system, then the real data of weather conditions are interfaced to the analogue inputs of the RTDS. The outcomes of the simulation demonstrate the effectiveness of the proposed simulation scheme in this paper. The results shows that the cost effective verifying for the efficiency or availability and stability of PV generation systems and the comparison research of various control schemes like MPPT under the same real weather conditions are possible.

• Polymer(Korea)
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• v.29 no.4
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• pp.331-337
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• 2005

In general, alkanethiolates having carboxylic acid in the tail group have been used as biorecepton. In this study, we have immobilized a cytochrome c protein using conjugated aromaticthiolates in order to improve the electrical property and physical stability of alkanethilolates. The pattern formation of self-assembled aromaticthiolate monolayers was as follow. Aromatic thiolates bound on the gold surface by the adsorption of 4'-mercapto-biphenyl-4-carboxylic acid and 4-mercapto-[1,1';4',1']terphenyl-4'-carboxylic acid were oxidized by the irradiation of deep UV light through a negative mask. The negative type pattern of the self-assembled monolayer (SAM) was obtained by developing with a deionized water. The pattern formation and electrical conductivity of aromaticthiolate SAMs was investigated by the measurements of STM and AFM. In addition, cytochrome c or ferrocene amide was immobilized onto the patterned substrate. We also studied on the effect of conjugated aromatic thiolates on the electrical activity of cytochrome c or ferrocene amide by cyclic voltammetry.

• Bulletin of the Korean Chemical Society
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• v.7 no.5
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• pp.395-399
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• 1986

Intramolecular proton transfer equilibria of acetamide and methyl carbamate have been studied theoretically by MNDO MO method. For both substrates, carbonyl-O protonated tautomer was found to be the most stable form, the next most stable one being N-protonated form. Gas phase proton transfers take place by the 1,3-proton rearrangement process and in all cases have prohibitively high activation barriers. When however one solvate water molecule participates in the process, the barriers are lowered substantially and the process proceeds in an intermolecular manner through the intermediacy of the water molecule via a triple-well type potential energy surface; three wells correspond to reactant(RC), intermediate(IC) and product complex(PC) of proton donor-acceptor pairs whereas two transition states(TS) have proton-bridge structure. General scheme of the process can be represented for a substrate with two basic centers(heteroatoms) of A and B as, $$ABH\limits^+\;+\;H_2O\;{\to}\;ABH\limits^+{\cdots}{\limits_{RC}}OH_2\;{\to}\;AB{\cdots}H\limits_{TS}^+{\cdots}{\limits_{1}}OH_2\;{\to}\;AB{\cdots}{\limits_{IC}}H\limits^+OH_2\;{\to}\;BA{\cdots}H\limits_{TS}^+{\cdots}{\limits_{2}}OH_2\;{\to}\;BA H\limits^+{\cdots}{\limits_{PC}}OH_2\;{\to}\;BAH\limits^+\;+\;H_2O$$ Involvement of a second solvate water had negligible effect on the relative stabilities of the tautomers but lowered barrier heights by 5∼6 Kcal/mol. It was calculated that the abundance of the methoxy-O protonated tautomer of the methyl carbamate will be negligible, since the tautomer is unfavorable thermodynamically as well as kinetically. Fully optimized stationary points are reported.

• Wind and Structures
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• v.24 no.6
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• pp.579-611
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• 2017

Bora is a strong, usually dry temporally and spatially transient wind that is common at the eastern Adriatic Coast and many other dynamically similar regions around the world. One of the Bora main characteristics is its gustiness, when wind velocities can reach up to five times the mean velocity. Bora often creates significant problems to traffic, structures and human life in general. In this study, Bora velocity and near-ground turbulence are studied using the results of three-level high-frequency Bora field measurements carried out on a meteorological tower near the city of Split, Croatia. These measurements are analyzed for a period from April 2010 until June 2011. This rather long period allows for making quite robust and reliable conclusions. The focus is on mean Bora velocity, turbulence intensity, Reynolds shear stress and turbulence length scale profiles, as well as on Bora velocity power spectra and thermal stratification. The results are compared with commonly used empirical laws and recommendations provided in the ESDU 85020 wind engineering standard to question its applicability to Bora. The obtained results report some interesting findings. In particular, the empirical power- and logarithmic laws proved to fit mean Bora velocity profiles well. With decreasing Bora velocity there is an increase in the power-law exponent and aerodynamic surface roughness length, and simultaneously a decrease in friction velocity. This indicates an urban-like velocity profile for smaller wind velocities and a rural-like velocity profile for larger wind velocities. Bora proved to be near-neutral thermally stratified. Turbulence intensity and lateral component of turbulence length scales agree well with ESDU 85020 for this particular terrain type. Longitudinal and vertical turbulence length scales, Reynolds shear stress and velocity power spectra differ considerably from ESDU 85020. This may have significant implications on calculations of Bora wind loads on structures.