• 제목/요약/키워드: surface impedance

검색결과 750건 처리시간 0.029초

Corrosion Behaviors of Dental Implant Alloy after Micro-sized Surface Modification in Electrolytes Containing Mn Ion

  • Kang, Jung-In;Son, Mee-Kyoung;Choe, Han-Cheol
    • Journal of Korean Dental Science
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    • 제11권2호
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    • pp.71-81
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    • 2018
  • Purpose: The purpose of this study was to investigate the corrosion behaviors of dental implant alloy after microsized surface modification in electrolytes containing Mn ion. Materials and Methods: $Mn-TiO_2$ coatings were prepared on the Ti-6Al-4V alloy for dental implants using a plasma electrolytic oxidation (PEO) method carried out in electrolytes containing different concentrations of Mn, namely, 0%, 5%, and 20%. Potentiodynamic method was employed to examine the corrosion behaviors, and the alternatingcurrent (AC) impedance behaviors were examined in 0.9% NaCl solution at $36.5^{\circ}C{\pm}1.0^{\circ}C$ using a potentiostat and an electrochemical impedance spectroscope. The potentiodynamic test was performed with a scanning rate of $1.667mV\;s^{-1}$ from -1,500 to 2,000 mV. A frequency range of $10^{-1}$ to $10^5Hz$ was used for the electrochemical impedance spectroscopy (EIS) measurements. The amplitude of the AC signal was 10 mV, and 5 points per decade were used. The morphology and structure of the samples were examined using field-emission scanning electron microscopy and thin-film X-ray diffraction. The elemental analysis was performed using energy-dispersive X-ray spectroscopy. Result: The PEO-treated surface exhibited an irregular pore shape, and the pore size and number of the pores increased with an increase in the Mn concentration. For the PEO-treated surface, a higher corrosion current density ($I_{corr}$) and a lower corrosion potential ($E_{corr}$) was obtained as compared to that of the bulk surface. However, the current density in the passive regions ($I_{pass}$) was found to be more stable for the PEO-treated surface than that of the bulk surface. As the Mn concentration increased, the capacitance values of the outer porous layer and the barrier layer decreased, and the polarization resistance of the barrier layers increased. In the case of the Mn/Ca-P coatings, the corroded surface was found to be covered with corrosion products. Conclusion: It is confirmed that corrosion resistance and polarization resistance of PEO-treated alloy increased as Mn content increased, and PEO-treated surface showed lower current density in the passive region.

박막 고체산화물 연료전지용 이트리아 안정화 지르코니아 전해질 연마표면상의 공기극 성능 (Performance of Air Electrodes with a Surface-Polished Yttria-Stabilized Zircona Electrolyte for Thin-Film Solid Oxide Fuel Cells)

  • 이유기
    • 한국재료학회지
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    • 제11권4호
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    • pp.283-289
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    • 2001
  • 50/50 vol% LSM-YSZ (La$_{1-x}$Sr$_{x}$MnO$_3$-yttria stabilized zirconia)의 복합공기극이 콜로이드 증착법에 의해 연마된 YSZ 전해질상에 증착되었다. 그 전극 특성은 주사전자현미경, X선회절과 임피던스 분석기에 의해 연구되어졌다. 90$0^{\circ}C$에서 공기/LSM -YSZ/YSZ/Pt/공기 셀에 대해 측정된 전형적인 임피던스 스펙트럼들은 2개의 불완전한 호(depressed arc)로 구성되었다. LSM 전극에 대한 YSZ의 첨가는 전극내의 삼상계(TPB) 영역을 증가시켰으며, 이것이 LSM-YSZ 복합공기극의 비저항을 감소시켰다. 또한 전해질 표면의 불순물 제거와 TPB 길이의 증가를 위한 전해질 표면연마는 공기극의 비저항을 훨씬 더 감소시켰다. LSM-YSZ 공기극의 비저항은 작동온도, 공기극의 조성과 입자크기, 인가전류 및 전해질의 표면거칠기에 의해 큰 영향을 받았다.

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표면코팅 경량골재의 전기저항 특성 (Investigation of Electrical Resistance Properties in Surface-Coated Lightweight Aggregate)

  • 김호진;김창현;최정욱;박선규
    • 한국건축시공학회지
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    • 제23권6호
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    • pp.727-738
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    • 2023
  • 계면은 콘크리트 강도 결정 요인 중 가장 약한 영역으로, 골재와 시멘트 페이스트 사이에서 형성된다. 경량골재는 원재료를 팽창, 소성시켜 제조하기 때문에 표면에 수많은 공극을 형성하여 밀도가 낮은 장점을 지니지만 골재 강도가 약하다. 콘크리트는 골재강도가 약하면 골재의 파단이 발생한다. 경량골재의 콘크리트 적용은 골재 파단 때문으로 계면의 강도가 중요하다. 본 연구에서는 경량골재의 계면강도 증진을 위해 고로슬래그 미분말로 골재표면을 코팅하고, 시험체의 임피던스를 비교하여 표면개질에 의한 계면 변화를 분석하였다. 실험결과, 경량골재 표면코팅 시 압축강도가 약 4%정도 증가하였고, 강도 증가에 따라 임피던스 값 중 레지스턴스 값이 증가하는 것을 확인하였다.

차음재의 음향투과손실 측정에 Two-Microphone Impedance Tube Method의 적용과 한계 (The Limit and Application of Two-microphone Impedance Tube Method to the Sound Transmission Loss Measurement of Sound Isolation Materials)

  • 이승;안민홍;이동훈
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2002년도 춘계학술대회논문집
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    • pp.883-888
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    • 2002
  • This study describes the limit and application of the two-microphone impedance tube method to the sound transmission loss measurement of several sound isolation materials with different physical properties. For the sound isolation materials having small flexural rigidity, it is shown that the two-microphone impedance tube method is validated to practically measure the sound transmission loss. For the sound isolation materials having large flexural rigidity, on the other hand, it is found that the two-microphone impedance tube method is no longer valid to measure the sound transmission loss because the regions of resonance and mass law are moved into the higher frequencies. In addition, in order to accurately measure the sound transmission loss of sound isolation materials, their size should be decided based on the consideration of the effect of acoustic excitation on their vibration response.

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Impedance-based health monitoring and mechanical testing of structures

  • Palomino, Lizeth Vargas;de Moura, Jose Dos Reis Vieira Jr.;Tsuruta, Karina Mayumi;Rade, Domingos Alves;Steffen, Valder Jr.
    • Smart Structures and Systems
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    • 제7권1호
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    • pp.15-25
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    • 2011
  • The mechanical properties obtained from mechanical tests, such as tensile, buckling, impact and fatigue tests, are largely applied to several materials and are used today for preliminary studies for the investigation of a desired element in a structure and prediction of its behavior in use. This contribution focus on two widely used different tests: tensile and fatigue tests. Small PZT (Lead Titanate Zirconate) patches are bonded on the surface of test samples for impedance-based health monitoring purposes. Together with these two tests, the electromechanical impedance technique was performed by using aluminum test samples similar to those used in the aeronautical industry. The results obtained both from tensile and fatigue tests were compared with the impedance signatures. Finally, statistical meta-models were built to investigate the possibility of determining the state of the structure from the impedance signatures.

SPT 동적신호를 이용한 지반정보 추정에 관한 해석적 연구 (Analytical Studies for Estimating Soil Properties from the SPT Dynamic Signals)

  • 이병식;김영수;김범상
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2002년도 봄 학술발표회 논문집
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    • pp.423-430
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    • 2002
  • A feasibility of a trial test method was evaluated analytically, in which the elastic modulus of a soil deposit was tried to estimate by analyzing dynamic signals measured during conducting the SPT. If there existed a reliable relationship between the impedance ratio of a rod to a soil and the amplitude ratio of a reflected to an incident wave signal at the tip of steel rod contacting the soil surface, it was expected that one could determine the impedance of soil, and then roughly estimate the elastic modulus from the impedance. For a simple rod-soil system, the existence of the relevant relationship was verified in this study by analyzing computed wave signals propagating up and down through the rod. On the basis of these results, thus, a potential of the test method to practical applications could be seen. However, apparent theoretical shortcomings possessed in this approach were also realized since the soil part had an unconfined contact area where contacted with the rod. Therefore, it was concluded that further studies needed to be conducted, in which the reliable theoretical relationship between the impedance and the amplitude ratio as well as the effective contacting soil area contributing to wave reflection should be justified.

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Thermal Model for Power Converters Based on Thermal Impedance

  • Xu, Yang;Chen, Hao;Lv, Sen;Huang, Feifei;Hu, Zhentao
    • Journal of Power Electronics
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    • 제13권6호
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    • pp.1080-1089
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    • 2013
  • In this paper, the superposition principle of a heat sink temperature rise is verified based on the mathematical model of a plate-fin heat sink with two mounted heat sources. According to this, the distributed coupling thermal impedance matrix for a heat sink with multiple devices is present, and the equations for calculating the device transient junction temperatures are given. Then methods to extract the heat sink thermal impedance matrix and to measure the Epoxy Molding Compound (EMC) surface temperature of the power Metal Oxide Semiconductor Field Effect Transistor (MOSFET) instead of the junction temperature or device case temperature are proposed. The new thermal impedance model for the power converters in Switched Reluctance Motor (SRM) drivers is implemented in MATLAB/Simulink. The obtained simulation results are validated with experimental results. Compared with the Finite Element Method (FEM) thermal model and the traditional thermal impedance model, the proposed thermal model can provide a high simulation speed with a high accuracy. Finally, the temperature rise distributions of a power converter with two control strategies, the maximum junction temperature rise, the transient temperature rise characteristics, and the thermal coupling effect are discussed.